DE3445063A1 - Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen - Google Patents
Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasenInfo
- Publication number
- DE3445063A1 DE3445063A1 DE19843445063 DE3445063A DE3445063A1 DE 3445063 A1 DE3445063 A1 DE 3445063A1 DE 19843445063 DE19843445063 DE 19843445063 DE 3445063 A DE3445063 A DE 3445063A DE 3445063 A1 DE3445063 A1 DE 3445063A1
- Authority
- DE
- Germany
- Prior art keywords
- absorption
- stage
- absorption liquid
- expansion
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007789 gas Substances 0.000 title claims description 64
- 238000000034 method Methods 0.000 title claims description 26
- 238000010521 absorption reaction Methods 0.000 claims description 132
- 239000007788 liquid Substances 0.000 claims description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 15
- 230000008929 regeneration Effects 0.000 claims description 10
- 238000011069 regeneration method Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- RMGHERXMTMUMMV-UHFFFAOYSA-N 2-methoxypropane Chemical compound COC(C)C RMGHERXMTMUMMV-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- -1 glycol dialkyl ether Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843445063 DE3445063A1 (de) | 1984-12-11 | 1984-12-11 | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
| NO854706A NO160178C (no) | 1984-12-11 | 1985-11-25 | Fremgangsmaate ved fjerning av co2 og/eller h2s fra gasser. |
| CA000496618A CA1290553C (en) | 1984-12-11 | 1985-12-02 | Removal of co -and/or h s from gases |
| EP85115549A EP0190434A3 (de) | 1984-12-11 | 1985-12-06 | Verfahren zum Entfernen von Co2 und/oder H2S aus Gasen |
| JP60275239A JPS61138515A (ja) | 1984-12-11 | 1985-12-09 | ガスからｃｏ↓２及び／或はｈ↓２ｓを除去する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843445063 DE3445063A1 (de) | 1984-12-11 | 1984-12-11 | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3445063A1 true DE3445063A1 (de) | 1986-06-12 |
Family
ID=6252419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19843445063 Withdrawn DE3445063A1 (de) | 1984-12-11 | 1984-12-11 | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0190434A3 (cg-RX-API-DMAC7.html) |
| JP (1) | JPS61138515A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1290553C (cg-RX-API-DMAC7.html) |
| DE (1) | DE3445063A1 (cg-RX-API-DMAC7.html) |
| NO (1) | NO160178C (cg-RX-API-DMAC7.html) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0408100A1 (de) * | 1989-07-11 | 1991-01-16 | METALLGESELLSCHAFT Aktiengesellschaft | Verfahren zum Regenerieren einer hochsiedenden, CO2 und H2S enthaltenden Waschlösung |
| ITUB20154126A1 (it) * | 2015-10-06 | 2017-04-06 | Giammarco Vetrocoke S R L | Procedimento perfezionato di rimozione selettiva di gas da miscele gassose che li contengono mediante l'impiego di soluzioni di lavaggio funzionanti con un ciclo chimico-fisico di assorbimento e rigenerazione ed impianto per attuare il procedimento |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3518368A1 (de) * | 1985-05-22 | 1986-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
| US4814104A (en) * | 1987-02-05 | 1989-03-21 | Uop | Tertiary alkanolamine absorbent containing an ethyleneamine promoter and its method of use |
| DE19828977A1 (de) * | 1998-06-29 | 1999-12-30 | Basf Ag | Verfahren zur Entfernung saurer Gasbestandteile aus Gasen |
| DE10028637A1 (de) | 2000-06-09 | 2001-12-13 | Basf Ag | Verfahren zum Entsäuern eines Kohlenwasserstoff-Fluidstroms |
| DE10135370A1 (de) | 2001-07-20 | 2003-01-30 | Basf Ag | Verfahren zur Entfernung saurer Gase aus einem Gasstrom |
| DE10306254A1 (de) | 2003-02-14 | 2004-08-26 | Basf Ag | Absorptionsmittel und Verfahren zur Entfernung saurer Gase aus Fluiden |
| DE102005033837B4 (de) | 2005-07-20 | 2019-02-28 | Basf Se | Verfahren zum Entfernen von sauren Gasen und Ammoniak aus einem Fluidstrom |
| CN102292139B (zh) | 2009-01-29 | 2014-09-03 | 巴斯夫欧洲公司 | 用于除去酸性气体的包含氨基酸和酸性促进剂的吸收剂 |
| US8221712B2 (en) | 2009-05-12 | 2012-07-17 | Basf Se | Absorption medium for the selective removal of hydrogen sulfide from fluid streams |
| US20130244312A1 (en) * | 2011-10-26 | 2013-09-19 | Phillips 66 Company | Systems and methods for carbon dioxide absorption |
| EP2990090A1 (de) | 2014-08-25 | 2016-03-02 | Basf Se | Absorptionsmittel zur selektiven Entfernung von Schwefelwasserstoff aus einem Fluidstrom |
| CA2959095C (en) | 2014-08-25 | 2022-08-09 | Basf Se | Removal of carbon dioxide from a fluid flow |
| CA2959093C (en) | 2014-08-25 | 2022-11-22 | Basf Se | Removal of hydrogen sulphide and carbon dioxide from a stream of fluid |
| CN106604771B (zh) | 2014-08-25 | 2020-06-09 | 巴斯夫欧洲公司 | 用于气体洗涤的具有叔烷基氨基和伯氨基的二胺 |
| BR112018003738A2 (pt) | 2015-09-29 | 2018-09-25 | Basf Se | amina cíclica para remoção seletiva de sulfeto de hidrogênio |
| KR20180057628A (ko) | 2015-09-29 | 2018-05-30 | 바스프 에스이 | 황화수소의 선택적 제거를 위한 흡수제 |
| CA3000286A1 (en) | 2015-09-29 | 2017-04-06 | Basf Se | Method for the selective removal of hydrogen sulfide |
| CN109069984B (zh) | 2016-04-25 | 2021-09-03 | 巴斯夫欧洲公司 | 吗啉基受阻胺化合物在选择性除去硫化氢中的用途 |
| EP3468692A1 (de) | 2016-06-10 | 2019-04-17 | Basf Se | Cyclohexandiamine zur verwendung in der gaswäsche |
| MY190751A (en) | 2016-08-01 | 2022-05-12 | Basf Se | Two-stage method for removing co2 from synthesis gas |
| US11173446B2 (en) | 2017-02-10 | 2021-11-16 | Basf Se | Process for removal of acid gases from a fluid stream |
| CN110650785B (zh) | 2017-05-15 | 2022-05-24 | 巴斯夫欧洲公司 | 用于选择性脱除硫化氢的吸收剂和方法 |
| JP7101759B2 (ja) | 2017-09-04 | 2022-07-15 | ビーエーエスエフ ソシエタス・ヨーロピア | 硫化水素を選択的に除去するための吸収剤および方法 |
| EP3927450B1 (en) | 2019-02-18 | 2023-06-07 | Basf Se | Process for removal of acid gases from a fluid stream with a liquid absorbent comprising a piperazine ring |
| CN114173908B (zh) | 2019-09-10 | 2025-04-01 | 巴斯夫欧洲公司 | 从流体料流中移除酸性气体的方法 |
| IL311126A (en) | 2021-08-27 | 2024-04-01 | Enerkem Inc | Maximizing syngas carbon utilization and conversion to biofuel |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2551717C3 (de) * | 1975-11-18 | 1980-11-13 | Basf Ag, 6700 Ludwigshafen | und ggf. COS aus Gasen |
-
1984
- 1984-12-11 DE DE19843445063 patent/DE3445063A1/de not_active Withdrawn
-
1985
- 1985-11-25 NO NO854706A patent/NO160178C/no not_active IP Right Cessation
- 1985-12-02 CA CA000496618A patent/CA1290553C/en not_active Expired - Lifetime
- 1985-12-06 EP EP85115549A patent/EP0190434A3/de not_active Withdrawn
- 1985-12-09 JP JP60275239A patent/JPS61138515A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0408100A1 (de) * | 1989-07-11 | 1991-01-16 | METALLGESELLSCHAFT Aktiengesellschaft | Verfahren zum Regenerieren einer hochsiedenden, CO2 und H2S enthaltenden Waschlösung |
| ITUB20154126A1 (it) * | 2015-10-06 | 2017-04-06 | Giammarco Vetrocoke S R L | Procedimento perfezionato di rimozione selettiva di gas da miscele gassose che li contengono mediante l'impiego di soluzioni di lavaggio funzionanti con un ciclo chimico-fisico di assorbimento e rigenerazione ed impianto per attuare il procedimento |
| WO2017060796A1 (en) * | 2015-10-06 | 2017-04-13 | Giammarco-Vetrocoke S.R.L. | Hybrid process and plant for the selective absorption of gases from a gas mixture |
| RU2717533C2 (ru) * | 2015-10-06 | 2020-03-23 | Гиаммарко-Ветрококе С.Р.Л. | Гибридный способ и установка для выборочного поглощения газов из газовой смеси |
Also Published As
| Publication number | Publication date |
|---|---|
| NO854706L (no) | 1986-06-12 |
| NO160178B (no) | 1988-12-12 |
| CA1290553C (en) | 1991-10-15 |
| JPS61138515A (ja) | 1986-06-26 |
| NO160178C (no) | 1989-03-22 |
| EP0190434A3 (de) | 1987-09-30 |
| JPH0576326B2 (cg-RX-API-DMAC7.html) | 1993-10-22 |
| EP0190434A2 (de) | 1986-08-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |