DE3029789C2 - Wäßrige Polysiloxanemulsion - Google Patents
Wäßrige PolysiloxanemulsionInfo
- Publication number
- DE3029789C2 DE3029789C2 DE3029789A DE3029789A DE3029789C2 DE 3029789 C2 DE3029789 C2 DE 3029789C2 DE 3029789 A DE3029789 A DE 3029789A DE 3029789 A DE3029789 A DE 3029789A DE 3029789 C2 DE3029789 C2 DE 3029789C2
- Authority
- DE
- Germany
- Prior art keywords
- emulsion
- weight
- parts
- water
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title claims description 120
- 229920001296 polysiloxane Polymers 0.000 title claims description 28
- -1 polysiloxane Polymers 0.000 title claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 125000000129 anionic group Chemical group 0.000 claims description 8
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 4
- 229940075614 colloidal silicon dioxide Drugs 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 16
- 239000004115 Sodium Silicate Substances 0.000 description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 15
- 229910052911 sodium silicate Inorganic materials 0.000 description 15
- 238000000576 coating method Methods 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 150000003460 sulfonic acids Chemical class 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 150000007514 bases Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 229920006294 polydialkylsiloxane Polymers 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical class CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- NNAVBEAARXTLEG-UHFFFAOYSA-N 2-(10-methylundecyl)phenol Chemical class CC(C)CCCCCCCCCC1=CC=CC=C1O NNAVBEAARXTLEG-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical compound CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 description 1
- GSWAOPJLTADLTN-UHFFFAOYSA-N oxidanimine Chemical compound [O-][NH3+] GSWAOPJLTADLTN-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000004447 silicone coating Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003450 sulfenic acids Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000002435 tendon Anatomy 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/064,152 US4244849A (en) | 1979-08-06 | 1979-08-06 | Silicone emulsion which provides an elastomeric product and methods for preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3029789A1 DE3029789A1 (de) | 1981-02-19 |
| DE3029789C2 true DE3029789C2 (de) | 1983-11-17 |
Family
ID=22053917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3029789A Expired DE3029789C2 (de) | 1979-08-06 | 1980-08-06 | Wäßrige Polysiloxanemulsion |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4244849A (Direct) |
| JP (1) | JPS5946989B2 (Direct) |
| AU (1) | AU535238B2 (Direct) |
| BE (1) | BE884642A (Direct) |
| BR (1) | BR8004947A (Direct) |
| CA (1) | CA1160379A (Direct) |
| DE (1) | DE3029789C2 (Direct) |
| FR (1) | FR2463164A1 (Direct) |
| GB (1) | GB2057474B (Direct) |
| IT (1) | IT1132272B (Direct) |
| MX (1) | MX155266A (Direct) |
| NL (1) | NL185722C (Direct) |
| SE (1) | SE441453B (Direct) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4273813A (en) * | 1980-05-19 | 1981-06-16 | Dow Corning Corporation | Method of providing waterproof coating for masonry walls |
| US4548835A (en) * | 1981-07-16 | 1985-10-22 | Matsushita Electric Industrial Company, Limited | Method for fabricating electrodes for use in lead storage batteries |
| US4504549A (en) * | 1983-05-20 | 1985-03-12 | Union Carbide Corporation | Elastomeric silicone finishes applied to substrates and method of preparing same |
| JPS6096650A (ja) * | 1983-10-31 | 1985-05-30 | Toray Silicone Co Ltd | シリコ−ン水性エマルジヨン組成物の製造方法 |
| US4547312A (en) * | 1984-08-31 | 1985-10-15 | Dow Corning Corporation | Electrically conductive elastomers from emulsions |
| US4545914A (en) * | 1984-08-31 | 1985-10-08 | Dow Corning Corporation | Conductive elastomers from electrically conductive fibers in silicone emulsion |
| US4609486A (en) * | 1985-02-25 | 1986-09-02 | Dow Corning Corporation | Silicone water-based emulsions having improved shelf life |
| US4590220A (en) * | 1985-05-24 | 1986-05-20 | Dow Corning Corporation | Method of producing a silicone water-based elastomer |
| US4647618A (en) * | 1985-05-24 | 1987-03-03 | Dow Corning Corporation | Method of producing a silicone water-based elastomer |
| IL78560A0 (en) * | 1985-06-28 | 1986-08-31 | Miles Lab | Electrochemical sensor and membrane therefor |
| US4631296A (en) * | 1986-02-18 | 1986-12-23 | Dow Corning Corporation | Method of producing a silicone water-based elastomer |
| US4634733A (en) * | 1986-02-18 | 1987-01-06 | Dow Corning Corporation | Method of producing a silicone water-based elastomer |
| DE3637836A1 (de) * | 1986-11-06 | 1988-05-19 | Wacker Chemie Gmbh | Waessrige silicondispersionen |
| US4753035A (en) * | 1987-02-04 | 1988-06-28 | Dow Corning Corporation | Crosslinked silicone coatings for botanical seeds |
| US4950502A (en) * | 1987-09-10 | 1990-08-21 | Dow Corning Corporation | Method of hydrophobing silica |
| FR2621921B1 (fr) * | 1987-10-20 | 1990-02-23 | Rhone Poulenc Chimie | Emulsion aqueuse de silicone pouvant reticuler en un elastomere par elimination de l'eau |
| US4824877A (en) * | 1988-02-02 | 1989-04-25 | Dow Corning Corporation | High polymer content silicone emulsions |
| FR2627502A1 (fr) * | 1988-02-18 | 1989-08-25 | Rhone Poulenc Chimie | Emulsion de silicone pouvant reticuler en un elastomere par elimination de l'eau |
| US5973061A (en) * | 1988-08-31 | 1999-10-26 | Rhone-Poulenc Chimie | Aqueous silicone dispersions crosslinkable into elastometric state by dehydration |
| FR2637605B1 (fr) * | 1988-10-11 | 1990-12-14 | Rhone Poulenc Chimie | Dispersion aqueuse de silicone a base de siliconate reticulant en un elastomere par elimination de l'eau |
| FR2642765B1 (fr) * | 1989-02-03 | 1991-04-26 | Rhone Poulenc Chimie | Dispersion aqueuse de silicone a base d'aminosilane et/ou d'amidosilane reticulant en un elastomere par elimination de l'eau |
| GB8906588D0 (en) * | 1989-03-22 | 1989-05-04 | Dow Chemical Co | Seed treatment |
| FR2647798B1 (fr) * | 1989-05-31 | 1991-09-13 | Rhone Poulenc Chimie | Dispersion aqueuse a base d'huiles silicones fonctionnalisees pouvant reticuler en un elastomere par elimination de l'eau |
| CA2017090A1 (en) * | 1990-05-17 | 1991-11-17 | Stephen Dunn | Coating composition |
| DE4419257A1 (de) * | 1994-06-01 | 1995-12-07 | Wacker Chemie Gmbh | Verfahren zur wasserabweisenden Imprägnierung von Gips |
| FR2721317B1 (fr) * | 1994-06-20 | 1996-09-06 | Rhone Poulenc Chimie | Produit dérivé de silicate possédant des propriétés builder et tensioactives. |
| FR2721318B1 (fr) * | 1994-06-20 | 1996-12-06 | Rhone Poulenc Chimie | Polymère silicié organominéral, son utilisation comme agent tensio-actif dans les compositions détergentes et compositions détergentes contenant ledit polymère. |
| US5494562A (en) * | 1994-06-27 | 1996-02-27 | Ciba Corning Diagnostics Corp. | Electrochemical sensors |
| GB9511241D0 (en) * | 1995-06-03 | 1995-07-26 | Crompton Garland Ltd | Paint compositions |
| US5668203A (en) * | 1995-06-07 | 1997-09-16 | Xerox Corporation | Elastomeric articles containing haloceramer compositions |
| US5744199A (en) * | 1996-10-31 | 1998-04-28 | Dow Corning Corporation | Method of sealing openings in structural components of buildings for controlling the passage of smoke |
| US6319982B1 (en) | 1998-09-08 | 2001-11-20 | Ck Witco Corporation | Waterborne silicone adhesives, sealants and coatings |
| DE19933710A1 (de) * | 1999-07-19 | 2001-01-25 | Daniele Casalini | Oberflächenbeschichteter Hartstoff |
| US20060178289A1 (en) * | 2004-07-20 | 2006-08-10 | Enrique Hernandez | Multifunctional material compositions and methods |
| US20070161539A1 (en) * | 2006-01-12 | 2007-07-12 | Enrique Hernandez | Method of regulating degree of polymerization of an alkali metal silicate in solution using pH |
| WO2009077389A1 (de) * | 2007-12-14 | 2009-06-25 | Henkel Ag & Co. Kgaa | Härtbare zusammensetzungen enthaltend wässrige dispersionen von organopolysiloxanen |
| DE102008003155A1 (de) | 2008-01-03 | 2009-07-09 | Henkel Ag & Co. Kgaa | Härtbare Zusammensetzungen enthaltend wässrige Dispersionen von Organopolysiloxanen |
| DE102007060919A1 (de) | 2007-12-14 | 2009-06-18 | Henkel Ag & Co. Kgaa | Härtbare Zusammensetzungen enthaltend wässrige Dispersionen von Organopolysiloxanen |
| DE202012104490U1 (de) * | 2012-11-20 | 2014-02-27 | Tremco Illbruck Productie B.V. | Schaumzusammensetzung für Bauzwecke |
| BR102013002396B1 (pt) * | 2013-01-31 | 2024-01-30 | Maycon Isense Dalpiaz | Processo de obtenção de composto semipastoso antiaderente para aço líquido em metal sólido e composto semipastoso antiaderente para aço líquido em metal sólido |
| CN112391114B (zh) * | 2020-11-11 | 2021-11-05 | 住井科技(深圳)有限公司 | 绝缘涂料组合物以及绝缘皮膜 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA862183A (en) * | 1971-01-26 | E. Nelson Melvin | Fiberglass treatment | |
| GB1024024A (en) * | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
| US3355406A (en) * | 1965-01-21 | 1967-11-28 | Dow Corning | Silicone rubber latexes reinforced with silsesquioxanes |
| BE759286A (fr) * | 1969-11-24 | 1971-05-24 | Dow Corning | Emulsions de siloxanes a durcissement rapide utiles comme agents de separation |
| US3706695A (en) * | 1970-10-12 | 1972-12-19 | Dow Corning | Method of preparing a silicone emulsion and regenerating same and electrically conductive product |
| JPS5096627A (Direct) * | 1973-12-26 | 1975-07-31 | ||
| JPS52155661A (en) * | 1976-06-22 | 1977-12-24 | Shin Etsu Chem Co Ltd | Preparation of organopolysiloxane-silicate salt complex |
-
1979
- 1979-08-06 US US06/064,152 patent/US4244849A/en not_active Expired - Lifetime
-
1980
- 1980-07-04 CA CA000355526A patent/CA1160379A/en not_active Expired
- 1980-07-30 MX MX183362A patent/MX155266A/es unknown
- 1980-07-31 IT IT23838/80A patent/IT1132272B/it active
- 1980-08-05 BE BE0/201657A patent/BE884642A/fr not_active IP Right Cessation
- 1980-08-05 JP JP55107623A patent/JPS5946989B2/ja not_active Expired
- 1980-08-05 AU AU61101/80A patent/AU535238B2/en not_active Ceased
- 1980-08-05 FR FR8017281A patent/FR2463164A1/fr active Granted
- 1980-08-05 NL NLAANVRAGE8004454,A patent/NL185722C/xx not_active IP Right Cessation
- 1980-08-06 BR BR8004947A patent/BR8004947A/pt not_active IP Right Cessation
- 1980-08-06 DE DE3029789A patent/DE3029789C2/de not_active Expired
- 1980-08-06 SE SE8005588A patent/SE441453B/sv not_active IP Right Cessation
- 1980-08-06 GB GB8025632A patent/GB2057474B/en not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| MX155266A (es) | 1988-02-12 |
| BR8004947A (pt) | 1981-02-17 |
| NL8004454A (nl) | 1981-02-10 |
| SE8005588L (sv) | 1981-02-07 |
| DE3029789A1 (de) | 1981-02-19 |
| AU535238B2 (en) | 1984-03-08 |
| CA1160379A (en) | 1984-01-10 |
| GB2057474B (en) | 1983-04-07 |
| FR2463164A1 (fr) | 1981-02-20 |
| FR2463164B1 (Direct) | 1983-02-25 |
| SE441453B (sv) | 1985-10-07 |
| IT1132272B (it) | 1986-07-02 |
| BE884642A (fr) | 1981-02-05 |
| NL185722C (nl) | 1990-07-02 |
| JPS5946989B2 (ja) | 1984-11-16 |
| AU6110180A (en) | 1981-02-12 |
| NL185722B (nl) | 1990-02-01 |
| IT8023838A0 (it) | 1980-07-31 |
| JPS5624446A (en) | 1981-03-09 |
| GB2057474A (en) | 1981-04-01 |
| US4244849A (en) | 1981-01-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3029789C2 (de) | Wäßrige Polysiloxanemulsion | |
| DE3689130T2 (de) | Verfahren zur Herstellung von wässrigem Latex aus vernetztem Polydiorganosiloxan. | |
| DE1494065A1 (de) | Verfahren zur Haertung von Organopolysiloxan bei Zimmertemperatur | |
| DE2358784A1 (de) | Kalt haertende silikon-kautschukzusammensetzungen | |
| DE2644551A1 (de) | Loesungsmittelbestaendige kalthaertende silikonkautschuk-massen | |
| DE1289989B (de) | Lagerbestaendige Organopolysiloxanlatices | |
| DE69108603T2 (de) | Zusammensetzungen für flammhemmende Überzugsmittel und beschichtete Gegenstände. | |
| DE2719013C3 (de) | Polymerengemisch | |
| DE3704657A1 (de) | Teilchenfoermige mehrphasenpolymerisate | |
| DE3704655A1 (de) | Teilchenfoermige mehrphasenpolymerisate | |
| DE2556559A1 (de) | Verfahren zum herstellen eines polysiloxans | |
| DE3927362A1 (de) | Verfahren zur herstellung einer polyorganosiloxanmasse | |
| EP0828794B1 (de) | Wässrige dispersionen von organopolysiloxanen | |
| DE2350369A1 (de) | Verfahren zur herstellung von diorganopolysiloxanen | |
| DE3687320T2 (de) | Wasser enthaltender kitt auf basis von organopolysiloxanen. | |
| DE2702056C3 (de) | Verfahren zur Herstellung eines Polysiloxanelastomeren | |
| DE2255116A1 (de) | Vernetzung von polymeren | |
| DE2943832C2 (de) | Verfahren zur Herstellung einer Polysiloxanemulsion und deren Verwendung | |
| DE1495956C3 (de) | Verfahren zur Herstellung von Organopolysiloxancopolymeren | |
| DE3019655A1 (de) | Siliconemulsion, verfahren zu ihrer herstellung und ihre verwendung | |
| DE2618418A1 (de) | Siloxancopolymer | |
| CH646987A5 (de) | Mit sauerstoff vernetzbare mischung auf basis von mercaptofunktionellen organosiloxanen. | |
| DE1814823A1 (de) | Haertbare Kompositionen aus Silanolendblockiertem Polydiorganosiloxan und Alkoxycyclopolysiloxan | |
| DE2142594C2 (de) | Polydiorganosiloxan-Polystyrol-Blockcopolymere | |
| DE2154011A1 (Direct) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| 8128 | New person/name/address of the agent |
Representative=s name: SPOTT, G., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 800 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |