DE3017123A1 - Fungizid - Google Patents
FungizidInfo
- Publication number
- DE3017123A1 DE3017123A1 DE19803017123 DE3017123A DE3017123A1 DE 3017123 A1 DE3017123 A1 DE 3017123A1 DE 19803017123 DE19803017123 DE 19803017123 DE 3017123 A DE3017123 A DE 3017123A DE 3017123 A1 DE3017123 A1 DE 3017123A1
- Authority
- DE
- Germany
- Prior art keywords
- copper
- salt
- polymer
- parts
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000010949 copper Substances 0.000 title claims abstract description 20
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 19
- 239000000417 fungicide Substances 0.000 title claims abstract description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 150000003863 ammonium salts Chemical class 0.000 title claims abstract description 8
- 150000003839 salts Chemical class 0.000 title abstract description 4
- 229920001577 copolymer Polymers 0.000 title description 8
- 239000002253 acid Substances 0.000 title 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims abstract description 3
- -1 copper amine salt Chemical class 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 29
- 241000196324 Embryophyta Species 0.000 abstract description 7
- 241000233622 Phytophthora infestans Species 0.000 abstract description 4
- 240000003768 Solanum lycopersicum Species 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 abstract description 3
- 239000003973 paint Substances 0.000 abstract description 3
- 235000016068 Berberis vulgaris Nutrition 0.000 abstract description 2
- 241000335053 Beta vulgaris Species 0.000 abstract description 2
- 241000530549 Cercospora beticola Species 0.000 abstract description 2
- 241001661371 Exobasidium vexans Species 0.000 abstract description 2
- 241001181532 Hemileia vastatrix Species 0.000 abstract description 2
- 235000008694 Humulus lupulus Nutrition 0.000 abstract description 2
- 244000141359 Malus pumila Species 0.000 abstract description 2
- 240000008790 Musa x paradisiaca Species 0.000 abstract description 2
- 241001281803 Plasmopara viticola Species 0.000 abstract description 2
- 241000184297 Pseudocercospora musae Species 0.000 abstract description 2
- 244000061456 Solanum tuberosum Species 0.000 abstract description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 abstract description 2
- 241000228452 Venturia inaequalis Species 0.000 abstract description 2
- 230000003373 anti-fouling effect Effects 0.000 abstract description 2
- 235000021016 apples Nutrition 0.000 abstract description 2
- 235000021015 bananas Nutrition 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 229920000447 polyanionic polymer Polymers 0.000 abstract description 2
- 235000012015 potatoes Nutrition 0.000 abstract description 2
- 241001281802 Pseudoperonospora Species 0.000 abstract 1
- 244000269722 Thea sinensis Species 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 239000000178 monomer Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 206010061217 Infestation Diseases 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
- 239000004128 Copper(II) sulphate Substances 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 241000342307 Pseudoperonospora humuli Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002969 artificial stone Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/13—Dicarboxylic acids
- C07C57/145—Maleic acid
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
- A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/126—Acids containing more than four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
- C07C55/02—Dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (22)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803017123 DE3017123A1 (de) | 1980-05-03 | 1980-05-03 | Fungizid |
GR64628A GR75196B (enrdf_load_stackoverflow) | 1980-05-03 | 1981-04-08 | |
DE8181102722T DE3161008D1 (en) | 1980-05-03 | 1981-04-10 | Copper complexes, their preparation, their use in controlling plant pests and agents therefor |
US06/252,800 US4409358A (en) | 1980-05-03 | 1981-04-10 | Copper complexes |
AT81102722T ATE4766T1 (de) | 1980-05-03 | 1981-04-10 | Kupferkomplexe, ihre herstellung, ihre verwendung zur bekaempfung von pflanzenschaedlingen und mittel dafuer. |
EP81102722A EP0039788B1 (de) | 1980-05-03 | 1981-04-10 | Kupferkomplexe, ihre Herstellung, ihre Verwendung zur Bekämpfung von Pflanzenschädlingen und Mittel dafür |
IL62645A IL62645A (en) | 1980-05-03 | 1981-04-14 | Copper complexes,their preparation and their use in controlling plant pests |
CA000375391A CA1171426A (en) | 1980-05-03 | 1981-04-14 | Copper complexes, their preparation, their use in controlling plant pests, and agents for such control |
GB8112616A GB2077740B (en) | 1980-05-03 | 1981-04-23 | Copper complexes and their use in controlling plant pests |
IE950/81A IE51149B1 (en) | 1980-05-03 | 1981-04-29 | Copper complexes,their preparation,their use in controlling plant pests,and agents for such control |
MA19338A MA19132A1 (fr) | 1980-05-03 | 1981-04-29 | Complexes de cuivre,leur preparation,leur emploi pour la lutte contre les parasites vegetaux et produits anti-parasitaires qui les renferment . |
PT72950A PT72950B (en) | 1980-05-03 | 1981-04-29 | Process for the preparation of complex copper salts having phytosanitary effect and phytosanitary compositions containing them |
HU811150A HU184955B (en) | 1980-05-03 | 1981-04-30 | Pesticide compositions containing complex copper compounds |
BR8102689A BR8102689A (pt) | 1980-05-03 | 1981-04-30 | Processo de preparacao de complexos de cobre, aplicaveis para combater organismos fitopatogenicos e respectivas composicoes |
ES501820A ES8300003A1 (es) | 1980-05-03 | 1981-04-30 | Procedimiento para la obtencion de aminoacatos de cobre |
AU70015/81A AU538632B2 (en) | 1980-05-03 | 1981-04-30 | Copper complexes and their use in controlling plant pests |
JP6529581A JPS56169694A (en) | 1980-05-03 | 1981-05-01 | Copper ammine salt, its manufacture, plant protection agent containing it and expulsion of plant disease and vermin |
DK194181A DK160910C (da) | 1980-05-03 | 1981-05-01 | Planteforligeligt kobberaminsalt af en polycarboxylsyre med fungicid og baktericid virkning samt fremgangsmaade til bekaempelse af planteangribende svampe eller bakterier |
ZA00812901A ZA812901B (en) | 1980-05-03 | 1981-05-01 | Copper complexes,ther preparation,their use in controlling plant pests,and agents for such control |
US06/474,309 US4528185A (en) | 1980-05-03 | 1983-03-11 | Copper complexes, their preparation, their use in controlling plant pests, and agents for such control |
KE3432A KE3432A (en) | 1980-05-03 | 1984-07-26 | Copper complexes their preparation their use in controlling plant pests and agents for such control |
MY469/86A MY8600469A (en) | 1980-05-03 | 1986-12-30 | Copper complexes their preparation their use in controlling plant pests and agents for such control |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803017123 DE3017123A1 (de) | 1980-05-03 | 1980-05-03 | Fungizid |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3017123A1 true DE3017123A1 (de) | 1981-11-05 |
Family
ID=6101615
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19803017123 Withdrawn DE3017123A1 (de) | 1980-05-03 | 1980-05-03 | Fungizid |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS56169694A (enrdf_load_stackoverflow) |
DE (1) | DE3017123A1 (enrdf_load_stackoverflow) |
HU (1) | HU184955B (enrdf_load_stackoverflow) |
ZA (1) | ZA812901B (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1982003817A1 (en) * | 1981-05-08 | 1982-11-11 | Sundman Carl Erik | Wood preservative compositions |
DE3520313A1 (de) * | 1984-06-20 | 1986-01-09 | Kemira Oy, Helsinki | Holzschutzmittel |
DE102006008843A1 (de) * | 2006-02-25 | 2007-08-30 | Spiess-Urania Chemicals Gmbh | Verfahren zur Behandlung von Hölzern unter Verwendung von kupferaminhaltigen Holzschutzmitteln |
WO2022118255A1 (en) * | 2020-12-02 | 2022-06-09 | Adama Makhteshim Ltd. | Copper-based fungicide composition |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2530201B2 (ja) * | 1988-03-02 | 1996-09-04 | 北興化学工業株式会社 | 付着性改良剤および付着性良好な農薬粉剤 |
ZA931681B (en) * | 1992-04-03 | 1993-12-07 | Griffin Corp | Copper complex bactericide/fungicide and method of making same |
DE10351004A1 (de) * | 2003-10-30 | 2005-05-25 | Basf Ag | Nanopartikuläre Wirkstoffformulierungen |
WO2007069767A1 (ja) * | 2005-12-16 | 2007-06-21 | Riken | 無機銅化合物を有効成分とする農園芸用殺菌剤 |
MX2013002320A (es) * | 2010-08-27 | 2013-09-26 | Gowan Com Internat E Servicos Limitada | Composicones de tratamiento de plantas y metodos para su uso. |
US9474282B2 (en) * | 2013-12-13 | 2016-10-25 | Tony John Hall | Acid-solubilized copper-ammonium complexes and copper-zinc-ammonium complexes, compositions, preparations, methods, and uses |
CN108024530B (zh) * | 2015-09-30 | 2022-09-20 | 陶氏环球技术有限责任公司 | 制备抗微生物组合物的方法 |
JP6757181B2 (ja) * | 2016-05-31 | 2020-09-16 | 株式会社日本触媒 | 抗菌剤 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54117024A (en) * | 1978-03-01 | 1979-09-11 | Bp Chem Int Ltd | Copper ammonium complex composition * production thereof and protection of base substance |
NO810830L (no) * | 1980-03-22 | 1981-09-23 | Bp Chem Int Ltd | Metallaminkarboksylater og deres anvendelse som preservativer |
-
1980
- 1980-05-03 DE DE19803017123 patent/DE3017123A1/de not_active Withdrawn
-
1981
- 1981-04-30 HU HU811150A patent/HU184955B/hu not_active IP Right Cessation
- 1981-05-01 ZA ZA00812901A patent/ZA812901B/xx unknown
- 1981-05-01 JP JP6529581A patent/JPS56169694A/ja active Granted
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1982003817A1 (en) * | 1981-05-08 | 1982-11-11 | Sundman Carl Erik | Wood preservative compositions |
DE3520313A1 (de) * | 1984-06-20 | 1986-01-09 | Kemira Oy, Helsinki | Holzschutzmittel |
DE102006008843A1 (de) * | 2006-02-25 | 2007-08-30 | Spiess-Urania Chemicals Gmbh | Verfahren zur Behandlung von Hölzern unter Verwendung von kupferaminhaltigen Holzschutzmitteln |
WO2022118255A1 (en) * | 2020-12-02 | 2022-06-09 | Adama Makhteshim Ltd. | Copper-based fungicide composition |
Also Published As
Publication number | Publication date |
---|---|
JPH0413321B2 (enrdf_load_stackoverflow) | 1992-03-09 |
JPS56169694A (en) | 1981-12-26 |
ZA812901B (en) | 1982-05-26 |
HU184955B (en) | 1984-11-28 |
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