DE2941464A1 - Flammschutzmittel fuer polyphenylenaether-harze - Google Patents
Flammschutzmittel fuer polyphenylenaether-harzeInfo
- Publication number
- DE2941464A1 DE2941464A1 DE19792941464 DE2941464A DE2941464A1 DE 2941464 A1 DE2941464 A1 DE 2941464A1 DE 19792941464 DE19792941464 DE 19792941464 DE 2941464 A DE2941464 A DE 2941464A DE 2941464 A1 DE2941464 A1 DE 2941464A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- phosphine oxide
- parts
- polyphenylene ether
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 229920001955 polyphenylene ether Polymers 0.000 title claims abstract description 14
- 229920005989 resin Polymers 0.000 title claims abstract description 9
- 239000011347 resin Substances 0.000 title claims abstract description 9
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 title claims description 6
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 title description 2
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 239000004793 Polystyrene Substances 0.000 claims abstract description 8
- 229920002223 polystyrene Polymers 0.000 claims abstract description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 21
- ILFYYSUCZQEGOL-UHFFFAOYSA-N 3-[bis(2-cyanoethyl)phosphoryl]propanenitrile Chemical compound N#CCCP(=O)(CCC#N)CCC#N ILFYYSUCZQEGOL-UHFFFAOYSA-N 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- PDFFEDMPZWGYSJ-UHFFFAOYSA-N 3-[2-cyanoethyl-[(2,4,6-trimethylphenyl)methyl]phosphoryl]propanenitrile Chemical compound CC1=CC(C)=C(CP(=O)(CCC#N)CCC#N)C(C)=C1 PDFFEDMPZWGYSJ-UHFFFAOYSA-N 0.000 claims description 3
- -1 Pentamethylbenzyl Chemical group 0.000 claims description 3
- 125000006177 alkyl benzyl group Chemical group 0.000 claims description 2
- 229920002959 polymer blend Polymers 0.000 claims 4
- 125000006184 2,5-dimethyl benzyl group Chemical group [H]C1=C(C([H])=C(C(=C1[H])C([H])([H])[H])C([H])([H])*)C([H])([H])[H] 0.000 claims 1
- 239000008240 homogeneous mixture Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 229920001169 thermoplastic Polymers 0.000 abstract description 3
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000011342 resin composition Substances 0.000 description 6
- ZKWABBRIUSNHJG-UHFFFAOYSA-N 3-[benzyl(2-cyanoethyl)phosphoryl]propanenitrile Chemical compound N#CCCP(=O)(CCC#N)CC1=CC=CC=C1 ZKWABBRIUSNHJG-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 3
- 229940073608 benzyl chloride Drugs 0.000 description 3
- 229920005669 high impact polystyrene Polymers 0.000 description 3
- 239000004797 high-impact polystyrene Substances 0.000 description 3
- UNRGEIXQCZHICP-UHFFFAOYSA-N 2-(chloromethyl)-1,3,5-trimethylbenzene Chemical compound CC1=CC(C)=C(CCl)C(C)=C1 UNRGEIXQCZHICP-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- DSIQDXZNQNRKSD-UHFFFAOYSA-N bis(2-cyanoethyl)-oxophosphanium Chemical compound N#CCC[P+](=O)CCC#N DSIQDXZNQNRKSD-UHFFFAOYSA-N 0.000 description 2
- 239000012496 blank sample Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920006380 polyphenylene oxide Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- ISNICOKBNZOJQG-UHFFFAOYSA-N 1,1,2,3,3-pentamethylguanidine Chemical compound CN=C(N(C)C)N(C)C ISNICOKBNZOJQG-UHFFFAOYSA-N 0.000 description 1
- GIIKDPPVXLAAQJ-UHFFFAOYSA-N 3-(2-cyanoethylphosphonoyl)propanenitrile Chemical compound N#CCCP(=O)CCC#N GIIKDPPVXLAAQJ-UHFFFAOYSA-N 0.000 description 1
- IGTOUCHXDLMVMN-UHFFFAOYSA-N 3-[2-cyanoethyl(2-hydroxypropan-2-yl)phosphoryl]propanenitrile Chemical compound N#CCCP(=O)(C(C)(O)C)CCC#N IGTOUCHXDLMVMN-UHFFFAOYSA-N 0.000 description 1
- 235000009781 Myrtillocactus geometrizans Nutrition 0.000 description 1
- 240000009125 Myrtillocactus geometrizans Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000012485 toluene extract Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5397—Phosphine oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
- C08G2261/312—Non-condensed aromatic systems, e.g. benzene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95120278A | 1978-10-13 | 1978-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2941464A1 true DE2941464A1 (de) | 1980-04-24 |
Family
ID=25491412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19792941464 Withdrawn DE2941464A1 (de) | 1978-10-13 | 1979-10-12 | Flammschutzmittel fuer polyphenylenaether-harze |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5552348A (enrdf_load_stackoverflow) |
| DE (1) | DE2941464A1 (enrdf_load_stackoverflow) |
| NL (1) | NL7907579A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3731607A1 (de) * | 1987-09-19 | 1989-03-30 | Hoechst Ag | Stabilisierte, aromatische polyetherketone enthaltende mischung und deren verwendung zur herstellung von formteilen |
-
1979
- 1979-10-11 JP JP13009179A patent/JPS5552348A/ja active Granted
- 1979-10-12 DE DE19792941464 patent/DE2941464A1/de not_active Withdrawn
- 1979-10-12 NL NL7907579A patent/NL7907579A/nl not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3731607A1 (de) * | 1987-09-19 | 1989-03-30 | Hoechst Ag | Stabilisierte, aromatische polyetherketone enthaltende mischung und deren verwendung zur herstellung von formteilen |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6216972B2 (enrdf_load_stackoverflow) | 1987-04-15 |
| JPS5552348A (en) | 1980-04-16 |
| NL7907579A (nl) | 1980-04-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |