DE293842C - - Google Patents
Info
- Publication number
- DE293842C DE293842C DENDAT293842D DE293842DA DE293842C DE 293842 C DE293842 C DE 293842C DE NDAT293842 D DENDAT293842 D DE NDAT293842D DE 293842D A DE293842D A DE 293842DA DE 293842 C DE293842 C DE 293842C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- parts
- dimethylanilinarsinic
- additional
- arsic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 4
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical class [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000000802 nitrating effect Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- -1 dinitromethylnitraminophenyl - Chemical class 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000006396 nitration reaction Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 150000001495 arsenic compounds Chemical class 0.000 description 1
- VJWWIRSVNSXUAC-UHFFFAOYSA-N arsinic acid Chemical compound O[AsH2]=O VJWWIRSVNSXUAC-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/66—Arsenic compounds
- C07F9/70—Organo-arsenic compounds
- C07F9/74—Aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 293842 KLASSE Mg. GRUPPE- M 293842 CLASS GROUP Mg.
Zusatz zum Patent 285572 *).Addition to patent 285572 *).
Patentiert im Deutschen Reiche vom 15. Oktober 1912 ab. Längste Dauer: 13. Mai 1927.Patented in the German Empire on October 15, 1912. Longest duration: May 13, 1927.
Durch Patent 285572 und dessen Zusatzpatent 286667 ist ein Verfahren zur Darstellung eines Bismethylaminotetraminoarsenobenzols geschützt, welches darin besteht, daß man auf p-Dimethylanilinarsenoxyd Nitriersäure zur Einwirkung bringt und die so erhaltene Dinitromethylnitraminophenyl - ρ - arsinsäure mit Schwermetallen bzw. mit Schwermetallsalzen in saurer Lösung reduziert.A method of representation is provided by patent 285572 and its additional patent 286667 a bismethylaminotetraminoarsenobenzene protected, which consists in that one brings nitrating acid to action on p-dimethylanilinarene oxide and the resulting dinitromethylnitraminophenyl - ρ - arsic acid reduced with heavy metals or with heavy metal salts in acidic solution.
In der ersten Phase dieses Verfahrens wird die ajs Ausgangsstoff dienende aromatische Arsenverbindung mit dreiwertigem Arsen zur Arsinsäure oxydiert. Es ist nun, wie gefunden wurde, auch möglich, von jeder anderen Arsenverbindung des Dimethylanilins auszugehen, die der gleichen Oxydationsstufe angehört und bei der Einwirkung von Nitriersäure p-Dimethylanilinarsinsäure liefert, oder von der fertiggebildeten Arsinsäure selbst.In the first phase of this process, the ajs starting material is used aromatic Arsenic compound oxidized with trivalent arsenic to arsinic acid. It is now as found became possible to start from any other arsenic compound of dimethylaniline, which belongs to the same stage of oxidation and, when exposed to nitrating acid, p-dimethylanilinarsinic acid supplies, or from the finished arsic acid itself.
i. Nitrierung von p-Dimethylanilinarsenchlorür. i. Nitration of p-dimethylanilinarium chloride.
4 Teile p-Dimethylanilinarsenchlorür (Ann; d. Chem. 270 [1892], S. 141) werden in 40 Teilen konzentrierter Schwefelsäure gelöst, bei 0 bis io° mit einem Gemisch von je 6 Teilen kon-4 parts of p-dimethylanilinarium chloride (Ann; d. Chem. 270 [1892], p. 141) are in 40 parts concentrated sulfuric acid, at 0 to 10 ° with a mixture of 6 parts each
zentrierter Schwefelsäure und rauchender Salpetersäure versetzt und unter Rühren 5 Stunden auf 40 bis 50 ° erwärmt. Nach dem Erkalten gießt man auf etwa 100 Teile Eis und saugt die abgeschiedene Dinitromethylnitraminophenyl-p-arsinsäure ab. Sie wird mit Wasser gut abgewaschen, getrocknet und nach den im Hauptpatent bzw. dessen Zusatzpatent 286667 beschriebenen Verfahren weiterbehandelt.centered sulfuric acid and fuming nitric acid added and heated to 40 to 50 ° with stirring for 5 hours. After cooling down it is poured onto about 100 parts of ice and the separated dinitromethylnitraminophenyl-p-arsic acid is sucked away. It is washed off well with water, dried and according to the main patent or its additional patent 286667 described method further treated.
2. Nitrierung von p-Dimethylanilinarsinsäure.2. Nitration of p-dimethylanilinarsinic acid.
4 Teile p-Dimethylanilinarsinsäure (vgl. Patentschrift 200065, Kl.i2q) werden in 40 Teilen konzentrierter Schwefelsäure gelöst und wie im Beispiel 1 mit 12 Teilen Nitriersäure nitriert.4 parts of p-dimethylanilinarsinic acid (see patent specification 200065, class i2q) are in 40 parts Dissolved concentrated sulfuric acid and nitrated as in Example 1 with 12 parts of nitrating acid.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE286667T |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE293842C true DE293842C (en) | 1916-08-25 |
Family
ID=6059109
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT293842D Expired DE293842C (en) | |||
| DENDAT286668D Expired DE286668C (en) | |||
| DENDAT294731D Expired DE294731C (en) | |||
| DENDAT286667D Expired DE286667C (en) | |||
| DENDAT285572D Expired DE285572C (en) |
Family Applications After (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT286668D Expired DE286668C (en) | |||
| DENDAT294731D Expired DE294731C (en) | |||
| DENDAT286667D Expired DE286667C (en) | |||
| DENDAT285572D Expired DE285572C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (5) | DE285572C (en) |
-
0
- DE DENDAT293842D patent/DE293842C/de not_active Expired
- DE DENDAT286668D patent/DE286668C/de not_active Expired
- DE DENDAT294731D patent/DE294731C/de not_active Expired
- DE DENDAT286667D patent/DE286667C/de not_active Expired
- DE DENDAT285572D patent/DE285572C/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE286667C (en) | 1915-08-24 |
| DE294731C (en) | 1916-10-17 |
| DE286668C (en) | 1915-08-25 |
| DE285572C (en) | 1900-01-01 |
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