DE2816823C2 - Verwendung von Diacrylsäure- oder Dimethacrylsäureester zur Herstellung von polymerisierbaren Dentalmassen - Google Patents
Verwendung von Diacrylsäure- oder Dimethacrylsäureester zur Herstellung von polymerisierbaren DentalmassenInfo
- Publication number
- DE2816823C2 DE2816823C2 DE2816823A DE2816823A DE2816823C2 DE 2816823 C2 DE2816823 C2 DE 2816823C2 DE 2816823 A DE2816823 A DE 2816823A DE 2816823 A DE2816823 A DE 2816823A DE 2816823 C2 DE2816823 C2 DE 2816823C2
- Authority
- DE
- Germany
- Prior art keywords
- acid esters
- tooth
- polymerization
- bis
- dimethacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002148 esters Chemical class 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000002253 acid Substances 0.000 title claims description 11
- 125000004386 diacrylate group Chemical group 0.000 title claims description 8
- 239000005548 dental material Substances 0.000 title claims description 4
- 230000001588 bifunctional effect Effects 0.000 claims description 13
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 3
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 238000005299 abrasion Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 238000011049 filling Methods 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- -1 methylene acrylate radical Chemical class 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 239000010453 quartz Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 239000000178 monomer Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 125000005395 methacrylic acid group Chemical group 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 4
- 244000028419 Styrax benzoin Species 0.000 description 4
- 235000000126 Styrax benzoin Nutrition 0.000 description 4
- 235000008411 Sumatra benzointree Nutrition 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 235000019382 gum benzoic Nutrition 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 239000002685 polymerization catalyst Substances 0.000 description 4
- OXYKVVLTXXXVRT-UHFFFAOYSA-N (4-chlorobenzoyl) 4-chlorobenzenecarboperoxoate Chemical compound C1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1 OXYKVVLTXXXVRT-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229960002130 benzoin Drugs 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 150000008366 benzophenones Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 239000012230 colorless oil Substances 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 208000002925 dental caries Diseases 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- JMYZLRSSLFFUQN-UHFFFAOYSA-N (2-chlorobenzoyl) 2-chlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1Cl JMYZLRSSLFFUQN-UHFFFAOYSA-N 0.000 description 1
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- OGBWMWKMTUSNKE-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CCCCCC(OC(=O)C(C)=C)OC(=O)C(C)=C OGBWMWKMTUSNKE-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- JUVSRZCUMWZBFK-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-methylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1 JUVSRZCUMWZBFK-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910003930 SiCb Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000007656 barbituric acids Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical class C* 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical class C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000000030 silines Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003455 sulfinic acids Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dental Preparations (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH482377A CH629664A5 (en) | 1977-04-19 | 1977-04-19 | Polymerisable composition for dental purposes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2816823A1 DE2816823A1 (de) | 1978-10-26 |
| DE2816823C2 true DE2816823C2 (de) | 1982-04-29 |
Family
ID=4283163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2816823A Expired DE2816823C2 (de) | 1977-04-19 | 1978-04-18 | Verwendung von Diacrylsäure- oder Dimethacrylsäureester zur Herstellung von polymerisierbaren Dentalmassen |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS53130896A (en, 2012) |
| AT (1) | AT355728B (en, 2012) |
| BE (1) | BE866091A (en, 2012) |
| CA (1) | CA1109597A (en, 2012) |
| CH (1) | CH629664A5 (en, 2012) |
| DD (1) | DD135995A5 (en, 2012) |
| DE (1) | DE2816823C2 (en, 2012) |
| FR (1) | FR2387646A1 (en, 2012) |
| GB (1) | GB1576080A (en, 2012) |
| NL (1) | NL182049C (en, 2012) |
| SE (1) | SE436684B (en, 2012) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7141616B2 (en) | 1999-12-17 | 2006-11-28 | 3M Espe Ag | Radically curable urethane prepolymers and their use in dental materials |
| WO2011039243A1 (de) | 2009-09-29 | 2011-04-07 | Christa Hillebrand | Korrekturverfahren für hand- oder fussnägel |
| DE102010035856A1 (de) | 2010-08-30 | 2012-03-01 | Heraeus Kulzer Gmbh | Molkekulardispers verteilter Octenidinwirkstoff in Dentalmaterial |
| DE102010046697A1 (de) | 2010-09-28 | 2012-03-29 | Kettenbach Gmbh & Co. Kg | Polymerisierbares Dentalmaterial mit Reaktiv-Pastenbildner, gehärtetes Dentalmaterial und deren Verwendung |
| EP2436366A2 (de) | 2010-09-30 | 2012-04-04 | VOCO GmbH | Kompositmaterial umfassend ein Monomer mit einem polyalicyclischen Strukturelement als Versiegelungsmaterial |
| WO2014033280A2 (de) | 2012-08-31 | 2014-03-06 | Kettenbach Gmbh & Co. Kg | Radikalisch polymerisierbares dentalmaterial, gehärtetes produkt und verwendung |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2931925A1 (de) * | 1979-08-07 | 1981-02-26 | Bayer Ag | (meth)acrylsaeureester von ethergruppen enthaltenden tricyclischen decandiolen |
| USRE35264E (en) * | 1981-05-04 | 1996-06-04 | Dentsply Research & Development Corp. | Dental adhesive system |
| US4375966A (en) * | 1981-08-24 | 1983-03-08 | Sybron Corporation | System for making direct oral impression tray |
| US4674980A (en) * | 1982-05-03 | 1987-06-23 | Den-Mat, Inc. | Dental composite and porcelain repair |
| DE3522006A1 (de) * | 1985-06-20 | 1987-01-02 | Bayer Ag | (meth)-acrylsaeure-derivate von tricyclodecanen und ihre verwendung |
| DE3522005A1 (de) * | 1985-06-20 | 1987-01-02 | Bayer Ag | (meth)-acrylsaeureester und ihre verwendung |
| DE3607331A1 (de) * | 1986-03-06 | 1987-09-10 | Espe Pharm Praep | (meth)acrylsaeureester und ihre verwendung zur herstellung von dentalmassen |
| DE3609038A1 (de) * | 1986-03-18 | 1987-09-24 | Espe Stiftung | Roentgenopake polymerisierbare dentalmassen |
| WO1988005651A1 (en) * | 1987-02-04 | 1988-08-11 | Dental Composite Ltd. | Radiopaque glass ionomer cement liner for dental cavities |
| DE3708618A1 (de) * | 1987-03-17 | 1988-09-29 | Kulzer & Co Gmbh | Kunststoff-zahnersatzteil |
| DE3837569A1 (de) * | 1988-11-04 | 1990-05-10 | Espe Stiftung | Mit sichtbarem licht aushaertbare dentalmassen |
| JPH0733404B2 (ja) * | 1989-10-11 | 1995-04-12 | 三洋化成工業株式会社 | 成形用組成物および成形体の製造法 |
| DE4032505A1 (de) * | 1990-10-12 | 1991-08-14 | Thera Ges Fuer Patente | Verwendung von composite-fuellmaterialien zur befestigung von inlays, onlays, verblendschalen und dergleichen mittels hochfrequenter vibrationen |
| DE19502751A1 (de) * | 1995-01-23 | 1996-08-08 | Ivoclar Ag | Verfahren zur Herstellung von Modellen für die Zahntechnik |
| DE10058830B4 (de) | 2000-11-27 | 2005-01-27 | 3M Espe Ag | Verwendung von verzweigten Polysäuren in Dentalmassen und Dentalmassen enthaltend verzweigte Polysäuren |
| DE10107985C1 (de) | 2001-02-19 | 2002-04-18 | 3M Espe Ag | Polymerisierbare Zubereitungen auf der Basis von Siliziumverbindungen mit aliphatischen und cycloaliphatischen Epoxidgruppen und deren Verwendung |
| DE10124028B4 (de) | 2001-05-16 | 2010-02-18 | 3M Espe Ag | Selbstadhäsive Dentalmaterialien |
| US8084514B2 (en) * | 2005-05-13 | 2011-12-27 | E. I. Du Pont De Nemours And Company | Materials leading to improved dental composites and dental composites made therefrom |
| DE102007034457A1 (de) * | 2007-07-20 | 2009-01-22 | Heraeus Kulzer Gmbh | Dentalkomposite mit niedriger Schrumpfspannung und hoher Biegefestigkeit |
| WO2011034780A1 (en) | 2009-09-15 | 2011-03-24 | 3M Innovative Properties Company | Dental implant abutments and methods of use |
| EP2436365B1 (de) | 2010-09-30 | 2017-03-08 | VOCO GmbH | Kompositmaterial umfassend ein Monomer mit einem polyalicyclischen Strukturelement |
| EP2436363B1 (de) | 2010-09-30 | 2017-01-18 | VOCO GmbH | Zusammensetzung umfassend ein Monomer mit einem polyalicyclischen Strukturelement zum Füllen und/oder Versiegeln eines Wurzelkanals |
| DE102012001978A1 (de) * | 2012-02-02 | 2013-08-08 | Voco Gmbh | Dentale Kompositmaterialien enthaltend tricyclische Weichmacher |
| DE102013008176A1 (de) | 2012-10-05 | 2014-04-10 | Voco Gmbh | Kit und Verfahren zur indirekten chairside Herstellung von Kompositinlays |
| EP3338756B1 (de) | 2016-12-21 | 2020-02-26 | VOCO GmbH | Lagerstabiler kunststoffmodifizierter glasionomerzement |
| DE102018114690A1 (de) | 2018-06-19 | 2019-12-19 | Voco Gmbh | Thermowirksame dentale Kompositzusammensetzung |
| DE102021113969A1 (de) | 2021-05-31 | 2022-12-01 | Mühlbauer Technology Gmbh | Monomermischung zur Herstellung eines Dentalmaterials |
| DE102022116577A1 (de) | 2022-07-04 | 2024-01-04 | Mühlbauer Technology Gmbh | Monomermischung zur Herstellung eines Dentalmaterials |
| DE102023111186A1 (de) | 2023-05-02 | 2024-11-07 | Mühlbauer Technology Gmbh | Radikalisch polymerisierbare Verbindung und Zusammensetzung |
| DE102023135732A1 (de) | 2023-12-19 | 2025-06-26 | Mühlbauer Technology Gmbh | Radikalisch polymerisierbare Verbindung und Zusammensetzung |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH557674A (de) * | 1968-05-15 | 1975-01-15 | Espe Pharm Praep | Material zur herstellung von zahnfuellungen und zahnersatzteilen. |
-
1977
- 1977-04-19 CH CH482377A patent/CH629664A5/de not_active IP Right Cessation
-
1978
- 1978-04-18 FR FR7811389A patent/FR2387646A1/fr active Granted
- 1978-04-18 DD DD78204856A patent/DD135995A5/xx unknown
- 1978-04-18 SE SE7804386A patent/SE436684B/sv not_active IP Right Cessation
- 1978-04-18 DE DE2816823A patent/DE2816823C2/de not_active Expired
- 1978-04-18 NL NLAANVRAGE7804096,A patent/NL182049C/xx not_active IP Right Cessation
- 1978-04-18 AT AT273278A patent/AT355728B/de not_active IP Right Cessation
- 1978-04-18 JP JP4620278A patent/JPS53130896A/ja active Granted
- 1978-04-18 BE BE186873A patent/BE866091A/xx not_active IP Right Cessation
- 1978-04-18 GB GB15266/78A patent/GB1576080A/en not_active Expired
- 1978-04-18 CA CA301,369A patent/CA1109597A/en not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7141616B2 (en) | 1999-12-17 | 2006-11-28 | 3M Espe Ag | Radically curable urethane prepolymers and their use in dental materials |
| WO2011039243A1 (de) | 2009-09-29 | 2011-04-07 | Christa Hillebrand | Korrekturverfahren für hand- oder fussnägel |
| DE102009043355A1 (de) | 2009-09-29 | 2011-04-07 | Christa Hillebrand | Korrekturverfahren für Hand- oder Fußnägel |
| DE102010035856A1 (de) | 2010-08-30 | 2012-03-01 | Heraeus Kulzer Gmbh | Molkekulardispers verteilter Octenidinwirkstoff in Dentalmaterial |
| DE102010046697A1 (de) | 2010-09-28 | 2012-03-29 | Kettenbach Gmbh & Co. Kg | Polymerisierbares Dentalmaterial mit Reaktiv-Pastenbildner, gehärtetes Dentalmaterial und deren Verwendung |
| WO2012052249A2 (de) | 2010-09-28 | 2012-04-26 | Kettenbach Gmbh & Co. Kg | Polymerisierbares dentalmaterial mit reaktiv-pastenbildner, gehärtetes dentalmaterial und deren verwendung |
| EP2436366A2 (de) | 2010-09-30 | 2012-04-04 | VOCO GmbH | Kompositmaterial umfassend ein Monomer mit einem polyalicyclischen Strukturelement als Versiegelungsmaterial |
| WO2014033280A2 (de) | 2012-08-31 | 2014-03-06 | Kettenbach Gmbh & Co. Kg | Radikalisch polymerisierbares dentalmaterial, gehärtetes produkt und verwendung |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS53130896A (en) | 1978-11-15 |
| CA1109597A (en) | 1981-09-22 |
| NL182049B (nl) | 1987-08-03 |
| GB1576080A (en) | 1980-10-01 |
| FR2387646B1 (en, 2012) | 1984-08-10 |
| NL182049C (nl) | 1988-01-04 |
| AT355728B (de) | 1980-03-25 |
| BE866091A (fr) | 1978-08-14 |
| JPS631281B2 (en, 2012) | 1988-01-12 |
| DD135995A5 (de) | 1979-06-13 |
| SE7804386L (sv) | 1978-10-20 |
| CH629664A5 (en) | 1982-05-14 |
| FR2387646A1 (fr) | 1978-11-17 |
| NL7804096A (nl) | 1978-10-23 |
| SE436684B (sv) | 1985-01-21 |
| DE2816823A1 (de) | 1978-10-26 |
| ATA273278A (de) | 1979-08-15 |
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