DE2750007A1 - Verfahren zur herstellung von kohlenwasserstoffen durch umsetzen von kohlenmonoxid mit wasserstoff an einem katalysator - Google Patents

Verfahren zur herstellung von kohlenwasserstoffen durch umsetzen von kohlenmonoxid mit wasserstoff an einem katalysator

Info

Publication number
DE2750007A1
DE2750007A1 DE19772750007 DE2750007A DE2750007A1 DE 2750007 A1 DE2750007 A1 DE 2750007A1 DE 19772750007 DE19772750007 DE 19772750007 DE 2750007 A DE2750007 A DE 2750007A DE 2750007 A1 DE2750007 A1 DE 2750007A1
Authority
DE
Germany
Prior art keywords
catalyst
weight
iron
catalysts
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19772750007
Other languages
German (de)
English (en)
Other versions
DE2750007C2 (fr
Inventor
Henricus Michael Jose Bijwaard
Swan Tiong Sie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of DE2750007A1 publication Critical patent/DE2750007A1/de
Application granted granted Critical
Publication of DE2750007C2 publication Critical patent/DE2750007C2/de
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/045—Regeneration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE19772750007 1976-11-10 1977-11-08 Verfahren zur herstellung von kohlenwasserstoffen durch umsetzen von kohlenmonoxid mit wasserstoff an einem katalysator Granted DE2750007A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7612460A NL7612460A (nl) 1976-11-10 1976-11-10 Werkwijze voor de bereiding van koolwater- stoffen.

Publications (2)

Publication Number Publication Date
DE2750007A1 true DE2750007A1 (de) 1978-05-18
DE2750007C2 DE2750007C2 (fr) 1987-08-27

Family

ID=19827203

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19772750007 Granted DE2750007A1 (de) 1976-11-10 1977-11-08 Verfahren zur herstellung von kohlenwasserstoffen durch umsetzen von kohlenmonoxid mit wasserstoff an einem katalysator

Country Status (11)

Country Link
JP (1) JPS5359604A (fr)
AU (1) AU513157B2 (fr)
BE (1) BE860395A (fr)
CA (1) CA1089495A (fr)
DE (1) DE2750007A1 (fr)
FR (1) FR2370712B1 (fr)
GB (1) GB1548468A (fr)
IN (1) IN147159B (fr)
IT (1) IT1087492B (fr)
NL (1) NL7612460A (fr)
ZA (1) ZA776649B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3026175A1 (de) * 1979-07-13 1981-01-29 Shell Int Research Verfahren zur herstellung von fischer-tropsch-katalysatoren und deren verwendung
WO1986007350A1 (fr) * 1985-06-15 1986-12-18 The British Petroleum Company P.L.C. Catalyseur de conversion d'un gaz de synthese, production et utilisations dudit catalyseur

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL190574C (nl) * 1979-07-13 1994-05-02 Shell Int Research Werkwijze voor de bereiding van ijzermagnesium katalysatoren en de toepassing daarvan bij de bereiding van koolwaterstoffen.
DK144602C (da) * 1979-12-18 1982-09-27 Haldor Topsoe As Fremgangsmaade til fremstilling af en gasblanding med hoejt indhold af c2-kulbrinter
NL8003313A (nl) * 1980-06-06 1982-01-04 Shell Int Research Werkwijze voor de bereiding van middeldestillaten.
US4605676A (en) * 1981-10-13 1986-08-12 Chevron Research Company Synthesis gas conversion using ROR-activated catalyst
US4613624A (en) * 1981-10-13 1986-09-23 Chevron Research Company Conversion of synthesis gas to diesel fuel and catalyst therefor
US4605679A (en) * 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
ATE21340T1 (de) * 1982-11-22 1986-08-15 Shell Int Research Verfahren zur herstellung eines fischer-tropsch- katalysators, der auf diese weise hergestellte katalysator und seine verwendung zur herstellung von kohlenwasserstoffen.
JPS6023330A (ja) * 1983-07-15 1985-02-05 Daido Sanso Kk 炭化水素の製造方法
CA1234158A (fr) * 1983-11-15 1988-03-15 Johannes K. Minderhoud Preparation des hydrocarbures
CA1240708A (fr) * 1983-11-15 1988-08-16 Johannes K. Minderhoud Preparation d'hydrocarbures
GB2169614A (en) * 1984-12-31 1986-07-16 Mobil Oil Corp Producing alpha-olefins and their conversion into lubricants
IN166813B (fr) * 1985-01-18 1990-07-21 Shell Int Research
US4717702A (en) * 1985-04-26 1988-01-05 Shell Internationale Research Maatschappij Bv Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst
GB8623233D0 (en) * 1986-09-26 1986-10-29 British Petroleum Co Plc Syngas conversion catalyst
GB9010076D0 (en) * 1990-05-04 1990-06-27 Shell Int Research Process for the conversion of methanol into liquid hydrocarbons
FR2694013B1 (fr) * 1992-07-27 1994-09-30 Inst Francais Du Petrole Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures.
JP2007181755A (ja) * 2006-01-05 2007-07-19 Nippon Gas Gosei Kk 液化石油ガス製造用触媒、および、この触媒を用いた液化石油ガスの製造方法
JP2010116328A (ja) * 2008-11-11 2010-05-27 Nippon Oil Corp 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法
TWI473652B (zh) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
CN103949262A (zh) * 2014-04-21 2014-07-30 武汉凯迪工程技术研究总院有限公司 一种用于合成气生产α-烯烃的结构化铁基催化剂及制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE881497C (de) * 1951-10-09 1953-06-29 Ruhrchemie Ag Eisenkatalysator fuer die Kohlenoxydhydrierung mit hohem Gehalt an benzinartigen Kohlenwasserstoffen
DE919288C (de) * 1949-09-13 1954-10-18 Ruhrchemie Ag Verfahren zur Herstellung von Eisenkatalysatoren, die fuer die insbesondere unter hoher Gasbelastung durchgefuehrte katalytische Kohlenoxydhydrierung geeignet sind

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE919288C (de) * 1949-09-13 1954-10-18 Ruhrchemie Ag Verfahren zur Herstellung von Eisenkatalysatoren, die fuer die insbesondere unter hoher Gasbelastung durchgefuehrte katalytische Kohlenoxydhydrierung geeignet sind
DE881497C (de) * 1951-10-09 1953-06-29 Ruhrchemie Ag Eisenkatalysator fuer die Kohlenoxydhydrierung mit hohem Gehalt an benzinartigen Kohlenwasserstoffen

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3026175A1 (de) * 1979-07-13 1981-01-29 Shell Int Research Verfahren zur herstellung von fischer-tropsch-katalysatoren und deren verwendung
WO1986007350A1 (fr) * 1985-06-15 1986-12-18 The British Petroleum Company P.L.C. Catalyseur de conversion d'un gaz de synthese, production et utilisations dudit catalyseur
EP0209980A1 (fr) * 1985-06-15 1987-01-28 The British Petroleum Company p.l.c. Conversion du gaz de synthèse
JPS62503100A (ja) * 1985-06-15 1987-12-10 ザ　ブリテイツシユ　ピトロ−リアム　カンパニ−　ピ−エルシ− 合成ガス変換触媒、その製造およびそれらの使用

Also Published As

Publication number Publication date
AU2970877A (en) 1979-04-26
FR2370712A1 (fr) 1978-06-09
NL7612460A (nl) 1978-05-12
JPS6337090B2 (fr) 1988-07-22
GB1548468A (en) 1979-07-18
DE2750007C2 (fr) 1987-08-27
JPS5359604A (en) 1978-05-29
IN147159B (fr) 1979-12-01
CA1089495A (fr) 1980-11-11
AU513157B2 (en) 1980-11-20
FR2370712B1 (fr) 1980-10-10
IT1087492B (it) 1985-06-04
ZA776649B (en) 1978-08-30
BE860395A (nl) 1978-05-03

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