DE2744185C3 - Verfahren zur dauerhaften Fixierung eines vernetzten Polydiorganosiloxans auf der Oberfläche von Polyamid- oder Polyesterfasern und/bzw. oder Cellulosefaser - Google Patents
Verfahren zur dauerhaften Fixierung eines vernetzten Polydiorganosiloxans auf der Oberfläche von Polyamid- oder Polyesterfasern und/bzw. oder CellulosefaserInfo
- Publication number
- DE2744185C3 DE2744185C3 DE2744185A DE2744185A DE2744185C3 DE 2744185 C3 DE2744185 C3 DE 2744185C3 DE 2744185 A DE2744185 A DE 2744185A DE 2744185 A DE2744185 A DE 2744185A DE 2744185 C3 DE2744185 C3 DE 2744185C3
- Authority
- DE
- Germany
- Prior art keywords
- polydiorganosiloxane
- groups
- fibers
- siloxane units
- crosslinked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 title claims description 53
- 238000000034 method Methods 0.000 title claims description 42
- 230000008569 process Effects 0.000 title claims description 19
- 229920003043 Cellulose fiber Polymers 0.000 title claims description 7
- 229920000728 polyester Polymers 0.000 title claims description 6
- 239000004952 Polyamide Substances 0.000 title claims description 4
- 229920002647 polyamide Polymers 0.000 title claims description 4
- -1 siloxane units Chemical group 0.000 claims description 63
- 239000007788 liquid Substances 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 239000004744 fabric Substances 0.000 description 26
- 238000002360 preparation method Methods 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 20
- 229920000139 polyethylene terephthalate Polymers 0.000 description 18
- 239000005020 polyethylene terephthalate Substances 0.000 description 18
- 239000000523 sample Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000007921 spray Substances 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- 239000004753 textile Substances 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000013068 control sample Substances 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 5
- 101150065749 Churc1 gene Proteins 0.000 description 5
- 102100038239 Protein Churchill Human genes 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 229920001558 organosilicon polymer Polymers 0.000 description 5
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000033228 biological regulation Effects 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 238000005108 dry cleaning Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 125000000962 organic group Chemical group 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920006037 cross link polymer Polymers 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 125000005358 mercaptoalkyl group Chemical group 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 229920005594 polymer fiber Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000011867 re-evaluation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000008237 rinsing water Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000004584 weight gain Effects 0.000 description 2
- 235000019786 weight gain Nutrition 0.000 description 2
- WACNXHCZHTVBJM-UHFFFAOYSA-N 1,2,3,4,5-pentafluorobenzene Chemical compound FC1=CC(F)=C(F)C(F)=C1F WACNXHCZHTVBJM-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920002821 Modacrylic Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910020489 SiO3 Inorganic materials 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2352—Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72949876A | 1976-10-04 | 1976-10-04 | |
| US05/822,474 US4311760A (en) | 1976-10-04 | 1977-08-08 | Method for applying mercaptoalkyl-containing polydiorganosiloxanes to textile fibers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2744185A1 DE2744185A1 (de) | 1978-04-06 |
| DE2744185B2 DE2744185B2 (de) | 1980-09-18 |
| DE2744185C3 true DE2744185C3 (de) | 1982-03-04 |
Family
ID=27111896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2744185A Expired DE2744185C3 (de) | 1976-10-04 | 1977-09-30 | Verfahren zur dauerhaften Fixierung eines vernetzten Polydiorganosiloxans auf der Oberfläche von Polyamid- oder Polyesterfasern und/bzw. oder Cellulosefaser |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4311760A (OSRAM) |
| JP (1) | JPS5345497A (OSRAM) |
| CA (1) | CA1106111A (OSRAM) |
| DE (1) | DE2744185C3 (OSRAM) |
| FR (1) | FR2366400A1 (OSRAM) |
| GB (1) | GB1588139A (OSRAM) |
| IT (1) | IT1088057B (OSRAM) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2922376C2 (de) * | 1979-06-01 | 1983-12-08 | Chemische Fabrik Pfersee Gmbh, 8900 Augsburg | Verfahren und Mittel zum Weichmachen von Textilmaterial |
| DE3034380A1 (de) * | 1980-09-12 | 1982-03-25 | Th. Goldschmidt Ag, 4300 Essen | Zubereitung zum schrumpffestmachen von wolle |
| DE3108595A1 (de) * | 1981-03-06 | 1982-09-16 | Wacker-Chemie GmbH, 8000 München | Verfahren zur beschichtung von unterlagen |
| SE455466C (sv) * | 1986-03-10 | 1993-07-05 | Moelnlycke Ab | Foerband foer vaetskande saar |
| US5846604A (en) * | 1988-03-14 | 1998-12-08 | Nextec Applications, Inc. | Controlling the porosity and permeation of a web |
| US5856245A (en) * | 1988-03-14 | 1999-01-05 | Nextec Applications, Inc. | Articles of barrier webs |
| US5698303A (en) * | 1988-03-14 | 1997-12-16 | Nextec Applications, Inc. | Controlling the porosity and permeation of a web |
| US6040251A (en) * | 1988-03-14 | 2000-03-21 | Nextec Applications Inc. | Garments of barrier webs |
| US5912116A (en) * | 1988-03-14 | 1999-06-15 | Nextec Applications, Inc. | Methods of measuring analytes with barrier webs |
| US6312523B1 (en) | 1988-03-14 | 2001-11-06 | Nextec Applications, Inc. | Apparatus of feedback control for the placement of a polymer composition into a web |
| US5874164A (en) * | 1988-03-14 | 1999-02-23 | Nextec Applications, Inc. | Barrier webs having bioactive surfaces |
| US5876792A (en) * | 1988-03-14 | 1999-03-02 | Nextec Applications, Inc. | Methods and apparatus for controlled placement of a polymer composition into a web |
| US5954902A (en) * | 1988-03-14 | 1999-09-21 | Nextec Applications, Inc. | Controlling the porosity and permeation of a web |
| US6083602A (en) * | 1988-03-14 | 2000-07-04 | Nextec Applications, Inc. | Incontinent garments |
| US5958137A (en) * | 1989-03-10 | 1999-09-28 | Nextec Applications, Inc. | Apparatus of feedback control for the placement of a polymer composition into a web |
| US5935637A (en) * | 1989-03-10 | 1999-08-10 | Nextec Applications, Inc. | Method of feedback control for the placement of a polymer composition into a web |
| US5089598A (en) * | 1990-10-05 | 1992-02-18 | General Electric Company | Endcapped, chain-extended and branched polyesters |
| US5358747A (en) * | 1992-12-28 | 1994-10-25 | Aluminum Company Of America | Siloxane coating process for carbon or graphite substrates |
| US5492730A (en) * | 1992-12-28 | 1996-02-20 | Aluminum Company Of America | Siloxane coating process for metal or ceramic substrates |
| US6071602A (en) * | 1995-06-07 | 2000-06-06 | Nextec Applications, Inc. | Controlling the porosity and permeation of a web |
| US6688607B2 (en) * | 1997-04-18 | 2004-02-10 | Henkel Loctite Corporation | Material for sealing threaded pipe joints, and dispenser therefor |
| GB0030177D0 (en) * | 2000-12-11 | 2001-01-24 | Unilever Plc | Textile care composition |
| US20080235879A1 (en) * | 2007-03-28 | 2008-10-02 | Ecolab Inc. | Method of producing substantially wrinkle-free textile surfaces |
| EP2770015B1 (en) | 2013-02-26 | 2018-03-28 | Armacell Enterprise GmbH & Co. KG | Upgrading polyester wastes with silanes and their blends |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2464231A (en) * | 1945-06-18 | 1949-03-15 | Continental Oil Co | Method for preparing pentamethylene silicone polymers |
| US2719165A (en) * | 1953-04-15 | 1955-09-27 | Gen Electric | Triorganosilylmethyl sulfur derivatives |
| US3078292A (en) * | 1958-05-13 | 1963-02-19 | Gen Electric | Hydrolyzable silyl thioethers |
| DE1163818B (de) * | 1962-05-05 | 1964-02-27 | Goldschmidt Ag Th | Verfahren zur Herstellung von ªÏ-mercaptoalkylgruppenhaltigen Organosiliciumverbindungen |
| GB1052009A (OSRAM) * | 1964-07-30 | |||
| NL127712C (OSRAM) * | 1964-12-21 | |||
| NL133796C (OSRAM) * | 1965-01-21 | 1900-01-01 | ||
| DE1570567A1 (de) * | 1965-05-14 | 1969-07-31 | Bayer Ag | Verfahren zur Herstellung mercaptomethylsubstituierter Organopolysiloxane |
| US3382196A (en) * | 1965-06-03 | 1968-05-07 | Dow Corning | Organic rubbers with mercaptoorganosiloxanes having improved elongation |
| CH615968D (OSRAM) * | 1967-04-26 | 1900-01-01 | ||
| US3637427A (en) * | 1968-01-13 | 1972-01-25 | Nippon Rayon Kk | Process for imparting high-elastic recovery to extensible knitted or woven fabrics and product obtained |
| US3694480A (en) * | 1968-06-11 | 1972-09-26 | Union Carbide Corp | Novel organofunctional silicon compounds substituted with halogen and processes for making same |
| US3655713A (en) * | 1970-07-13 | 1972-04-11 | Dow Corning | Silacyclopentane thiols and thiolates |
| DE2405717B2 (de) * | 1974-02-06 | 1980-04-24 | Wacker-Chemie Gmbh, 8000 Muenchen | Verfahren zur Erhöhung der Gleitfähigkeit und zum Antielektrostatischmachen von organischen Fasern |
-
1977
- 1977-08-08 US US05/822,474 patent/US4311760A/en not_active Expired - Lifetime
- 1977-09-19 CA CA287,031A patent/CA1106111A/en not_active Expired
- 1977-09-20 GB GB39121/77A patent/GB1588139A/en not_active Expired
- 1977-09-30 DE DE2744185A patent/DE2744185C3/de not_active Expired
- 1977-10-03 IT IT2821577A patent/IT1088057B/it active
- 1977-10-03 JP JP11889777A patent/JPS5345497A/ja active Granted
- 1977-10-03 FR FR7729659A patent/FR2366400A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2744185A1 (de) | 1978-04-06 |
| JPS5345497A (en) | 1978-04-24 |
| JPS5629031B2 (OSRAM) | 1981-07-06 |
| IT1088057B (it) | 1985-06-04 |
| US4311760A (en) | 1982-01-19 |
| FR2366400A1 (fr) | 1978-04-28 |
| CA1106111A (en) | 1981-08-04 |
| DE2744185B2 (de) | 1980-09-18 |
| FR2366400B1 (OSRAM) | 1980-01-18 |
| GB1588139A (en) | 1981-04-15 |
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