DE2621941C3 - Verfahren zur Herstellung von Kohle und Kohlenwasserstoffdämpfen aus Gummi durch thermische Zersetzung - Google Patents
Verfahren zur Herstellung von Kohle und Kohlenwasserstoffdämpfen aus Gummi durch thermische ZersetzungInfo
- Publication number
- DE2621941C3 DE2621941C3 DE2621941A DE2621941A DE2621941C3 DE 2621941 C3 DE2621941 C3 DE 2621941C3 DE 2621941 A DE2621941 A DE 2621941A DE 2621941 A DE2621941 A DE 2621941A DE 2621941 C3 DE2621941 C3 DE 2621941C3
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- pyrolysis
- coal
- heat transfer
- hydrocarbon vapors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 title claims description 48
- 239000005060 rubber Substances 0.000 title claims description 48
- 239000003245 coal Substances 0.000 title claims description 21
- 229930195733 hydrocarbon Natural products 0.000 title claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 12
- 238000005979 thermal decomposition reaction Methods 0.000 title claims 2
- 238000000197 pyrolysis Methods 0.000 claims description 27
- 239000006229 carbon black Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000003365 glass fiber Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 239000002699 waste material Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000011152 fibreglass Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- 229920003051 synthetic elastomer Polymers 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000005061 synthetic rubber Substances 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- -1 Steel Chemical class 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/482—Preparation from used rubber products, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US57833875A | 1975-05-16 | 1975-05-16 | |
| US05/604,874 US4038100A (en) | 1975-05-16 | 1975-08-14 | Char composition and a method for making a char composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2621941A1 DE2621941A1 (de) | 1976-11-25 |
| DE2621941B2 DE2621941B2 (de) | 1978-08-31 |
| DE2621941C3 true DE2621941C3 (de) | 1979-04-26 |
Family
ID=27077475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2621941A Expired DE2621941C3 (de) | 1975-05-16 | 1976-05-17 | Verfahren zur Herstellung von Kohle und Kohlenwasserstoffdämpfen aus Gummi durch thermische Zersetzung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4038100A (enExample) |
| JP (1) | JPS51142083A (enExample) |
| CA (1) | CA1070480A (enExample) |
| DE (1) | DE2621941C3 (enExample) |
| FR (1) | FR2310866A1 (enExample) |
| GB (1) | GB1494300A (enExample) |
| IT (1) | IT1061276B (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4284616A (en) * | 1978-02-15 | 1981-08-18 | Intenco, Inc. | Process for recovering carbon black and hydrocarbons from used tires |
| US4250158A (en) * | 1978-02-15 | 1981-02-10 | Intenco, Inc. | Process for recovering carbon black and hydrocarbons from used tires |
| US4231998A (en) * | 1978-08-31 | 1980-11-04 | Tosco Corporation | Method for separating carbon black from fiberglass |
| GB2073059B (en) * | 1980-04-01 | 1983-04-07 | Tosco Corp | Method and apparatus for separating carbon black from fibreglass |
| US4353752A (en) * | 1981-01-07 | 1982-10-12 | Lyakhevich Genrickh D | Method of making a suspension of a filler for rubber mixtures |
| YU42033B (en) * | 1982-03-05 | 1988-04-30 | Sava Kranj | Method for the continuous processing of crude waste rubber into a secondary rubber raw material |
| US4686007A (en) * | 1983-06-17 | 1987-08-11 | Belorussky Politekhnichesky Institut | Method of thermally decomposing polymeric material |
| US5037628A (en) * | 1987-08-14 | 1991-08-06 | American Tire Reclamation, Inc. | Method for reclaiming carbonaceous material from a waste material |
| US5157176A (en) * | 1990-07-26 | 1992-10-20 | Munger Joseph H | Recycling process, apparatus and product produced by such process for producing a rubber extender/plasticizing agent from used automobile rubber tires |
| US5230777A (en) * | 1991-12-13 | 1993-07-27 | James Jarrell | Apparatus for producing fuel and carbon black from rubber tires |
| US5427022A (en) * | 1992-10-27 | 1995-06-27 | American Tire Reclamation, Inc. | Apparatus for axial compression of tires having aligning member |
| GB2280451B (en) * | 1993-06-29 | 1998-01-28 | Leybold Durferrit Gmbh | Process for embrittling and crushing of plastics/rubber |
| DE4418562A1 (de) * | 1993-06-29 | 1995-01-12 | Leybold Durferrit Gmbh | Verfahren und Vorrichtung zur Behandlung von im wesentlichen aus Kunststoff oder Gummi bestehendem Gut |
| US5894012A (en) * | 1993-08-19 | 1999-04-13 | Gilbert W. Denison | Method and system for recovering marketable end products from waste rubber |
| US5783046A (en) | 1994-11-28 | 1998-07-21 | Gentech, Inc. | Process and apparatus for the destructive distillation of rubber |
| US6221329B1 (en) * | 1999-03-09 | 2001-04-24 | Svedala Industries, Inc. | Pyrolysis process for reclaiming desirable materials from vehicle tires |
| DE19945771C1 (de) * | 1999-09-24 | 2001-02-22 | Muehlen Gmbh & Co Kg Dr | Verfahren zur Vergasung von organischen Stoffen und Stoffgemischen |
| DE10055360B4 (de) * | 2000-11-08 | 2004-07-29 | Mühlen, Heinz-Jürgen, Dr.rer.Nat. | Verfahren zur Vergasung von flüssigen bis pastösen organischen Stoffen und Stoffgemischen |
| GB2406563A (en) * | 2003-10-03 | 2005-04-06 | Susan Claire Powell Wright | A method of refining carbon black char |
| JP4860162B2 (ja) * | 2005-02-14 | 2012-01-25 | 住友ゴム工業株式会社 | ゴム組成物およびそれからなるタイヤ |
| FR2945817B1 (fr) * | 2009-05-25 | 2013-09-27 | Francois Hustache | Nouveau dispositif pour la gazeification de dechets organiques, et procede de mise en oeuvre de ce dispositif |
| IN2012DN03077A (enExample) | 2009-10-14 | 2015-07-31 | Reklaim Inc | |
| JP5925195B2 (ja) | 2010-06-22 | 2016-05-25 | カーティン ユニバーシティ オブ テクノロジーＣｕｒｔｉｎ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｔｅｃｈｎｏｌｏｇｙ | 微粒子炭素質原料の破砕熱分解のための方法およびシステム |
| WO2021209276A1 (en) * | 2020-04-17 | 2021-10-21 | Nantek Hub S.L. | Pyrolysis process to obtain petrochemical products from plastic waste |
| US20220161461A1 (en) * | 2020-11-24 | 2022-05-26 | Mobile Biochar Solutions LLC | Windmill blade disposal and recycling system |
| EP4155367A1 (en) | 2021-09-23 | 2023-03-29 | Nantek Hub S.L. | Pyrolysis process activated by nanocarbon-based metal free reagents to obtain synthetic fuels from plastic waste |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442789A (en) * | 1966-10-26 | 1969-05-06 | Technikoil Inc | Shale oil recovery process |
| US3496094A (en) * | 1967-11-24 | 1970-02-17 | Oil Shale Corp | Apparatus and method for retorting solids |
| US3644131A (en) * | 1970-03-25 | 1972-02-22 | William W Gotshall | Reinforcing agent from scrap rubber char |
| US3691056A (en) * | 1971-04-13 | 1972-09-12 | Oil Shale Corp | Process for retorting oil shale in the absence of shale ash |
| US3823221A (en) * | 1972-03-20 | 1974-07-09 | Firestone Tire & Rubber Co | Production of a char reinforcing agent from pyrolyzed scrap rubber |
| US3823224A (en) * | 1972-03-20 | 1974-07-09 | Firestone Tire & Rubber Co | Production of a char reinforcing agent from pyrolyzed scrap-rubber |
| US3823223A (en) * | 1972-06-05 | 1974-07-09 | Firestone Tire & Rubber Co | Rubber-reinforcing agent |
| JPS5033912B2 (enExample) * | 1972-06-12 | 1975-11-04 | ||
| NL7210632A (enExample) * | 1972-08-03 | 1974-02-05 | ||
| JPS4934983A (enExample) * | 1972-08-05 | 1974-03-30 | ||
| JPS5140882B2 (enExample) * | 1973-01-05 | 1976-11-06 | ||
| US3875077A (en) * | 1973-03-28 | 1975-04-01 | Yasuhiro Sanga | Method of and apparatus for producing activated charcoal from waste tires |
-
1975
- 1975-08-14 US US05/604,874 patent/US4038100A/en not_active Expired - Lifetime
-
1976
- 1976-05-12 IT IT49440/76A patent/IT1061276B/it active
- 1976-05-13 FR FR7614486A patent/FR2310866A1/fr active Granted
- 1976-05-14 CA CA252,532A patent/CA1070480A/en not_active Expired
- 1976-05-14 GB GB20055/76A patent/GB1494300A/en not_active Expired
- 1976-05-15 JP JP51055991A patent/JPS51142083A/ja active Pending
- 1976-05-17 DE DE2621941A patent/DE2621941C3/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2310866B1 (enExample) | 1981-08-07 |
| IT1061276B (it) | 1983-02-28 |
| GB1494300A (en) | 1977-12-07 |
| DE2621941B2 (de) | 1978-08-31 |
| JPS51142083A (en) | 1976-12-07 |
| FR2310866A1 (fr) | 1976-12-10 |
| US4038100A (en) | 1977-07-26 |
| DE2621941A1 (de) | 1976-11-25 |
| CA1070480A (en) | 1980-01-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: TOSCO CORP. (EINE GES.N.D. GES.D. STAATES NEVADA), |
|
| 8339 | Ceased/non-payment of the annual fee |