DE2611542A1 - Fluessiges wasch- und reinigungsmittel - Google Patents
Fluessiges wasch- und reinigungsmittelInfo
- Publication number
- DE2611542A1 DE2611542A1 DE19762611542 DE2611542A DE2611542A1 DE 2611542 A1 DE2611542 A1 DE 2611542A1 DE 19762611542 DE19762611542 DE 19762611542 DE 2611542 A DE2611542 A DE 2611542A DE 2611542 A1 DE2611542 A1 DE 2611542A1
- Authority
- DE
- Germany
- Prior art keywords
- cleaning agent
- sulfinyl
- washing
- radicals
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims description 22
- 239000007788 liquid Substances 0.000 title claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 29
- UXDHDPFGSDSRPS-UHFFFAOYSA-N 3-(2-carboxyethylsulfinyl)propanoic acid Chemical compound OC(=O)CCS(=O)CCC(O)=O UXDHDPFGSDSRPS-UHFFFAOYSA-N 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 18
- 239000003352 sequestering agent Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 4
- 239000003752 hydrotrope Substances 0.000 claims description 3
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 20
- 239000008233 hard water Substances 0.000 description 13
- 159000000000 sodium salts Chemical class 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- 239000000344 soap Substances 0.000 description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- KASHINAHDSRLHE-UHFFFAOYSA-N C(CC)(=O)OS(=O)OC(CC)=O.[Na] Chemical compound C(CC)(=O)OS(=O)OC(CC)=O.[Na] KASHINAHDSRLHE-UHFFFAOYSA-N 0.000 description 5
- 229920000388 Polyphosphate Polymers 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000001205 polyphosphate Substances 0.000 description 5
- 235000011176 polyphosphates Nutrition 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 4
- -1 sulfinyl carboxylic acid Chemical class 0.000 description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 4
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 159000000007 calcium salts Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- IILQHMMTOSAJAR-UHFFFAOYSA-L disodium;2-(carboxylatomethoxy)acetate Chemical compound [Na+].[Na+].[O-]C(=O)COCC([O-])=O IILQHMMTOSAJAR-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- WKVMOQXBMPYPGK-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].OC(=O)CN(CC(O)=O)CC(O)=O WKVMOQXBMPYPGK-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000003490 Thiodipropionic acid Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- XHBBVSGBJWSGKN-UHFFFAOYSA-H hexasodium 2-[bis(carboxylatomethyl)amino]acetate Chemical compound N(CC(=O)[O-])(CC(=O)[O-])CC(=O)[O-].[Na+].[Na+].[Na+].N(CC(=O)[O-])(CC(=O)[O-])CC(=O)[O-].[Na+].[Na+].[Na+] XHBBVSGBJWSGKN-UHFFFAOYSA-H 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- AUKDKWLCVXCCBN-UHFFFAOYSA-N thiodiacetic acid sulfoxide Chemical compound OC(=O)CS(=O)CC(O)=O AUKDKWLCVXCCBN-UHFFFAOYSA-N 0.000 description 1
- 235000019303 thiodipropionic acid Nutrition 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/567,331 US4147673A (en) | 1975-04-11 | 1975-04-11 | Detergent composition containing sulfinyl dipropionic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2611542A1 true DE2611542A1 (de) | 1976-10-28 |
Family
ID=24266718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762611542 Pending DE2611542A1 (de) | 1975-04-11 | 1976-03-18 | Fluessiges wasch- und reinigungsmittel |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4147673A (https=) |
| JP (1) | JPS51121008A (https=) |
| BE (1) | BE840623A (https=) |
| BR (1) | BR7602152A (https=) |
| CA (1) | CA1066983A (https=) |
| DE (1) | DE2611542A1 (https=) |
| FR (1) | FR2307036A1 (https=) |
| GB (1) | GB1505934A (https=) |
| IT (1) | IT1059746B (https=) |
| NL (1) | NL7603616A (https=) |
| SE (1) | SE7604151L (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0628624A1 (en) | 1993-06-09 | 1994-12-14 | The Procter & Gamble Company | Protease containing dye transfer inhibiting compositions |
| EP0709452A1 (en) | 1994-10-27 | 1996-05-01 | The Procter & Gamble Company | Cleaning compositions comprising xylanases |
| EP0747470A1 (en) | 1995-06-08 | 1996-12-11 | The Procter & Gamble Company | Cleaning compositions comprising keratanase |
| EP0747469A1 (en) | 1995-06-08 | 1996-12-11 | The Procter & Gamble Company | Cleaning compositions comprising chondroitinase |
| EP0932667B1 (en) | 1996-11-04 | 2008-10-01 | Novozymes A/S | Subtilase variants and compositions |
| JP4044143B2 (ja) | 1996-11-04 | 2008-02-06 | ノボザイムス アクティーゼルスカブ | ズブチラーゼ変異体及び組成物 |
| BRPI9911086B1 (pt) | 1998-06-10 | 2016-08-02 | Novozymes As | composição de limpeza, processo para tratar tecidos a máquina, e uso de uma mananase |
| GB0103871D0 (en) | 2001-02-16 | 2001-04-04 | Unilever Plc | Bleaching composition of enhanced stability and a process for making such a composition |
| MXPA05006071A (es) | 2002-12-11 | 2005-09-30 | Novozymes As | Composicion detergente. |
| WO2004074419A2 (en) | 2003-02-18 | 2004-09-02 | Novozymes A/S | Detergent compositions |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1054217A (https=) * | 1963-06-05 | |||
| US3635830A (en) * | 1968-05-24 | 1972-01-18 | Lever Brothers Ltd | Detergent compositions containing oxydisuccing acid salts as builders |
| US3692685A (en) * | 1968-05-24 | 1972-09-19 | Lever Brothers Ltd | Detergent compositions |
| US3635829A (en) * | 1969-05-19 | 1972-01-18 | Ethyl Corp | Detergent formulations |
| US3707503A (en) * | 1970-11-25 | 1972-12-26 | Lever Brothers Ltd | Stabilized liquid detergent composition |
| US3753913A (en) * | 1971-06-24 | 1973-08-21 | Nat Starch Chem Corp | Polycarboxylic thioether detergent builders |
| BE787231A (fr) * | 1971-08-05 | 1973-02-05 | Texaco Trinidad | Composition detergente |
-
1975
- 1975-04-11 US US05/567,331 patent/US4147673A/en not_active Expired - Lifetime
-
1976
- 1976-02-04 JP JP51010445A patent/JPS51121008A/ja active Pending
- 1976-03-11 GB GB9810/76A patent/GB1505934A/en not_active Expired
- 1976-03-15 CA CA247,915A patent/CA1066983A/en not_active Expired
- 1976-03-18 DE DE19762611542 patent/DE2611542A1/de active Pending
- 1976-04-07 NL NL7603616A patent/NL7603616A/xx not_active Application Discontinuation
- 1976-04-08 BR BR7602152A patent/BR7602152A/pt unknown
- 1976-04-08 SE SE7604151A patent/SE7604151L/xx unknown
- 1976-04-09 BE BE166052A patent/BE840623A/xx unknown
- 1976-04-09 FR FR7610440A patent/FR2307036A1/fr active Granted
- 1976-04-09 IT IT22141/76A patent/IT1059746B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2307036A1 (fr) | 1976-11-05 |
| GB1505934A (en) | 1978-04-05 |
| SE7604151L (sv) | 1976-10-12 |
| CA1066983A (en) | 1979-11-27 |
| BE840623A (fr) | 1976-10-11 |
| AU1247476A (en) | 1977-11-10 |
| FR2307036B3 (https=) | 1979-01-05 |
| IT1059746B (it) | 1982-06-21 |
| NL7603616A (nl) | 1976-10-13 |
| JPS51121008A (en) | 1976-10-22 |
| US4147673A (en) | 1979-04-03 |
| BR7602152A (pt) | 1976-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |