DE2463384C3 - Verwendung eines kristallinen Zeolithpulvers des Typs A als Phosphatersatz in Wasch- und Reinigungsmitteln - Google Patents
Verwendung eines kristallinen Zeolithpulvers des Typs A als Phosphatersatz in Wasch- und ReinigungsmittelnInfo
- Publication number
- DE2463384C3 DE2463384C3 DE19742463384 DE2463384A DE2463384C3 DE 2463384 C3 DE2463384 C3 DE 2463384C3 DE 19742463384 DE19742463384 DE 19742463384 DE 2463384 A DE2463384 A DE 2463384A DE 2463384 C3 DE2463384 C3 DE 2463384C3
- Authority
- DE
- Germany
- Prior art keywords
- crystallization
- zeolite powder
- water
- synthesis mixture
- sio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 14
- 239000010457 zeolite Substances 0.000 title claims description 14
- 229910019142 PO4 Inorganic materials 0.000 title claims description 5
- 239000003599 detergent Substances 0.000 title claims description 5
- 239000000843 powder Substances 0.000 title claims 8
- 239000012459 cleaning agent Substances 0.000 title claims 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims 4
- 239000010452 phosphate Substances 0.000 title claims 4
- 238000002425 crystallisation Methods 0.000 claims description 21
- 230000008025 crystallization Effects 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- 238000003786 synthesis reaction Methods 0.000 claims description 18
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 12
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 238000004062 sedimentation Methods 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 8
- 238000005496 tempering Methods 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 150000004645 aluminates Chemical class 0.000 claims description 6
- 238000001228 spectrum Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 4
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 238000005342 ion exchange Methods 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 239000012452 mother liquor Substances 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 3
- 239000002808 molecular sieve Substances 0.000 claims 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 3
- 238000004140 cleaning Methods 0.000 claims 2
- 239000013078 crystal Substances 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 238000002083 X-ray spectrum Methods 0.000 claims 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000005216 hydrothermal crystallization Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000010899 nucleation Methods 0.000 claims 1
- 230000006911 nucleation Effects 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 238000010008 shearing Methods 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000005265 energy consumption Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742463384 DE2463384C3 (de) | 1974-10-02 | 1974-10-02 | Verwendung eines kristallinen Zeolithpulvers des Typs A als Phosphatersatz in Wasch- und Reinigungsmitteln |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2447021A DE2447021C3 (de) | 1974-10-02 | 1974-10-02 | Kristallines Zeolithpulver des Typs A und das Verfahren zu seiner Herstellung |
| DE19742463384 DE2463384C3 (de) | 1974-10-02 | 1974-10-02 | Verwendung eines kristallinen Zeolithpulvers des Typs A als Phosphatersatz in Wasch- und Reinigungsmitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2463384C3 true DE2463384C3 (de) | 1987-12-03 |
Family
ID=25767770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742463384 Expired DE2463384C3 (de) | 1974-10-02 | 1974-10-02 | Verwendung eines kristallinen Zeolithpulvers des Typs A als Phosphatersatz in Wasch- und Reinigungsmitteln |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE2463384C3 (US07579456-20090825-P00002.png) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB339355A (en) * | 1929-09-07 | 1930-12-08 | Electric Smelting & Aluminum C | Improvements in and relating to detergents and method of preparing the same |
| US2213641A (en) * | 1938-09-01 | 1940-09-03 | Urlyn C Tainton | Cleaning powder |
| US3033641A (en) * | 1956-03-21 | 1962-05-08 | Union Carbide Corp | Process for cation separation using zeolitic materials |
| US3154494A (en) * | 1961-08-07 | 1964-10-27 | United States Borax Chem | Fabric laundry compositions |
| DE2204842A1 (de) * | 1971-02-09 | 1972-08-24 | Colgate-Palmolive Co., New York, N.Y. (V.StA.) | Rieselfähige nichtionogene Waschmittelzusätze |
| DE2143771B2 (de) * | 1970-09-02 | 1973-08-23 | Societe Francaise Des Silicates Speciaux Sifrance, Paris | Nichtkorrodierendes, festes waschund reinigungsmittel |
| US3755180A (en) * | 1972-02-25 | 1973-08-28 | Colgate Palmolive Co | Means to inhibit overglaze damage by automatic dishwashing detergents |
| DE2412837B2 (US07579456-20090825-P00002.png) * | 1973-04-13 | 1978-05-18 | Henkel Kgaa, 4000 Duesseldorf | |
| DE2422655B2 (de) * | 1973-05-11 | 1978-08-03 | The Procter & Gamble Co., Cincinnati, Ohio (V.St.A.) | Waschmittelzusammensetzung |
-
1974
- 1974-10-02 DE DE19742463384 patent/DE2463384C3/de not_active Expired
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB339355A (en) * | 1929-09-07 | 1930-12-08 | Electric Smelting & Aluminum C | Improvements in and relating to detergents and method of preparing the same |
| US2213641A (en) * | 1938-09-01 | 1940-09-03 | Urlyn C Tainton | Cleaning powder |
| US3033641A (en) * | 1956-03-21 | 1962-05-08 | Union Carbide Corp | Process for cation separation using zeolitic materials |
| US3154494A (en) * | 1961-08-07 | 1964-10-27 | United States Borax Chem | Fabric laundry compositions |
| DE2143771B2 (de) * | 1970-09-02 | 1973-08-23 | Societe Francaise Des Silicates Speciaux Sifrance, Paris | Nichtkorrodierendes, festes waschund reinigungsmittel |
| DE2204842A1 (de) * | 1971-02-09 | 1972-08-24 | Colgate-Palmolive Co., New York, N.Y. (V.StA.) | Rieselfähige nichtionogene Waschmittelzusätze |
| US3755180A (en) * | 1972-02-25 | 1973-08-28 | Colgate Palmolive Co | Means to inhibit overglaze damage by automatic dishwashing detergents |
| DE2412837B2 (US07579456-20090825-P00002.png) * | 1973-04-13 | 1978-05-18 | Henkel Kgaa, 4000 Duesseldorf | |
| DE2422655B2 (de) * | 1973-05-11 | 1978-08-03 | The Procter & Gamble Co., Cincinnati, Ohio (V.St.A.) | Waschmittelzusammensetzung |
Non-Patent Citations (2)
| Title |
|---|
| BRECK,D.W.: Zeolite Molecular Sieves, John Wiley & Sons, 1974, S.537, Tabelle 7.2 * |
| KRINGS,R.: Neuzeitliche Seifen und seifen- haltige Waschmittel, 1939, S.134, Zeilen 17-28 * |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| Q272 | Divided out of: |
Ref document number: 2447021 Country of ref document: DE |
|
| 8239 | Disposal/non-payment of the annual fee | ||
| 8281 | Inventor (new situation) |
Free format text: ROEBKE, WOLFGANG, DR., 5047 WESSELING, DE PARR, EHRFRIED KNEITEL, DIETER, 6458 RODENBACH, DE |
|
| 8280 | Miscellaneous part ii |
Free format text: IN HEFT 41/84, SEITE 7959, SP. 2: DIE VEROEFFENTLICHUNG IST ZU STREICHEN |
|
| AC | Divided out of |
Ref country code: DE Ref document number: 2447021 Format of ref document f/p: P |
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| C3 | Grant after two publication steps (3rd publication) | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: DEGUSSA AG, 6000 FRANKFURT, DE HENKEL KGAA, 4000 D |
|
| 8339 | Ceased/non-payment of the annual fee |