DE2262971A1 - Verfahren zur vergasung von kohle in einer mehrzahl wirbelschichtkammern - Google Patents

Verfahren zur vergasung von kohle in einer mehrzahl wirbelschichtkammern

Info

Publication number
DE2262971A1
DE2262971A1 DE2262971A DE2262971A DE2262971A1 DE 2262971 A1 DE2262971 A1 DE 2262971A1 DE 2262971 A DE2262971 A DE 2262971A DE 2262971 A DE2262971 A DE 2262971A DE 2262971 A1 DE2262971 A1 DE 2262971A1
Authority
DE
Germany
Prior art keywords
fluidized bed
coal
chamber
turbine
gasification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE2262971A
Other languages
German (de)
English (en)
Inventor
David H Archer
Lee E Brecher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Westinghouse Electric Corp
Original Assignee
Westinghouse Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Publication of DE2262971A1 publication Critical patent/DE2262971A1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/42—Sulfides or polysulfides of magnesium, calcium, strontium, or barium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675—Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Industrial Gases (AREA)
  • Treating Waste Gases (AREA)
DE2262971A 1972-01-11 1972-12-22 Verfahren zur vergasung von kohle in einer mehrzahl wirbelschichtkammern Pending DE2262971A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00216950A US3804606A (en) 1972-01-11 1972-01-11 Apparatus and method for desulfurizing and completely gasifying coal

Publications (1)

Publication Number Publication Date
DE2262971A1 true DE2262971A1 (de) 1973-07-19

Family

ID=22809101

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2262971A Pending DE2262971A1 (de) 1972-01-11 1972-12-22 Verfahren zur vergasung von kohle in einer mehrzahl wirbelschichtkammern

Country Status (10)

Country Link
US (1) US3804606A (enExample)
JP (1) JPS4881902A (enExample)
BE (1) BE793881A (enExample)
CA (1) CA958216A (enExample)
DE (1) DE2262971A1 (enExample)
ES (1) ES409568A1 (enExample)
FR (1) FR2167946A1 (enExample)
GB (1) GB1357990A (enExample)
IT (1) IT971862B (enExample)
SE (1) SE378257B (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3228532A1 (de) * 1982-07-30 1984-02-02 BKMI Industrieanlagen GmbH, 8000 München Verfahren zur verschwelung und vergasung von kohlenstoffhaltigen feststoffen
DE3434619A1 (de) * 1984-01-30 1985-08-08 VEB Schwermaschinenbau "Karl Liebknecht" Magdeburg-Kombinat für Dieselmotoren und Industrieanlagen, DDR 3011 Magdeburg Verfahren und vorrichtung zur mehrstufigen veredlung von organischen schuettguetern

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US3977844A (en) * 1973-05-09 1976-08-31 Slyke William J Van Process for producing a sulfur free combustible gas
DE2400772B2 (de) * 1974-01-08 1977-07-14 Khizia, Klaus, Dr-Ing, 4600 Dort mund, L & C Stemmuller GmbH, 5270 Gummersbach Anlage zur herstellung von festen und gasfoermigen schwefelarmen produkten aus kohle fuer die kombinierte strom- und gaserzeugung
US3978657A (en) * 1974-02-06 1976-09-07 Combustion Turbine Power, Inc. Turbine system
DE2429993C3 (de) * 1974-06-22 1984-01-05 Krupp-Koppers Gmbh, 4300 Essen Verfahren zum Erzeugen elektrischer Energie
AR205469A1 (es) * 1974-07-04 1976-05-07 Kiener Karl Procedimiento y dispositivo de obtencion de gas combustible
US4032305A (en) * 1974-10-07 1977-06-28 Squires Arthur M Treating carbonaceous matter with hot steam
US4099374A (en) * 1976-04-15 1978-07-11 Westinghouse Electric Corp. Gasifier-combined cycle plant
GB1573319A (en) * 1976-05-14 1980-08-20 Penny Turbines Ltd Noel Engine in which fuel is reacted in a plurality of stages
CH614016A5 (enExample) * 1976-06-11 1979-10-31 Sulzer Ag
US4277416A (en) * 1977-02-17 1981-07-07 Aminoil, Usa, Inc. Process for producing methanol
US4212160A (en) * 1977-12-22 1980-07-15 Combustion Engineering, Inc. Combined cycle power plant using low Btu gas
GB2027444B (en) * 1978-07-28 1983-03-02 Exxon Research Engineering Co Gasification of ash-containing solid fuels
DE2931427A1 (de) * 1978-11-17 1981-02-19 Steag Ag Anlage zur energiegewinnung aus festen fossilen brennstoffen, insbesondere steinkohle
US4238923A (en) * 1979-06-22 1980-12-16 Combustion Engineering, Inc. Method of low temperature heat utilization for atmospheric pressure coal gasification
US4282010A (en) * 1979-07-17 1981-08-04 The United States Of America As Represented By The United States Department Of Energy Fluidized bed injection assembly for coal gasification
US4391611A (en) * 1981-03-05 1983-07-05 The United States Of America As Represented By The United States Department Of Energy Gasification system
US4490157A (en) * 1983-01-10 1984-12-25 Combustion Engineering, Inc. Indirectly heated fluidized bed gasifier
US4496370A (en) * 1983-04-04 1985-01-29 Phillips Petroleum Company Zinc oxide-char gasification process
US4745038A (en) * 1983-11-10 1988-05-17 Westinghouse Electric Corp. Integrated gasification iron-air electrical system
GB8423949D0 (en) * 1984-09-21 1984-10-31 English Electric Co Ltd Fluidised-bed gasifier
US4667467A (en) * 1985-06-04 1987-05-26 Westinghouse Electric Corp. Method for energy conversion
DE3668347D1 (de) * 1985-09-02 1990-02-22 Siemens Ag Kombiniertes gas- und dampfturbinenkraftwerk.
GB2191782A (en) * 1986-06-17 1987-12-23 Midrex Int Bv Method and apparatus for producing upgraded synthetic fuel gas from coal
DE3629817A1 (de) * 1986-09-02 1988-03-03 Bergwerksverband Gmbh Verfahren zur verringerung der schadstoffemisionen von kraftwerken mit kombinierten gas-/dampfturbinenprozessen mit vorgeschalteter kohlevergasung
DE69100679T2 (de) * 1990-07-23 1994-04-28 Mitsubishi Heavy Ind Ltd Vergasende Verbrennungsmethode und vergasende Energieerzeugungsmethode.
DE4103362C1 (enExample) * 1991-02-05 1992-04-23 Voest Alpine Ind Anlagen
US5765365A (en) * 1993-03-15 1998-06-16 Mitsubishi Jukogyo Kabushiki Kaisha Coal gasification power generator
FI941141A7 (fi) * 1993-03-15 1994-09-16 Mitsubishi Heavy Ind Ltd Kivihiilen kaasuunnukseen perustuva energiankehitin
US5666801A (en) * 1995-09-01 1997-09-16 Rohrer; John W. Combined cycle power plant with integrated CFB devolatilizer and CFB boiler
US5895508A (en) * 1996-08-09 1999-04-20 The United States Of America As Represented By The United States Department Of Energy Down-flow moving-bed gasifier with catalyst recycle
AP2008004678A0 (en) * 2006-05-05 2008-12-31 Plascoenergy Ip Holdings A control system for the conversion of a carbonaceous feedstock into gas
WO2007131241A2 (en) 2006-05-05 2007-11-15 Plasco Energy Group Inc. A horizontally-oriented gasifier with lateral transfer system
JP2009536258A (ja) * 2006-05-05 2009-10-08 プラスコエナジー アイピー ホールデイングス，エス．エル．，ビルバオ，シャフハウゼン ブランチ プラズマトーチ熱を使用したガス改質システム
NZ573217A (en) * 2006-05-05 2011-11-25 Plascoenergy Ip Holdings S L Bilbao Schaffhausen Branch A facility for conversion of carbonaceous feedstock into a reformulated syngas containing CO and H2
US7451591B2 (en) * 2006-05-08 2008-11-18 Econo-Power International Corporation Production enhancements on integrated gasification combined cycle power plants
AP2008004698A0 (en) * 2006-06-05 2008-12-31 Plascoenergy Ip Holdings S L A gasifier comprising vertically successive processing regions
US20080148739A1 (en) * 2006-12-22 2008-06-26 Paul Marius A Fluidized bed heavy fuel combustor
CN102057222B (zh) * 2007-02-27 2013-08-21 普拉斯科能源Ip控股公司毕尔巴鄂-沙夫豪森分公司 具有加工过的原料/焦炭转化和气体重组的气化系统
TW200848151A (en) * 2007-05-11 2008-12-16 Plasco Energy Group Inc A gas reformulation system comprising means to optimise the effectiveness of gas conversion
US20080302106A1 (en) * 2007-06-07 2008-12-11 Econo-Power International Corporation Integration of coal fired steam plants with integrated gasification combined cycle power plants
WO2009009891A1 (en) * 2007-07-17 2009-01-22 Plasco Energy Group Inc. A gasifier comprising one or more fluid conduits
WO2010076499A2 (fr) 2008-12-16 2010-07-08 Jean-Xavier Morin Procede et dispositif de production et de purification de gaz de synthese
US20100313442A1 (en) * 2009-06-12 2010-12-16 Steven Craig Russell Method of using syngas cooling to heat drying gas for a dry feed system
US9321640B2 (en) 2010-10-29 2016-04-26 Plasco Energy Group Inc. Gasification system with processed feedstock/char conversion and gas reformulation
DE102015219398A1 (de) * 2015-10-07 2017-04-13 Siemens Aktiengesellschaft Verfahren zum Betreiben eines Gas-und-Dampf-Kombinationskraftwerks sowie Gas-und-Dampf-Kombinationskraftwerk
CN109852423B (zh) * 2018-11-23 2020-08-04 龙正环保股份有限公司 基于水管式冷凝饱和蒸汽锅炉驱动的生物质气化循环系统
ES2965008T3 (es) * 2021-01-06 2024-04-10 Gidara Energy B V Proceso para producir gas de síntesis a través de conversión termoquímica de biomasa y materiales residuales

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US2683657A (en) * 1948-05-29 1954-07-13 Hydrocarbon Research Inc Gasification of carbonaceous solids
US2727813A (en) * 1951-05-31 1955-12-20 Universal Oil Prod Co Production of combustible gas from hydrocarbonaceous solids, particularly bituminous coals
US3088816A (en) * 1960-12-09 1963-05-07 Huntington Chemical Corp Method and apparatus for the dry ash generation of hydrogen and carbon monoxide gases from solid fuels
GB1200727A (en) * 1966-11-15 1970-07-29 Struthers Scientific Int Corp Gas turbine plant comprising a combustible gas producer
US3481834A (en) * 1968-08-21 1969-12-02 Arthur M Squires Process and apparatus for desulfurizing fuels
US3597327A (en) * 1969-04-02 1971-08-03 Arthur M Squires Process for pyrolyzing a solid or liquid hydrocarbonaceous fuel in a fluidized bed

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3228532A1 (de) * 1982-07-30 1984-02-02 BKMI Industrieanlagen GmbH, 8000 München Verfahren zur verschwelung und vergasung von kohlenstoffhaltigen feststoffen
DE3434619A1 (de) * 1984-01-30 1985-08-08 VEB Schwermaschinenbau "Karl Liebknecht" Magdeburg-Kombinat für Dieselmotoren und Industrieanlagen, DDR 3011 Magdeburg Verfahren und vorrichtung zur mehrstufigen veredlung von organischen schuettguetern

Also Published As

Publication number Publication date
JPS4881902A (enExample) 1973-11-01
IT971862B (it) 1974-05-10
SE378257B (enExample) 1975-08-25
CA958216A (en) 1974-11-26
BE793881A (fr) 1973-07-11
GB1357990A (en) 1974-06-26
US3804606A (en) 1974-04-16
ES409568A1 (es) 1975-11-16
FR2167946A1 (enExample) 1973-08-24

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