GB1357990A - Process for desulphurizing and completely gasifying coal - Google Patents

Process for desulphurizing and completely gasifying coal

Info

Publication number
GB1357990A
GB1357990A GB5700672A GB5700672A GB1357990A GB 1357990 A GB1357990 A GB 1357990A GB 5700672 A GB5700672 A GB 5700672A GB 5700672 A GB5700672 A GB 5700672A GB 1357990 A GB1357990 A GB 1357990A
Authority
GB
United Kingdom
Prior art keywords
bed
coal
gasification
turbine
devolatilization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5700672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CBS Corp
Original Assignee
Westinghouse Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Publication of GB1357990A publication Critical patent/GB1357990A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/721Multistage gasification, e.g. plural parallel or serial gasification stages
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/42Sulfides or polysulfides of magnesium, calcium, strontium, or barium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/482Gasifiers with stationary fluidised bed
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • C10J2300/0996Calcium-containing inorganic materials, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807Recycle loops, e.g. gas, solids, heating medium, water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1884Heat exchange between at least two process streams with one stream being synthesis gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1892Heat exchange between at least two process streams with one stream being water/steam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]

Abstract

1357990 Coal desulphurization and gasification WESTINGHOUSE ELECTRIC CORP 11 Dec 1972 [11 Jan 1972] 57006/72 Heading C5E Coal is desulphurized and completely gasified in a plurality of fluidized beds through which a gas flow is conducted in opposition to a flow of crushed coal, which together with a calcium bearing material is introduced into a drying bed heated by hot gases and through a devolatilization and gasification bed to a combustion bed from which the ashes are removed, at least a portion of the gas stream being removed from the process before it enters the drying bed and the gases emanating from the drying bed returned to the combustion bed and recycled through the gasification and devolatilization beds. The calcium bearing material may be lime which is added to the crushed coal and the calcium sulphide formed is removed from the devolatilization and gasification bed. The coal may be first devolatilized in a separate bed from which the calcium sulphide is removed and then gasified in an additional fluidized bed. Ash is removed from the bottom of the combustion bed. The removed portion of the gas stream is conducted into a gas turbine having a compressor, a combustor, and a turbine portion which drives the compressor and generator, so that the turbine exhaust gases are essentially free of sulphur compounds. The hot gases passing through the drying bed consist of a portion of the turbine exhaust gases. The gas flow through the fluidized beds consists of pressurized air from the turbine compressor.
GB5700672A 1972-01-11 1972-12-11 Process for desulphurizing and completely gasifying coal Expired GB1357990A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00216950A US3804606A (en) 1972-01-11 1972-01-11 Apparatus and method for desulfurizing and completely gasifying coal

Publications (1)

Publication Number Publication Date
GB1357990A true GB1357990A (en) 1974-06-26

Family

ID=22809101

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5700672A Expired GB1357990A (en) 1972-01-11 1972-12-11 Process for desulphurizing and completely gasifying coal

Country Status (10)

Country Link
US (1) US3804606A (en)
JP (1) JPS4881902A (en)
BE (1) BE793881A (en)
CA (1) CA958216A (en)
DE (1) DE2262971A1 (en)
ES (1) ES409568A1 (en)
FR (1) FR2167946A1 (en)
GB (1) GB1357990A (en)
IT (1) IT971862B (en)
SE (1) SE378257B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT375088B (en) * 1974-07-04 1984-06-25 Kiener Karl Dipl Ing METHOD AND DEVICE FOR PRODUCING FUEL GASES FROM MUELL
GB2164660A (en) * 1984-09-21 1986-03-26 English Electric Co Ltd Gasification apparatus

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US3977844A (en) * 1973-05-09 1976-08-31 Slyke William J Van Process for producing a sulfur free combustible gas
DE2400772B2 (en) * 1974-01-08 1977-07-14 Khizia, Klaus, Dr-Ing, 4600 Dort mund, L & C Stemmuller GmbH, 5270 Gummersbach PLANT FOR THE MANUFACTURE OF SOLID AND GASFUL LOW SULFUR PRODUCTS FROM COAL FOR COMBINED ELECTRICITY AND GAS GENERATION
US3978657A (en) * 1974-02-06 1976-09-07 Combustion Turbine Power, Inc. Turbine system
DE2429993C3 (en) * 1974-06-22 1984-01-05 Krupp-Koppers Gmbh, 4300 Essen Method for generating electrical energy
US4032305A (en) * 1974-10-07 1977-06-28 Squires Arthur M Treating carbonaceous matter with hot steam
US4099374A (en) * 1976-04-15 1978-07-11 Westinghouse Electric Corp. Gasifier-combined cycle plant
GB1573319A (en) * 1976-05-14 1980-08-20 Penny Turbines Ltd Noel Engine in which fuel is reacted in a plurality of stages
CH614016A5 (en) * 1976-06-11 1979-10-31 Sulzer Ag
US4277416A (en) * 1977-02-17 1981-07-07 Aminoil, Usa, Inc. Process for producing methanol
US4212160A (en) * 1977-12-22 1980-07-15 Combustion Engineering, Inc. Combined cycle power plant using low Btu gas
GB2027444B (en) * 1978-07-28 1983-03-02 Exxon Research Engineering Co Gasification of ash-containing solid fuels
DE2931427A1 (en) * 1978-11-17 1981-02-19 Steag Ag PLANT FOR ENERGY FROM SOLID FOSSIL FUELS, IN PARTICULAR CHARCOAL
US4238923A (en) * 1979-06-22 1980-12-16 Combustion Engineering, Inc. Method of low temperature heat utilization for atmospheric pressure coal gasification
US4282010A (en) * 1979-07-17 1981-08-04 The United States Of America As Represented By The United States Department Of Energy Fluidized bed injection assembly for coal gasification
US4391611A (en) * 1981-03-05 1983-07-05 The United States Of America As Represented By The United States Department Of Energy Gasification system
DE3228532A1 (en) * 1982-07-30 1984-02-02 BKMI Industrieanlagen GmbH, 8000 München Process for carbonizing and gasifying carbonaceous solids
US4490157A (en) * 1983-01-10 1984-12-25 Combustion Engineering, Inc. Indirectly heated fluidized bed gasifier
US4496370A (en) * 1983-04-04 1985-01-29 Phillips Petroleum Company Zinc oxide-char gasification process
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JP2010500420A (en) 2006-05-05 2010-01-07 プラスコエナジー アイピー ホールデイングス,エス.エル.,ビルバオ,シャフハウゼン ブランチ Horizontally oriented gasifier with lateral transfer system
BRPI0711325A2 (en) * 2006-05-05 2011-08-30 Plascoenergy Ip Holdings S L Bilbao Schaffhausen Branch control system for converting a carbonaceous feedstock into gas
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US20080302106A1 (en) * 2007-06-07 2008-12-11 Econo-Power International Corporation Integration of coal fired steam plants with integrated gasification combined cycle power plants
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT375088B (en) * 1974-07-04 1984-06-25 Kiener Karl Dipl Ing METHOD AND DEVICE FOR PRODUCING FUEL GASES FROM MUELL
GB2164660A (en) * 1984-09-21 1986-03-26 English Electric Co Ltd Gasification apparatus

Also Published As

Publication number Publication date
SE378257B (en) 1975-08-25
ES409568A1 (en) 1975-11-16
BE793881A (en) 1973-07-11
US3804606A (en) 1974-04-16
JPS4881902A (en) 1973-11-01
IT971862B (en) 1974-05-10
CA958216A (en) 1974-11-26
DE2262971A1 (en) 1973-07-19
FR2167946A1 (en) 1973-08-24

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees