DE2256780C2 - Verfahren zur Herstellung von isotaktischem Polypropylen oder isotaktischen α-Olefincopolymeren mit wenigstens 50 Gewichtsprozent an Propyleneinheiten sowie feste titanhaltige Katalysatorkomponente zu dessen Durchführung - Google Patents
Verfahren zur Herstellung von isotaktischem Polypropylen oder isotaktischen α-Olefincopolymeren mit wenigstens 50 Gewichtsprozent an Propyleneinheiten sowie feste titanhaltige Katalysatorkomponente zu dessen DurchführungInfo
- Publication number
- DE2256780C2 DE2256780C2 DE2256780A DE2256780A DE2256780C2 DE 2256780 C2 DE2256780 C2 DE 2256780C2 DE 2256780 A DE2256780 A DE 2256780A DE 2256780 A DE2256780 A DE 2256780A DE 2256780 C2 DE2256780 C2 DE 2256780C2
- Authority
- DE
- Germany
- Prior art keywords
- titanium
- catalyst component
- containing catalyst
- reducing metal
- ticu
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010936 titanium Substances 0.000 title claims description 60
- 229910052719 titanium Inorganic materials 0.000 title claims description 59
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 58
- 239000003054 catalyst Substances 0.000 title claims description 45
- 239000007787 solid Substances 0.000 title claims description 44
- -1 polypropylene Polymers 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 19
- 229920001155 polypropylene Polymers 0.000 title claims description 18
- 239000004743 Polypropylene Substances 0.000 title claims description 17
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title claims description 6
- 239000004711 α-olefin Substances 0.000 title description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims description 36
- 239000002184 metal Substances 0.000 claims description 36
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 26
- 229910010165 TiCu Inorganic materials 0.000 claims description 20
- 239000008139 complexing agent Substances 0.000 claims description 18
- 230000003197 catalytic effect Effects 0.000 claims description 9
- 239000003701 inert diluent Substances 0.000 claims description 7
- 150000002902 organometallic compounds Chemical class 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 150000003573 thiols Chemical class 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 150000003003 phosphines Chemical class 0.000 claims description 3
- OUULRIDHGPHMNQ-UHFFFAOYSA-N stibane Chemical class [SbH3] OUULRIDHGPHMNQ-UHFFFAOYSA-N 0.000 claims description 3
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 72
- 238000006116 polymerization reaction Methods 0.000 description 31
- 239000000725 suspension Substances 0.000 description 23
- 239000003085 diluting agent Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 15
- 230000000694 effects Effects 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 238000006722 reduction reaction Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000460 chlorine Chemical group 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000011630 iodine Chemical group 0.000 description 1
- 229910052740 iodine Chemical group 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000013587 production medium Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU64328 | 1971-11-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2256780A1 DE2256780A1 (de) | 1973-05-30 |
| DE2256780C2 true DE2256780C2 (de) | 1986-12-04 |
Family
ID=19726885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2256780A Expired DE2256780C2 (de) | 1971-11-24 | 1972-11-20 | Verfahren zur Herstellung von isotaktischem Polypropylen oder isotaktischen α-Olefincopolymeren mit wenigstens 50 Gewichtsprozent an Propyleneinheiten sowie feste titanhaltige Katalysatorkomponente zu dessen Durchführung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4210735A (show.php) |
| JP (2) | JPS5240348B2 (show.php) |
| BE (1) | BE791441A (show.php) |
| DE (1) | DE2256780C2 (show.php) |
| FR (1) | FR2160873B1 (show.php) |
| GB (1) | GB1370559A (show.php) |
| IT (1) | IT968979B (show.php) |
| LU (1) | LU64328A1 (show.php) |
| NL (1) | NL157610B (show.php) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2533511C2 (de) * | 1974-07-31 | 1984-11-29 | Mitsubishi Chemical Industries Ltd., Tokio/Tokyo | Verfahren zur Herstellung von festem purpurfarbenem feingranuliertem Titantrichlorid und seine Verwendung zur Polymerisation von α-Olefinen |
| JPS5116297A (ja) * | 1974-07-31 | 1976-02-09 | Mitsubishi Chem Ind | Kotaisanenkachitanno seizohoho |
| US4182816A (en) | 1974-10-30 | 1980-01-08 | Imperial Chemical Industries Limited | Olefine polymerization process |
| US4354010A (en) | 1975-01-09 | 1982-10-12 | Imperial Chemical Industries Limited | Transition metal compound |
| US4111834A (en) | 1975-05-28 | 1978-09-05 | Imperial Chemical Industries Limited | Process for preparing a transition metal compound and it's use as a component in an olefin polymerization catalyst |
| JPS5273195A (en) | 1975-12-16 | 1977-06-18 | Toyo Sutoufuaa Kemikaru Yuugen | Manufacture of catalyst composite for alphaaolefine polymerization |
| DE2616260A1 (de) * | 1976-04-13 | 1977-11-03 | Basf Ag | Verfahren zur herstellung von poly-alpha-olefinen |
| JPS5439549U (show.php) * | 1977-08-24 | 1979-03-15 | ||
| JPS5831089B2 (ja) * | 1979-11-26 | 1983-07-04 | 有限会社 東洋ストウフア−・ケミカル | α−オレフィン重合用三塩化チタニウム触媒成分の製造方法 |
| JPS56136805A (en) * | 1980-03-29 | 1981-10-26 | Mitsui Petrochem Ind Ltd | Titanium catalyst component for olefin polymerization |
| US4398005A (en) * | 1981-01-23 | 1983-08-09 | Gulf Research & Development Company | Novel polymerization catalyst and process for using same to polymerize olefins |
| DE3876411T2 (de) * | 1987-07-10 | 1993-06-24 | Quantum Chem Corp | Katalysator fuer propylenpolymerisierung sowie verfahren. |
| US5061755A (en) * | 1988-10-25 | 1991-10-29 | Mitsubishi Kasei Corporation | Polypropylene composition and highly transparent polypropylene film made thereof |
| KR900016267A (ko) * | 1989-04-25 | 1990-11-13 | 노기 사다오 | 올레핀 중합체 제조용 삼염화티탄 조성물 및 이의 제조방법 |
| JP3336581B2 (ja) * | 1992-10-19 | 2002-10-21 | 富士写真フイルム株式会社 | 追記型光ディスクの媒体検査方法およびシステム |
| US8329790B2 (en) * | 2008-06-17 | 2012-12-11 | Bromine Compounds Ltd. | Polypropylene based formulations |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL243666A (show.php) * | 1958-10-10 | 1900-01-01 | ||
| DE1570919B2 (de) * | 1963-11-05 | 1970-12-17 | Mitsui Toatsu Chemicals, Inc., Tokio | Verfahren zur Herstellung von Horao- oder Mischpolymerisaten des Propylens. ° |
| US3492281A (en) * | 1967-06-29 | 1970-01-27 | Goodyear Tire & Rubber | Process for the polymerization of diolefins with beta titanium trichloride and organoaluminum compounds |
| DE1720329A1 (de) * | 1967-11-30 | 1971-06-16 | Basf Ag | Verfahren zum Herstellen von Polymerisaten aus alpha-Olefinen |
| US3701763A (en) * | 1969-10-20 | 1972-10-31 | Mitsui Petrochemical Ind | Process for polymerization of olefins and catalysts therefor |
| IE35231B1 (en) * | 1970-03-26 | 1975-12-24 | Solvay | Process for the preparation of a ziegler-natta type catalyst |
-
0
- BE BE791441D patent/BE791441A/xx not_active IP Right Cessation
-
1971
- 1971-11-24 LU LU64328A patent/LU64328A1/xx unknown
-
1972
- 1972-10-12 US US05/297,087 patent/US4210735A/en not_active Expired - Lifetime
- 1972-10-16 IT IT30525/72A patent/IT968979B/it active
- 1972-11-08 NL NL7215103.A patent/NL157610B/xx unknown
- 1972-11-17 FR FR7241062A patent/FR2160873B1/fr not_active Expired
- 1972-11-20 DE DE2256780A patent/DE2256780C2/de not_active Expired
- 1972-11-24 JP JP47117262A patent/JPS5240348B2/ja not_active Expired
- 1972-11-24 GB GB5434272A patent/GB1370559A/en not_active Expired
-
1977
- 1977-05-02 JP JP5003777A patent/JPS52138083A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5240348B2 (show.php) | 1977-10-12 |
| FR2160873A1 (show.php) | 1973-07-06 |
| BE791441A (fr) | 1973-05-16 |
| LU64328A1 (show.php) | 1973-06-21 |
| NL7215103A (show.php) | 1973-05-28 |
| FR2160873B1 (show.php) | 1976-04-23 |
| JPS52138083A (en) | 1977-11-17 |
| GB1370559A (en) | 1974-10-16 |
| JPS4864170A (show.php) | 1973-09-05 |
| DE2256780A1 (de) | 1973-05-30 |
| NL157610B (nl) | 1978-08-15 |
| IT968979B (it) | 1974-03-20 |
| US4210735A (en) | 1980-07-01 |
| JPS5618121B2 (show.php) | 1981-04-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |