GB1370559A - Process for the polymerisation of alpha-olefins - Google Patents

Process for the polymerisation of alpha-olefins

Info

Publication number
GB1370559A
GB1370559A GB5434272A GB5434272A GB1370559A GB 1370559 A GB1370559 A GB 1370559A GB 5434272 A GB5434272 A GB 5434272A GB 5434272 A GB5434272 A GB 5434272A GB 1370559 A GB1370559 A GB 1370559A
Authority
GB
United Kingdom
Prior art keywords
ticl
reacted
metal
isoamylether
nov
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5434272A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of GB1370559A publication Critical patent/GB1370559A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1370559 Polymerisation catalyst SOLVAY & CIE 24 Nov 1972 [24 Nov 1971] 54342/72 Heading B1E [Also in Division C3] A catalyst component containing TiCl 3 is prepared by reducing TiCl 4 with a metal of Groups Ia, IIa, IIb or IIIb of the Mendeleef Periodic Table to give a double chloride of the metal and Ti which is treated with a complexant capable of forming a complex with the chloride of the reducing metal and reacted with a liquid medium containing TiCl 4 to give a solid which is separated from its reaction medium. The preferred complexants have the formula R 2 O, R 2 S, RSH, R 3 N, R 2 NH or RNH 2 where the R's are the same or different C 1 -C 15 hydrocarbon radicals. In the examples 3TiCl 3 AlCl 3 , derived from TiCl 4 reduced with Al, is reacted with di-isoamylether, di-n-butylether, di-n-butylamine or di-n-butylsulphide then with a solution of TiCl 4 in n hexane or is reacted with di-isoamylether and the TiCl 4 solution together.
GB5434272A 1971-11-24 1972-11-24 Process for the polymerisation of alpha-olefins Expired GB1370559A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
LU64328 1971-11-24

Publications (1)

Publication Number Publication Date
GB1370559A true GB1370559A (en) 1974-10-16

Family

ID=19726885

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5434272A Expired GB1370559A (en) 1971-11-24 1972-11-24 Process for the polymerisation of alpha-olefins

Country Status (9)

Country Link
US (1) US4210735A (en)
JP (2) JPS5240348B2 (en)
BE (1) BE791441A (en)
DE (1) DE2256780C2 (en)
FR (1) FR2160873B1 (en)
GB (1) GB1370559A (en)
IT (1) IT968979B (en)
LU (1) LU64328A1 (en)
NL (1) NL157610B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4098907A (en) 1975-12-16 1978-07-04 Toyo Stauffer Chemical Co., Ltd. Method of preparing the catalyst component for α-olefin polymerization
US4182816A (en) 1974-10-30 1980-01-08 Imperial Chemical Industries Limited Olefine polymerization process
US4296222A (en) * 1976-04-13 1981-10-20 Basf Aktiengesellschaft Manufacture of poly-α-olefins
US4354010A (en) 1975-01-09 1982-10-12 Imperial Chemical Industries Limited Transition metal compound
US4400301A (en) 1975-05-28 1983-08-23 Imperial Chemical Industries Plc Transition metal compound

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5116297A (en) * 1974-07-31 1976-02-09 Mitsubishi Chem Ind KOTAISANENKACHITANNO SEIZOHOHO
DE2533511C2 (en) * 1974-07-31 1984-11-29 Mitsubishi Chemical Industries Ltd., Tokio/Tokyo Process for the preparation of solid purple colored finely granulated titanium trichloride and its use for the polymerization of α-olefins
JPS5439549U (en) * 1977-08-24 1979-03-15
JPS5831089B2 (en) * 1979-11-26 1983-07-04 有限会社 東洋ストウフア−・ケミカル Method for producing titanium trichloride catalyst component for α-olefin polymerization
JPS56136805A (en) * 1980-03-29 1981-10-26 Mitsui Petrochem Ind Ltd Titanium catalyst component for olefin polymerization
US4398005A (en) * 1981-01-23 1983-08-09 Gulf Research & Development Company Novel polymerization catalyst and process for using same to polymerize olefins
DE3876411T2 (en) * 1987-07-10 1993-06-24 Quantum Chem Corp PROPYLENE POLYMERIZATION CATALYST AND METHOD.
US5061755A (en) * 1988-10-25 1991-10-29 Mitsubishi Kasei Corporation Polypropylene composition and highly transparent polypropylene film made thereof
KR900016267A (en) * 1989-04-25 1990-11-13 노기 사다오 Titanium trichloride composition for the production of olefin polymers and process for the preparation thereof
JP3336581B2 (en) * 1992-10-19 2002-10-21 富士写真フイルム株式会社 Media inspection method and system for write-once optical disc
CN102119188B (en) 2008-06-17 2014-06-11 溴化合物有限公司 Polypropylene based formulations

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL243666A (en) * 1958-10-10 1900-01-01
DE1570919B2 (en) * 1963-11-05 1970-12-17 Mitsui Toatsu Chemicals, Inc., Tokio Process for the production of Horao- or copolymers of propylene. °
US3492281A (en) * 1967-06-29 1970-01-27 Goodyear Tire & Rubber Process for the polymerization of diolefins with beta titanium trichloride and organoaluminum compounds
DE1720329A1 (en) * 1967-11-30 1971-06-16 Basf Ag Process for the production of polymers from alpha-olefins
US3701763A (en) * 1969-10-20 1972-10-31 Mitsui Petrochemical Ind Process for polymerization of olefins and catalysts therefor
IE35231B1 (en) * 1970-03-26 1975-12-24 Solvay Process for the preparation of a ziegler-natta type catalyst

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4182816A (en) 1974-10-30 1980-01-08 Imperial Chemical Industries Limited Olefine polymerization process
US4354010A (en) 1975-01-09 1982-10-12 Imperial Chemical Industries Limited Transition metal compound
US4400301A (en) 1975-05-28 1983-08-23 Imperial Chemical Industries Plc Transition metal compound
US4098907A (en) 1975-12-16 1978-07-04 Toyo Stauffer Chemical Co., Ltd. Method of preparing the catalyst component for α-olefin polymerization
US4296222A (en) * 1976-04-13 1981-10-20 Basf Aktiengesellschaft Manufacture of poly-α-olefins

Also Published As

Publication number Publication date
FR2160873B1 (en) 1976-04-23
BE791441A (en) 1973-05-16
LU64328A1 (en) 1973-06-21
DE2256780C2 (en) 1986-12-04
DE2256780A1 (en) 1973-05-30
IT968979B (en) 1974-03-20
NL157610B (en) 1978-08-15
JPS5618121B2 (en) 1981-04-27
FR2160873A1 (en) 1973-07-06
JPS5240348B2 (en) 1977-10-12
JPS52138083A (en) 1977-11-17
JPS4864170A (en) 1973-09-05
US4210735A (en) 1980-07-01
NL7215103A (en) 1973-05-28

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee