DE2249813A1 - Thermoplastische hochtemperaturverbindungen und verfahren zu ihrer herstellung - Google Patents
Thermoplastische hochtemperaturverbindungen und verfahren zu ihrer herstellungInfo
- Publication number
- DE2249813A1 DE2249813A1 DE2249813A DE2249813A DE2249813A1 DE 2249813 A1 DE2249813 A1 DE 2249813A1 DE 2249813 A DE2249813 A DE 2249813A DE 2249813 A DE2249813 A DE 2249813A DE 2249813 A1 DE2249813 A1 DE 2249813A1
- Authority
- DE
- Germany
- Prior art keywords
- stabilizer
- filler
- lead
- compounds
- sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001169 thermoplastic Polymers 0.000 title claims description 55
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 55
- 150000001875 compounds Chemical class 0.000 title claims description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 title description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 81
- 239000004800 polyvinyl chloride Substances 0.000 claims description 80
- 239000000203 mixture Substances 0.000 claims description 70
- 239000000945 filler Substances 0.000 claims description 68
- 239000003381 stabilizer Substances 0.000 claims description 59
- 239000004014 plasticizer Substances 0.000 claims description 55
- 239000011347 resin Substances 0.000 claims description 44
- 229920005989 resin Polymers 0.000 claims description 44
- 239000003963 antioxidant agent Substances 0.000 claims description 31
- 239000000654 additive Substances 0.000 claims description 23
- 230000000996 additive effect Effects 0.000 claims description 21
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 21
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000003508 Dilauryl thiodipropionate Substances 0.000 claims description 18
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 claims description 18
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- GTDCAOYDHVNFCP-UHFFFAOYSA-N chloro(trihydroxy)silane Chemical compound O[Si](O)(O)Cl GTDCAOYDHVNFCP-UHFFFAOYSA-N 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 9
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical class [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 claims description 7
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 claims description 7
- 150000003606 tin compounds Chemical class 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 5
- 150000001805 chlorine compounds Chemical class 0.000 claims description 5
- IESWIBSMHJCJAG-UHFFFAOYSA-L dibutyltin(2+);8-methyl-2-(6-methylheptyl)-2-sulfanylnonanoate Chemical compound CCCC[Sn+2]CCCC.CC(C)CCCCCC(S)(C([O-])=O)CCCCCC(C)C.CC(C)CCCCCC(S)(C([O-])=O)CCCCCC(C)C IESWIBSMHJCJAG-UHFFFAOYSA-L 0.000 claims description 5
- YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 claims description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- 150000005690 diesters Chemical class 0.000 claims description 4
- 150000002611 lead compounds Chemical class 0.000 claims description 4
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 4
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 claims description 3
- 239000003490 Thiodipropionic acid Substances 0.000 claims description 3
- 229940065285 cadmium compound Drugs 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 235000019303 thiodipropionic acid Nutrition 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 229930185605 Bisphenol Natural products 0.000 claims 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 2
- 150000002989 phenols Chemical class 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 150000001662 cadmium compounds Chemical class 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 description 49
- 238000009472 formulation Methods 0.000 description 38
- 238000009413 insulation Methods 0.000 description 35
- 238000012360 testing method Methods 0.000 description 34
- 230000032683 aging Effects 0.000 description 33
- 235000006708 antioxidants Nutrition 0.000 description 26
- 230000035515 penetration Effects 0.000 description 24
- 239000000463 material Substances 0.000 description 12
- 239000004020 conductor Substances 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- PIOZZBNFRIZETM-UHFFFAOYSA-L magnesium;2-carbonoperoxoylbenzoic acid;2-oxidooxycarbonylbenzoate Chemical compound [Mg+2].OOC(=O)C1=CC=CC=C1C([O-])=O.OOC(=O)C1=CC=CC=C1C([O-])=O PIOZZBNFRIZETM-UHFFFAOYSA-L 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 230000035882 stress Effects 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910001651 emery Inorganic materials 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 241000156978 Erebia Species 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000012815 thermoplastic material Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 230000003679 aging effect Effects 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 2
- 238000009530 blood pressure measurement Methods 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- DUPIXUINLCPYLU-UHFFFAOYSA-N barium lead Chemical class [Ba].[Pb] DUPIXUINLCPYLU-UHFFFAOYSA-N 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- RUYJNKYXOHIGPH-UHFFFAOYSA-N dialuminum;trioxido(trioxidosilyloxy)silane Chemical compound [Al+3].[Al+3].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] RUYJNKYXOHIGPH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical class [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000012465 retentate Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00192630A US3824202A (en) | 1971-10-26 | 1971-10-26 | High temperature polyvinyl chloride compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2249813A1 true DE2249813A1 (de) | 1973-05-03 |
Family
ID=22710436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2249813A Withdrawn DE2249813A1 (de) | 1971-10-26 | 1972-10-11 | Thermoplastische hochtemperaturverbindungen und verfahren zu ihrer herstellung |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US3824202A (enExample) |
| JP (1) | JPS56458B2 (enExample) |
| AR (1) | AR220088A1 (enExample) |
| AU (1) | AU465566B2 (enExample) |
| BE (1) | BE789366A (enExample) |
| BR (1) | BR7207357D0 (enExample) |
| CA (1) | CA981439A (enExample) |
| DE (1) | DE2249813A1 (enExample) |
| FR (1) | FR2157868B1 (enExample) |
| GB (1) | GB1412994A (enExample) |
| IT (1) | IT970718B (enExample) |
| NL (1) | NL7214505A (enExample) |
| NO (1) | NO137646C (enExample) |
| SE (1) | SE400302B (enExample) |
| SU (1) | SU464121A3 (enExample) |
| ZA (1) | ZA727351B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953650A (en) * | 1972-06-02 | 1976-04-27 | Western Electric Company, Inc. | Strand material covered with clear flame retardant composition |
| US4026852A (en) * | 1975-02-10 | 1977-05-31 | N L Industries, Inc. | High temperature polyvinyl chloride compositions |
| DE2652328A1 (de) * | 1976-11-17 | 1978-05-18 | Neynaber Chemie Gmbh | Bleiverbindungen enthaltende stabilisator-gleitmittel-kombination fuer formmassen auf basis von polyvinylchlorid |
| US4447569A (en) * | 1982-10-08 | 1984-05-08 | Argus Chemical Corporation | Polyvinyl chloride resin compositions having a high volume resistivity and resistance to deterioration when heated at temperatures above 100 degrees C. |
| US5011660A (en) * | 1987-04-10 | 1991-04-30 | Huls America Inc. | Method of sterilizing medical grade film |
| US4839233A (en) * | 1987-04-10 | 1989-06-13 | Huls America, Inc. | Medical grade film and method of sterilizing the same and sterilized medical grade film |
| US5721024A (en) * | 1995-06-07 | 1998-02-24 | Pall Corporation | Material for flexible medical products |
| CN103613884B (zh) * | 2013-12-05 | 2016-01-27 | 山东慧科助剂股份有限公司 | Pvc用高效锌基复合热稳定剂及其制备方法 |
| WO2017110479A1 (ja) * | 2015-12-25 | 2017-06-29 | 日本ゼオン株式会社 | 塩化ビニル樹脂組成物、塩化ビニル樹脂成形体及び積層体 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3091597A (en) * | 1958-12-01 | 1963-05-28 | Union Carbide Corp | Compositions of vinyl chloride homopolymers and vinyl chloride-vinyl acetate copolymers |
| FR1467612A (fr) * | 1966-01-12 | 1967-01-27 | Continental Oil Co | Nouveaux plastifiants pour résines vinyliques et applications |
-
0
- BE BE789366D patent/BE789366A/xx unknown
-
1971
- 1971-10-26 US US00192630A patent/US3824202A/en not_active Expired - Lifetime
-
1972
- 1972-06-22 CA CA145,420A patent/CA981439A/en not_active Expired
- 1972-10-11 DE DE2249813A patent/DE2249813A1/de not_active Withdrawn
- 1972-10-16 ZA ZA727351A patent/ZA727351B/xx unknown
- 1972-10-16 NO NO3698/72A patent/NO137646C/no unknown
- 1972-10-16 FR FR7236602A patent/FR2157868B1/fr not_active Expired
- 1972-10-16 SE SE7213314A patent/SE400302B/xx unknown
- 1972-10-18 AU AU47869/72A patent/AU465566B2/en not_active Expired
- 1972-10-18 GB GB4809972A patent/GB1412994A/en not_active Expired
- 1972-10-19 JP JP10484272A patent/JPS56458B2/ja not_active Expired
- 1972-10-20 BR BR7357/72A patent/BR7207357D0/pt unknown
- 1972-10-20 AR AR244749A patent/AR220088A1/es active
- 1972-10-24 IT IT30865/72A patent/IT970718B/it active
- 1972-10-25 SU SU1840070A patent/SU464121A3/ru active
- 1972-10-26 NL NL7214505A patent/NL7214505A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU4786972A (en) | 1974-04-26 |
| CA981439A (en) | 1976-01-13 |
| FR2157868A1 (enExample) | 1973-06-08 |
| SU464121A3 (ru) | 1975-03-15 |
| IT970718B (it) | 1974-04-20 |
| NO137646B (no) | 1977-12-19 |
| FR2157868B1 (enExample) | 1976-08-20 |
| AU465566B2 (en) | 1975-10-02 |
| NL7214505A (enExample) | 1973-05-01 |
| SE400302B (sv) | 1978-03-20 |
| ZA727351B (en) | 1973-06-27 |
| BR7207357D0 (pt) | 1973-09-13 |
| AR220088A1 (es) | 1980-10-15 |
| GB1412994A (en) | 1975-11-05 |
| NO137646C (no) | 1978-03-29 |
| BE789366A (fr) | 1973-01-15 |
| JPS4851043A (enExample) | 1973-07-18 |
| US3824202A (en) | 1974-07-16 |
| JPS56458B2 (enExample) | 1981-01-08 |
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