DE2220617A1 - Verfahren zur herstellung von wasserstoff - Google Patents
Verfahren zur herstellung von wasserstoffInfo
- Publication number
- DE2220617A1 DE2220617A1 DE19722220617 DE2220617A DE2220617A1 DE 2220617 A1 DE2220617 A1 DE 2220617A1 DE 19722220617 DE19722220617 DE 19722220617 DE 2220617 A DE2220617 A DE 2220617A DE 2220617 A1 DE2220617 A1 DE 2220617A1
- Authority
- DE
- Germany
- Prior art keywords
- methanol
- catalyst
- hydrogen
- temperatures
- water vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 40
- 239000001257 hydrogen Substances 0.000 title claims description 38
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 72
- 239000003054 catalyst Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910002090 carbon oxide Inorganic materials 0.000 claims 1
- 239000012495 reaction gas Substances 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000000629 steam reforming Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N ammonium carbonate Chemical class N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- SXKJCXWNWBRZGB-UHFFFAOYSA-N chromium copper manganese Chemical compound [Mn][Cr][Cu] SXKJCXWNWBRZGB-UHFFFAOYSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722220617 DE2220617A1 (de) | 1972-04-27 | 1972-04-27 | Verfahren zur herstellung von wasserstoff |
| FR7308117A FR2181795A1 (en) | 1972-04-27 | 1973-03-07 | Hydrogen prepn - by reacting methanol vapour and steam in presence of copper catalyst |
| NL7303784A NL7303784A (enrdf_load_stackoverflow) | 1972-04-27 | 1973-03-19 | |
| IT2316173A IT982793B (it) | 1972-04-27 | 1973-04-19 | Processo per la produzione di idrogeno |
| JP4718673A JPS4947281A (enrdf_load_stackoverflow) | 1972-04-27 | 1973-04-24 | |
| BE6044131A BE798785A (fr) | 1972-04-27 | 1973-04-26 | Procede de preparation de l'hydrogene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722220617 DE2220617A1 (de) | 1972-04-27 | 1972-04-27 | Verfahren zur herstellung von wasserstoff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2220617A1 true DE2220617A1 (de) | 1973-11-15 |
Family
ID=5843411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722220617 Pending DE2220617A1 (de) | 1972-04-27 | 1972-04-27 | Verfahren zur herstellung von wasserstoff |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS4947281A (enrdf_load_stackoverflow) |
| BE (1) | BE798785A (enrdf_load_stackoverflow) |
| DE (1) | DE2220617A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2181795A1 (enrdf_load_stackoverflow) |
| IT (1) | IT982793B (enrdf_load_stackoverflow) |
| NL (1) | NL7303784A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996000186A1 (en) * | 1994-06-24 | 1996-01-04 | Johnson Matthey Public Limited Company | Self-sustaining hydrogen generator |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5231995A (en) * | 1975-09-08 | 1977-03-10 | Nissan Motor Co Ltd | Gas generator |
| DE2918405A1 (de) * | 1979-05-08 | 1980-11-20 | Metallgesellschaft Ag | Verfahren zur erzeugung von kohlenmonoxid und wasserstoff aus methanol |
| GB2053957A (en) * | 1979-06-27 | 1981-02-11 | Ici Ltd | Catalytic process involving carbon monoxide and hydrogen |
| BE884720A (fr) * | 1980-08-11 | 1981-02-11 | Catalysts & Chem Europ | Procede de reformage de methanol et dispositif mis en oeuvre |
| JPS5870839A (ja) * | 1981-10-26 | 1983-04-27 | Mitsui Toatsu Chem Inc | メタノ−ルのスチ−ムリフオ−ミング用触媒 |
| JPH07177B2 (ja) * | 1984-10-05 | 1995-01-11 | 川崎重工業株式会社 | メタノ−ル・スチ−ムリフォ−ミング用触媒の製造方法 |
| JPS6291402A (ja) * | 1985-10-16 | 1987-04-25 | Fuji Electric Co Ltd | メタノ−ル改質反応器 |
| FR2608144B1 (fr) * | 1986-12-16 | 1989-03-24 | Inst Francais Du Petrole | Procede de production d'hydrogene par reformage catalytique du methanol a la vapeur d'eau |
| JPH07116517A (ja) * | 1993-10-29 | 1995-05-09 | Takeshi Masumoto | メタノール改質用触媒およびその製造方法並びにメタノールの改質法 |
| EP1298089B1 (en) * | 2000-06-22 | 2005-01-19 | Consejo Superior De Investigaciones Cientificas | Method for obtaining hydrogen by partial methanol oxidation |
| JP2002079101A (ja) * | 2000-09-08 | 2002-03-19 | Hiroshima Industrial Technology Organization | メタノール水蒸気改質用触媒前駆体並びにメタノール水蒸気改質用触媒及びその製造方法 |
| JP4802505B2 (ja) * | 2005-01-28 | 2011-10-26 | 三菱瓦斯化学株式会社 | 触媒反応の実施方法 |
| CN107572478A (zh) * | 2017-09-22 | 2018-01-12 | 重庆润泰节能科技有限公司 | 一种甲醇裂解制氢气的制备方法及含氢燃料 |
| CN112547074A (zh) * | 2020-12-14 | 2021-03-26 | 川化集团有限责任公司 | 一种甲醇水蒸气重整制氢用催化剂、其制备方法及应用 |
-
1972
- 1972-04-27 DE DE19722220617 patent/DE2220617A1/de active Pending
-
1973
- 1973-03-07 FR FR7308117A patent/FR2181795A1/fr not_active Withdrawn
- 1973-03-19 NL NL7303784A patent/NL7303784A/xx unknown
- 1973-04-19 IT IT2316173A patent/IT982793B/it active
- 1973-04-24 JP JP4718673A patent/JPS4947281A/ja active Pending
- 1973-04-26 BE BE6044131A patent/BE798785A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996000186A1 (en) * | 1994-06-24 | 1996-01-04 | Johnson Matthey Public Limited Company | Self-sustaining hydrogen generator |
| AU683760B2 (en) * | 1994-06-24 | 1997-11-20 | Johnson Matthey Public Limited Company | Self-sustaining hydrogen generator |
| US5762658A (en) * | 1994-06-24 | 1998-06-09 | Johnson Matthey Public Limited Company | Self-sustaining hydrogene generator |
Also Published As
| Publication number | Publication date |
|---|---|
| IT982793B (it) | 1974-10-21 |
| JPS4947281A (enrdf_load_stackoverflow) | 1974-05-07 |
| BE798785A (fr) | 1973-10-26 |
| NL7303784A (enrdf_load_stackoverflow) | 1973-10-30 |
| FR2181795A1 (en) | 1973-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2549439C2 (enrdf_load_stackoverflow) | ||
| DE1568864C3 (de) | Verfahren zur Synthese von Methanol | |
| DE68905319T2 (de) | Herstellung von Wasserstoff aus Kohlenwasserstoffen. | |
| DE69309010T2 (de) | Verfahren zur Herstellung eines kohlenoxydreichen Gases | |
| DE3405217C2 (enrdf_load_stackoverflow) | ||
| DE2949588C2 (enrdf_load_stackoverflow) | ||
| EP4112540A1 (de) | Verfahren und vorrichtung zur erzeugung von wasserstoff aus ammoniak | |
| DE2220617A1 (de) | Verfahren zur herstellung von wasserstoff | |
| DE2741852A1 (de) | Verfahren zum dampfreformieren von kohlenwasserstoffen | |
| DE19625093A1 (de) | Verfahren zur Gewinnung von Kohlenmonoxid und Wasserstoff | |
| DE3780182T2 (de) | Herstellungsverfahren von synthesegas. | |
| DE2120315A1 (enrdf_load_stackoverflow) | ||
| DE2815985A1 (de) | Verfahren und vorrichtung zur reformierung von kohlenwasserstoffen | |
| DE2024301C3 (de) | Verfahren zur Herstellung von Methanol | |
| DE3503455C2 (de) | Herstellungsverfahren für ein Reduktionsgas | |
| DE2750006C2 (enrdf_load_stackoverflow) | ||
| DE3420579A1 (de) | Hochleistungs-methanierungsvorrichtung | |
| DE2345230C2 (de) | Verfahren zur Herstellung von künstlichem Erdgas | |
| DE2914806C2 (enrdf_load_stackoverflow) | ||
| DE60116459T2 (de) | Verfahren zur Herstellung eines Wasserstoff und Kohlenmonoxid enthaltenden Gemisches | |
| EP2598618B1 (de) | Verfahren zur herstellung von synthetischem erdgas | |
| DE10156092A1 (de) | Verfahren zur katalytischen Methanolherstellung sowie Vorrichtung zur Duchführung des Verfahrens | |
| DE2460792A1 (de) | Verfahren zur herstellung eines methanreichen gases | |
| DE1965266A1 (de) | Verfahren zur Herstellung von Methanol | |
| DE1567608C3 (de) | Verfahren zur Herstellung eines wasserstoffhaltigen Gases von erhöhtem Druck, insbesondere für die Ammoniaksynthese |