DE2157451A1 - Verfahren und Katalysator zum hydrierenden Entschwefeln von Rohöl oder abgetopptem Rohöl - Google Patents
Verfahren und Katalysator zum hydrierenden Entschwefeln von Rohöl oder abgetopptem RohölInfo
- Publication number
- DE2157451A1 DE2157451A1 DE19712157451 DE2157451A DE2157451A1 DE 2157451 A1 DE2157451 A1 DE 2157451A1 DE 19712157451 DE19712157451 DE 19712157451 DE 2157451 A DE2157451 A DE 2157451A DE 2157451 A1 DE2157451 A1 DE 2157451A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- pores
- radii
- pore volume
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 333
- 239000010779 crude oil Substances 0.000 title claims description 26
- 238000000034 method Methods 0.000 title claims description 19
- 230000008569 process Effects 0.000 title claims description 13
- 239000011148 porous material Substances 0.000 claims description 148
- 238000006477 desulfuration reaction Methods 0.000 claims description 48
- 230000023556 desulfurization Effects 0.000 claims description 48
- 229910052751 metal Inorganic materials 0.000 claims description 41
- 239000002184 metal Substances 0.000 claims description 41
- 150000002739 metals Chemical class 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 27
- 230000000737 periodic effect Effects 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000009826 distribution Methods 0.000 description 42
- 230000032683 aging Effects 0.000 description 35
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 26
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 21
- 229910052717 sulfur Inorganic materials 0.000 description 21
- 239000011593 sulfur Substances 0.000 description 21
- 229910052720 vanadium Inorganic materials 0.000 description 20
- 229940045605 vanadium Drugs 0.000 description 20
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 20
- 230000003197 catalytic effect Effects 0.000 description 15
- 230000000694 effects Effects 0.000 description 15
- 239000007858 starting material Substances 0.000 description 14
- 230000006872 improvement Effects 0.000 description 13
- 229910052759 nickel Inorganic materials 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000012535 impurity Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 241000158147 Sator Species 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- QZYDAIMOJUSSFT-UHFFFAOYSA-N [Co].[Ni].[Mo] Chemical compound [Co].[Ni].[Mo] QZYDAIMOJUSSFT-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 241000451318 Cryptacrus comes Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9096470A | 1970-11-19 | 1970-11-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2157451A1 true DE2157451A1 (de) | 1972-06-15 |
Family
ID=22225148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712157451 Pending DE2157451A1 (de) | 1970-11-19 | 1971-11-19 | Verfahren und Katalysator zum hydrierenden Entschwefeln von Rohöl oder abgetopptem Rohöl |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3730879A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS5544796B1 (cg-RX-API-DMAC10.html) |
| CA (1) | CA957311A (cg-RX-API-DMAC10.html) |
| DE (1) | DE2157451A1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB1365389A (cg-RX-API-DMAC10.html) |
| NL (1) | NL7115994A (cg-RX-API-DMAC10.html) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5141641B2 (cg-RX-API-DMAC10.html) * | 1972-01-06 | 1976-11-11 | ||
| US3844933A (en) * | 1972-10-16 | 1974-10-29 | Hydrocarbon Research Inc | Hydroconversion of coal-derived oils |
| US3876530A (en) * | 1973-08-22 | 1975-04-08 | Gulf Research Development Co | Multiple stage hydrodesulfurization with greater sulfur and metal removal in initial stage |
| US3891541A (en) * | 1973-08-29 | 1975-06-24 | Mobil Oil Corp | Process for demetalizing and desulfurizing residual oil with hydrogen and alumina-supported catalyst |
| US3977961A (en) * | 1974-02-07 | 1976-08-31 | Exxon Research And Engineering Company | Heavy crude conversion |
| US3887455A (en) * | 1974-03-25 | 1975-06-03 | Exxon Research Engineering Co | Ebullating bed process for hydrotreatment of heavy crudes and residua |
| US4054508A (en) * | 1975-02-21 | 1977-10-18 | Mobil Oil Corporation | Demetalation and desulfurization of residual oil utilizing hydrogen and trickle beds of catalysts in three zones |
| US3968029A (en) * | 1975-04-28 | 1976-07-06 | Gulf Research & Development Company | Desulfurization process employing multi-catalyst reactor |
| US4021330A (en) * | 1975-09-08 | 1977-05-03 | Continental Oil Company | Hydrotreating a high sulfur, aromatic liquid hydrocarbon |
| NZ184201A (en) * | 1976-08-12 | 1979-10-25 | Mobil Oil Corp | Residium hydroprocessing catalyst of group vi-b and viii metal sulfides and/or oxides on alumina |
| US4212729A (en) * | 1978-07-26 | 1980-07-15 | Standard Oil Company (Indiana) | Process for demetallation and desulfurization of heavy hydrocarbons |
| US4297242A (en) * | 1978-07-26 | 1981-10-27 | Standard Oil Company (Indiana) | Process for demetallation and desulfurization of heavy hydrocarbons |
| CA1182769A (en) * | 1980-04-10 | 1985-02-19 | Ronald S. Tolberg | Two-bed catalytic hydroprocessing for heavy hydrocarbon feedstocks |
| US4334976A (en) * | 1980-09-12 | 1982-06-15 | Mobil Oil Corporation | Upgrading of residual oil |
| US4421633A (en) * | 1981-03-13 | 1983-12-20 | Mobil Oil Corporation | Low pressure cyclic hydrocracking process using multi-catalyst bed reactor for heavy liquids |
| US4431526A (en) * | 1982-07-06 | 1984-02-14 | Union Oil Company Of California | Multiple-stage hydroprocessing of hydrocarbon oil |
| US4886594A (en) * | 1982-12-06 | 1989-12-12 | Amoco Corporation | Hydrotreating catalyst and process |
| JPS614533A (ja) * | 1984-06-15 | 1986-01-10 | Res Assoc Residual Oil Process<Rarop> | 水素化処理触媒およびこれを用いた重質鉱油の水素化脱硫分解方法 |
| US4913797A (en) * | 1985-11-21 | 1990-04-03 | Mobil Oil Corporation | Catalyst hydrotreating and dewaxing process |
| US4789462A (en) * | 1986-09-29 | 1988-12-06 | Chevron Research Company | Reverse-graded catalyst systems for hydrodemetalation and hydrodesulfurization |
| EP0514549B1 (en) * | 1990-12-07 | 1996-03-13 | Idemitsu Kosan Company Limited | Method of refining crude oil |
| US5851381A (en) * | 1990-12-07 | 1998-12-22 | Idemitsu Kosan Co., Ltd. | Method of refining crude oil |
| US5543036A (en) * | 1993-07-22 | 1996-08-06 | Mobil Oil Corporation | Process for hydrotreating |
| JP2958234B2 (ja) * | 1994-02-19 | 1999-10-06 | 株式会社コスモ総合研究所 | 重質炭化水素油の水素化処理方法 |
| EP2234710A2 (en) * | 2007-11-28 | 2010-10-06 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
| US8372267B2 (en) * | 2008-07-14 | 2013-02-12 | Saudi Arabian Oil Company | Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil |
| WO2010009082A1 (en) * | 2008-07-14 | 2010-01-21 | Saudi Arabian Oil Company | A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system |
| US9260671B2 (en) * | 2008-07-14 | 2016-02-16 | Saudi Arabian Oil Company | Process for the treatment of heavy oils using light hydrocarbon components as a diluent |
| US8491779B2 (en) * | 2009-06-22 | 2013-07-23 | Saudi Arabian Oil Company | Alternative process for treatment of heavy crudes in a coking refinery |
| US10603657B2 (en) | 2016-04-11 | 2020-03-31 | Saudi Arabian Oil Company | Nano-sized zeolite supported catalysts and methods for their production |
| US11084992B2 (en) | 2016-06-02 | 2021-08-10 | Saudi Arabian Oil Company | Systems and methods for upgrading heavy oils |
| US10301556B2 (en) | 2016-08-24 | 2019-05-28 | Saudi Arabian Oil Company | Systems and methods for the conversion of feedstock hydrocarbons to petrochemical products |
| US10689587B2 (en) | 2017-04-26 | 2020-06-23 | Saudi Arabian Oil Company | Systems and processes for conversion of crude oil |
| KR102474319B1 (ko) | 2017-07-17 | 2022-12-08 | 사우디 아라비안 오일 컴퍼니 | 오일 업그레이드 후 정제하여 중유를 가공처리하기 위한 시스템 및 방법 |
| KR102979756B1 (ko) | 2019-03-15 | 2026-06-18 | 루머스 테크놀로지 엘엘씨 | 증기 분해 전 희석 증기를 액상 탄화수소와 혼합하는 방법 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3184403A (en) * | 1960-09-12 | 1965-05-18 | Phillips Petroleum Co | Two-section catalyst bed |
| US3385781A (en) * | 1965-04-01 | 1968-05-28 | Exxon Research Engineering Co | Hydrocracking process |
-
1970
- 1970-11-19 US US00090964A patent/US3730879A/en not_active Expired - Lifetime
-
1971
- 1971-09-15 CA CA122,868A patent/CA957311A/en not_active Expired
- 1971-10-20 GB GB4867871A patent/GB1365389A/en not_active Expired
- 1971-11-11 JP JP8951171A patent/JPS5544796B1/ja active Pending
- 1971-11-19 DE DE19712157451 patent/DE2157451A1/de active Pending
- 1971-11-19 NL NL7115994A patent/NL7115994A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1365389A (en) | 1974-09-04 |
| JPS5544796B1 (cg-RX-API-DMAC10.html) | 1980-11-14 |
| CA957311A (en) | 1974-11-05 |
| NL7115994A (cg-RX-API-DMAC10.html) | 1972-05-24 |
| US3730879A (en) | 1973-05-01 |
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