DE2153437B2 - Reaktor zur Herstellung von Methanol - Google Patents
Reaktor zur Herstellung von MethanolInfo
- Publication number
- DE2153437B2 DE2153437B2 DE2153437A DE2153437A DE2153437B2 DE 2153437 B2 DE2153437 B2 DE 2153437B2 DE 2153437 A DE2153437 A DE 2153437A DE 2153437 A DE2153437 A DE 2153437A DE 2153437 B2 DE2153437 B2 DE 2153437B2
- Authority
- DE
- Germany
- Prior art keywords
- methanol
- pressure
- synthesis
- catalyst
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims description 51
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000003054 catalyst Substances 0.000 claims description 26
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- 238000003786 synthesis reaction Methods 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 16
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims 5
- 238000007906 compression Methods 0.000 claims 5
- 239000000047 product Substances 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 241000282376 Panthera tigris Species 0.000 claims 1
- 241000158147 Sator Species 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- 239000002826 coolant Substances 0.000 claims 1
- CTQZMNHRQCCAJE-UHFFFAOYSA-N copper;iron(2+);oxygen(2-) Chemical class [O-2].[O-2].[Fe+2].[Cu+2] CTQZMNHRQCCAJE-UHFFFAOYSA-N 0.000 claims 1
- 230000001419 dependent effect Effects 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 230000002349 favourable effect Effects 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 230000002101 lytic effect Effects 0.000 claims 1
- 239000007769 metal material Substances 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 8
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 229910000975 Carbon steel Inorganic materials 0.000 description 3
- 238000005253 cladding Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 101100011369 Caenorhabditis elegans egl-26 gene Proteins 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000669 Chrome steel Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 chlorine ions Chemical class 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2153437A DE2153437B2 (de) | 1971-10-27 | 1971-10-27 | Reaktor zur Herstellung von Methanol |
| ZA726256A ZA726256B (en) | 1971-10-27 | 1972-09-13 | Reactor for producing methanol |
| AT808572A AT318551B (de) | 1971-10-27 | 1972-09-20 | Reaktor zur Herstellung von Methanol |
| CS6568A CS161807B2 (show.php) | 1971-10-27 | 1972-09-27 | |
| NLAANVRAGE7213734,A NL172765C (nl) | 1971-10-27 | 1972-10-11 | Reactor voor het bereiden van methanol. |
| ES407581A ES407581A1 (es) | 1971-10-27 | 1972-10-13 | Reactor para la preapracion de metanol. |
| RO72641A RO62310A (show.php) | 1971-10-27 | 1972-10-25 | |
| IT30944/72A IT969922B (it) | 1971-10-27 | 1972-10-26 | Reattore per la produzione di metanolo |
| JP47108404A JPS4849707A (show.php) | 1971-10-27 | 1972-10-27 | |
| GB4978672A GB1389709A (en) | 1971-10-27 | 1972-10-27 | Production of methanol |
| US06/555,860 US4559207A (en) | 1971-10-27 | 1983-11-28 | Reactor for producing methanol and process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2153437A DE2153437B2 (de) | 1971-10-27 | 1971-10-27 | Reaktor zur Herstellung von Methanol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2153437A1 DE2153437A1 (de) | 1973-05-03 |
| DE2153437B2 true DE2153437B2 (de) | 1974-11-21 |
Family
ID=5823487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2153437A Ceased DE2153437B2 (de) | 1971-10-27 | 1971-10-27 | Reaktor zur Herstellung von Methanol |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4559207A (show.php) |
| JP (1) | JPS4849707A (show.php) |
| AT (1) | AT318551B (show.php) |
| CS (1) | CS161807B2 (show.php) |
| DE (1) | DE2153437B2 (show.php) |
| ES (1) | ES407581A1 (show.php) |
| GB (1) | GB1389709A (show.php) |
| IT (1) | IT969922B (show.php) |
| NL (1) | NL172765C (show.php) |
| RO (1) | RO62310A (show.php) |
| ZA (1) | ZA726256B (show.php) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU535073B2 (en) * | 1979-12-17 | 1984-03-01 | Unisearch Limited | Methanol synthesis catalyst and use thereof |
| IT1209532B (it) * | 1984-04-20 | 1989-08-30 | Snam Progetti | Processo per la sintesi di urea e materiale utilizzato nello stesso. |
| US4743432A (en) * | 1984-11-16 | 1988-05-10 | M.A.N. Maschinenfabrik Augsburg-Nurnberg | Vertical reactor for the generation of methanol |
| GB8524025D0 (en) * | 1985-09-30 | 1985-11-06 | Shell Int Research | Chemical equilibrium reaction |
| JPS6331535A (ja) * | 1986-07-23 | 1988-02-10 | Jgc Corp | 炭素析出抑止性含炭素化合物処理装置 |
| US5089532A (en) * | 1989-03-28 | 1992-02-18 | Iowa State University Research Foundation, Inc. | Catalyst, method of producing and using same for production of methanol and higher alcohols |
| US5266281A (en) * | 1989-09-16 | 1993-11-30 | Xytel Technologies Partnership | Catalytic reactor |
| US5079267A (en) * | 1989-09-16 | 1992-01-07 | Xytel Technologies Partnership | Methanol production |
| US5571483A (en) * | 1990-01-26 | 1996-11-05 | Exolon-Esk Company | System of converting environmentally pollutant waste gases to a useful product |
| US5254318A (en) * | 1992-07-20 | 1993-10-19 | Stone & Webster Engineering Corporation | Lined reformer tubes for high pressure reformer reactors |
| US5512255A (en) * | 1994-12-06 | 1996-04-30 | Wright Malta Corporation | Apparatus for producing methanol |
| DE19605572A1 (de) * | 1996-02-15 | 1997-08-21 | Metallgesellschaft Ag | Verfahren zum Erzeugen von Methanol |
| JP4995373B2 (ja) * | 2001-02-20 | 2012-08-08 | 三菱レイヨン株式会社 | 反応管、触媒の製造方法、不飽和アルデヒドおよび不飽和カルボン酸の製造方法 |
| EP1310475A1 (en) * | 2001-11-11 | 2003-05-14 | Methanol Casale S.A. | Process and plant for the heterogeneous synthesis of chemical compounds |
| EP2015866B1 (en) * | 2006-05-08 | 2011-09-14 | CompactGTL plc | Catalytic reactor comprising first and second catalyst |
| BRPI0906447B1 (pt) * | 2008-02-25 | 2022-03-03 | Haldor Topsøe A/S | Método de preparar metanol, e, reator de metanol para uso no mesmo |
| US20200355428A1 (en) | 2019-05-07 | 2020-11-12 | Luke Coleman | Method for synthesis gas purification |
| DE102023114369A1 (de) * | 2023-06-01 | 2024-12-05 | Man Energy Solutions Se | Hochtemperaturreaktor |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1440109A (en) * | 1920-05-03 | 1922-12-26 | Duriron Co | Armored container |
| US1934836A (en) * | 1926-11-26 | 1933-11-14 | Ig Farbenindustrie Ag | Process for the catalytic conversion of hydrocarbons |
| US1909358A (en) * | 1931-06-01 | 1933-05-16 | Selden Co | Catalytic apparatus |
| GB454428A (en) * | 1935-03-29 | 1936-09-29 | Coutts & Company | Improvements relating to the lining of apparatus for use when reacting carbon monoxide with hydrogen at elevated temperature and under pressure |
| US2308307A (en) * | 1939-06-10 | 1943-01-12 | Robinson Engineering Corp | Pipe, pipe lining, and method of making same |
| US2354163A (en) * | 1941-08-06 | 1944-07-18 | Weizmann Charles | Lining for hydrocarbon treating apparatus |
| US2632528A (en) * | 1947-09-27 | 1953-03-24 | Union Oil Co | Iron-group impregnated adsorbent in adsorption process |
| US2662911A (en) * | 1948-10-01 | 1953-12-15 | Metallgesellschaft Ag | Temperature control in the catalytic hydrogenation of carbon monoxide |
| US3326956A (en) * | 1962-06-08 | 1967-06-20 | Ici Ltd | Production of oxygenated hydrocarbons |
| US3152934A (en) * | 1962-10-03 | 1964-10-13 | Allegheny Ludlum Steel | Process for treating austenite stainless steels |
| US3449802A (en) * | 1964-05-18 | 1969-06-17 | Ray E Forsyth | Trim button |
| GB1159035A (en) * | 1965-08-18 | 1969-07-23 | Ici Ltd | Methanol Synthesis. |
| DE1668390C3 (de) * | 1967-09-01 | 1974-07-04 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Methanol |
| GB1245587A (en) * | 1968-04-08 | 1971-09-08 | Ici Ltd | Methanol production |
| US3959177A (en) * | 1973-12-07 | 1976-05-25 | Petrolite Corporation | Multifunctional corrosion inhibitors |
| GB1565419A (en) * | 1976-04-27 | 1980-04-23 | Crucible Inc | Stainless steel welded articles |
| US4405389A (en) * | 1982-10-21 | 1983-09-20 | Ingersoll-Rand Company | Austenitic stainless steel casting alloy for corrosive applications |
-
1971
- 1971-10-27 DE DE2153437A patent/DE2153437B2/de not_active Ceased
-
1972
- 1972-09-13 ZA ZA726256A patent/ZA726256B/xx unknown
- 1972-09-20 AT AT808572A patent/AT318551B/de not_active IP Right Cessation
- 1972-09-27 CS CS6568A patent/CS161807B2/cs unknown
- 1972-10-11 NL NLAANVRAGE7213734,A patent/NL172765C/xx not_active IP Right Cessation
- 1972-10-13 ES ES407581A patent/ES407581A1/es not_active Expired
- 1972-10-25 RO RO72641A patent/RO62310A/ro unknown
- 1972-10-26 IT IT30944/72A patent/IT969922B/it active
- 1972-10-27 JP JP47108404A patent/JPS4849707A/ja active Pending
- 1972-10-27 GB GB4978672A patent/GB1389709A/en not_active Expired
-
1983
- 1983-11-28 US US06/555,860 patent/US4559207A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4559207A (en) | 1985-12-17 |
| RO62310A (show.php) | 1977-08-15 |
| IT969922B (it) | 1974-04-10 |
| CS161807B2 (show.php) | 1975-06-10 |
| NL7213734A (show.php) | 1973-05-02 |
| ES407581A1 (es) | 1975-11-01 |
| AT318551B (de) | 1974-10-25 |
| JPS4849707A (show.php) | 1973-07-13 |
| GB1389709A (en) | 1975-04-09 |
| NL172765B (nl) | 1983-05-16 |
| DE2153437A1 (de) | 1973-05-03 |
| ZA726256B (en) | 1973-06-27 |
| NL172765C (nl) | 1983-10-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8235 | Patent refused |