DE2151104C3 - Verfahren zur Herstellung von Wasserstoffperoxyd - Google Patents
Verfahren zur Herstellung von WasserstoffperoxydInfo
- Publication number
- DE2151104C3 DE2151104C3 DE2151104A DE2151104A DE2151104C3 DE 2151104 C3 DE2151104 C3 DE 2151104C3 DE 2151104 A DE2151104 A DE 2151104A DE 2151104 A DE2151104 A DE 2151104A DE 2151104 C3 DE2151104 C3 DE 2151104C3
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- working
- working solution
- anthraquinone
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 32
- 238000000034 method Methods 0.000 title claims description 21
- 230000008569 process Effects 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000003054 catalyst Substances 0.000 claims description 43
- 239000012224 working solution Substances 0.000 claims description 35
- 238000005984 hydrogenation reaction Methods 0.000 claims description 30
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 150000004056 anthraquinones Chemical class 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 230000036571 hydration Effects 0.000 claims description 4
- 238000006703 hydration reaction Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 125000004151 quinonyl group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- -1 alkyl anthraquinone Chemical class 0.000 claims 4
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims 3
- 230000006872 improvement Effects 0.000 claims 3
- 150000002978 peroxides Chemical class 0.000 claims 3
- 238000002485 combustion reaction Methods 0.000 claims 2
- 230000009467 reduction Effects 0.000 claims 2
- 241000158147 Sator Species 0.000 claims 1
- 230000009471 action Effects 0.000 claims 1
- 230000008859 change Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000011877 solvent mixture Substances 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 239000012808 vapor phase Substances 0.000 claims 1
- 239000008207 working material Substances 0.000 claims 1
- 238000013459 approach Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- 239000012074 organic phase Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- IQDXNHZDRQHKEF-UHFFFAOYSA-N dialuminum;dicalcium;dioxido(oxo)silane Chemical compound [Al+3].[Al+3].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IQDXNHZDRQHKEF-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8280270A | 1970-10-21 | 1970-10-21 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2151104A1 DE2151104A1 (de) | 1972-04-27 |
| DE2151104B2 DE2151104B2 (de) | 1975-03-27 |
| DE2151104C3 true DE2151104C3 (de) | 1975-12-11 |
Family
ID=22173556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2151104A Expired DE2151104C3 (de) | 1970-10-21 | 1971-10-13 | Verfahren zur Herstellung von Wasserstoffperoxyd |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3755552A (OSRAM) |
| JP (1) | JPS5024274B1 (OSRAM) |
| BE (1) | BE774234A (OSRAM) |
| CA (1) | CA955376A (OSRAM) |
| DE (1) | DE2151104C3 (OSRAM) |
| ES (1) | ES396244A1 (OSRAM) |
| FR (1) | FR2111739B1 (OSRAM) |
| GB (1) | GB1361665A (OSRAM) |
| SE (1) | SE382200B (OSRAM) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58116370A (ja) * | 1981-12-29 | 1983-07-11 | 株式会社ブリヂストン | ゴルフボ−ル |
| US4428922A (en) | 1982-05-14 | 1984-01-31 | Fmc Corporation | Process for manufacturing hydrogen peroxide |
| SE431532B (sv) * | 1982-09-08 | 1984-02-13 | Eka Ab | Forfarande vid framstellning av veteperoxid |
| JPS59114158U (ja) * | 1983-01-19 | 1984-08-01 | 住友ゴム工業株式会社 | カラ−ゴルフボ−ル |
| US4485084A (en) * | 1984-02-24 | 1984-11-27 | Fmc Corporation | Hydrogen peroxide process |
| US4539196A (en) * | 1984-04-19 | 1985-09-03 | Fmc Corporation | Process for hydrogenating an alkylated anthraquinone |
| US4514376A (en) * | 1984-04-19 | 1985-04-30 | Fmc Corporation | Pregeneration of tetrahydroanthraquinones in a make-up solution to be added to a hydrogen peroxide working solution |
| FR2610320A1 (fr) * | 1987-02-03 | 1988-08-05 | Atochem | Composes peroxydes renfermant l'isotope 17o |
| FI82669C (fi) * | 1989-01-27 | 1991-04-10 | Kemira Oy | Foerfarande foer framstaellning av vaeteperoxid. |
| SE464867B (sv) * | 1989-02-23 | 1991-06-24 | Eka Nobel Ab | Foerfarande vid framstaellning av vaeteperoxid enligt antrakinonprocessen |
| FI95457C (fi) * | 1994-03-15 | 1996-02-12 | Kemira Chemicals Oy | Menetelmä vetyperoksidin valmistamiseksi ja siinä käytettävä reaktori |
| BE1012267A3 (fr) * | 1998-11-05 | 2000-08-01 | Solvay | Procede de fabrication de peroxyde d'hydrogene. |
| DE19953185A1 (de) | 1999-11-05 | 2001-05-23 | Degussa | Verfahren zur Herstellung von Wasserstoffperoxid |
-
1970
- 1970-10-21 US US00082802A patent/US3755552A/en not_active Expired - Lifetime
-
1971
- 1971-10-06 CA CA124,572A patent/CA955376A/en not_active Expired
- 1971-10-12 JP JP46079937A patent/JPS5024274B1/ja active Pending
- 1971-10-13 DE DE2151104A patent/DE2151104C3/de not_active Expired
- 1971-10-19 FR FR7137484A patent/FR2111739B1/fr not_active Expired
- 1971-10-20 BE BE774234A patent/BE774234A/xx not_active IP Right Cessation
- 1971-10-20 GB GB4875371A patent/GB1361665A/en not_active Expired
- 1971-10-20 SE SE7113299A patent/SE382200B/xx unknown
- 1971-10-21 ES ES396244A patent/ES396244A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE774234A (fr) | 1972-04-20 |
| ES396244A1 (es) | 1974-04-16 |
| SE382200B (sv) | 1976-01-19 |
| JPS5024274B1 (OSRAM) | 1975-08-14 |
| DE2151104A1 (de) | 1972-04-27 |
| FR2111739A1 (OSRAM) | 1972-06-09 |
| FR2111739B1 (OSRAM) | 1974-03-29 |
| US3755552A (en) | 1973-08-28 |
| GB1361665A (en) | 1974-07-30 |
| DE2151104B2 (de) | 1975-03-27 |
| CA955376A (en) | 1974-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8339 | Ceased/non-payment of the annual fee |