DE2133253B2 - Schäumfähige Teilchen aus Styrolpolymerisaten - Google Patents
Schäumfähige Teilchen aus StyrolpolymerisatenInfo
- Publication number
- DE2133253B2 DE2133253B2 DE2133253A DE2133253A DE2133253B2 DE 2133253 B2 DE2133253 B2 DE 2133253B2 DE 2133253 A DE2133253 A DE 2133253A DE 2133253 A DE2133253 A DE 2133253A DE 2133253 B2 DE2133253 B2 DE 2133253B2
- Authority
- DE
- Germany
- Prior art keywords
- percent
- weight
- styrene polymers
- foamable particles
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 32
- 239000002245 particle Substances 0.000 title claims description 16
- 229920000642 polymer Polymers 0.000 title claims description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 29
- 239000000194 fatty acid Substances 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- 239000004604 Blowing Agent Substances 0.000 claims description 10
- 239000003380 propellant Substances 0.000 claims description 7
- 150000005690 diesters Chemical class 0.000 claims description 6
- 150000005691 triesters Chemical class 0.000 claims description 5
- 239000003925 fat Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 17
- 239000004793 Polystyrene Substances 0.000 description 14
- 150000002148 esters Chemical class 0.000 description 14
- 235000011187 glycerol Nutrition 0.000 description 14
- 229920002223 polystyrene Polymers 0.000 description 14
- 238000001816 cooling Methods 0.000 description 11
- -1 glycerol fatty acid Chemical class 0.000 description 11
- 239000011324 bead Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000011049 pearl Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- 238000012432 intermediate storage Methods 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000600 sorbitol Substances 0.000 description 5
- 239000005662 Paraffin oil Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 238000007786 electrostatic charging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- QWTDNUCVQCZILF-UHFFFAOYSA-N iso-pentane Natural products CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE785883D BE785883A (fr) | 1971-07-05 | Particules transformables en mousse a base de polymeres du styrene | |
| DE2133253A DE2133253B2 (de) | 1971-07-05 | 1971-07-05 | Schäumfähige Teilchen aus Styrolpolymerisaten |
| NL7208559A NL7208559A (enExample) | 1971-07-05 | 1972-06-22 | |
| ES404365A ES404365A1 (es) | 1971-07-05 | 1972-06-28 | Procedimiento para la obtencion de particulas esponjables en polimeros de estireno. |
| RO71458A RO62307A (enExample) | 1971-07-05 | 1972-07-01 | |
| DD164135A DD97429A5 (enExample) | 1971-07-05 | 1972-07-03 | |
| AU44144/72A AU460475B2 (en) | 1971-07-05 | 1972-07-03 | Coated foamable styrene polymer particules |
| US00268831A US3789028A (en) | 1971-07-05 | 1972-07-03 | Coated foamable styrene polymer particles |
| IT26554/72A IT962381B (it) | 1971-07-05 | 1972-07-03 | Particelle in grado di espandersi da polimeri stirenici |
| PL1972156497A PL85219B1 (enExample) | 1971-07-05 | 1972-07-04 | |
| DK332872AA DK129852B (da) | 1971-07-05 | 1972-07-04 | Opskummelige partikler af styrenpolymerisater. |
| AT572572A AT315508B (de) | 1971-07-05 | 1972-07-04 | Schäumfähige Teilchen aus Styrolpolymerisaten |
| GB3143572A GB1392467A (en) | 1971-07-05 | 1972-07-05 | Coated foamable styrene polymer particles |
| FR7224304A FR2144800A1 (enExample) | 1971-07-05 | 1972-07-05 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2133253A DE2133253B2 (de) | 1971-07-05 | 1971-07-05 | Schäumfähige Teilchen aus Styrolpolymerisaten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2133253A1 DE2133253A1 (de) | 1973-01-25 |
| DE2133253B2 true DE2133253B2 (de) | 1974-05-02 |
Family
ID=5812649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2133253A Pending DE2133253B2 (de) | 1971-07-05 | 1971-07-05 | Schäumfähige Teilchen aus Styrolpolymerisaten |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3789028A (enExample) |
| AT (1) | AT315508B (enExample) |
| AU (1) | AU460475B2 (enExample) |
| BE (1) | BE785883A (enExample) |
| DD (1) | DD97429A5 (enExample) |
| DE (1) | DE2133253B2 (enExample) |
| DK (1) | DK129852B (enExample) |
| ES (1) | ES404365A1 (enExample) |
| FR (1) | FR2144800A1 (enExample) |
| GB (1) | GB1392467A (enExample) |
| IT (1) | IT962381B (enExample) |
| NL (1) | NL7208559A (enExample) |
| PL (1) | PL85219B1 (enExample) |
| RO (1) | RO62307A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0109492A1 (de) | 1982-10-26 | 1984-05-30 | Hüls Aktiengesellschaft | Verfahren zur Herstellung von verbesserten Formmassen aus kleinteiligen blähfähigen Styrolpolymerisaten durch Beschichten und Verwenden des beschichteten Produktes |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3916076A (en) * | 1971-12-06 | 1975-10-28 | Grace W R & Co | Rupturable polystyrene layered article |
| JPS52127968A (en) * | 1976-04-20 | 1977-10-27 | Hitachi Chemical Co Ltd | Expandable polystyrene powder |
| JPS5856568B2 (ja) * | 1977-02-04 | 1983-12-15 | 日立化成工業株式会社 | 新規発泡性スチレン系樹脂粒子およびその製造法 |
| GB1575990A (en) * | 1977-09-22 | 1980-10-01 | Labofina Sa | Process for producing expandable beads of vinylaromatic poymer resins |
| DE2942182A1 (de) * | 1979-10-18 | 1981-05-07 | Basf Ag, 6700 Ludwigshafen | Teilchenfoermige, treibmittelhaltige styrolpolymerisate und deren verwendung |
| DE3030053A1 (de) * | 1980-08-08 | 1982-03-25 | Basf Ag, 6700 Ludwigshafen | Teilchenfoermige, treibmittelhaltige styrolpolymerisate und deren verwendung |
| US4304797A (en) * | 1980-10-01 | 1981-12-08 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4312957A (en) * | 1980-10-01 | 1982-01-26 | Atlantic Richfield Company | Fast-cooling styrene polymer foams |
| US4278730A (en) * | 1980-10-01 | 1981-07-14 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4304796A (en) * | 1980-10-01 | 1981-12-08 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4278731A (en) * | 1980-10-01 | 1981-07-14 | Arco Polymers, Inc. | Fast-cooling styrene polymer foams |
| US4361656A (en) * | 1981-08-03 | 1982-11-30 | American Hoechst Corporation | Method of making expandable styrene-type polymer beads |
| CA1203950A (en) * | 1982-12-23 | 1986-04-29 | Harold S. Cox | Anti-static articles |
| US4429058A (en) | 1983-04-08 | 1984-01-31 | Cosden Technology, Inc. | Expandable polymeric styrene particles |
| US4439490A (en) * | 1983-04-08 | 1984-03-27 | Cosden Technology, Inc. | Expandable polymeric styrene particles |
| NL8600174A (nl) * | 1986-01-27 | 1987-08-17 | Holland Colours B V | Geexpandeerde en/of expandeerbare kunststofdeeljes met kleurstoflaag, alsmede hieruit gevormd voorwerp. |
| US4792572A (en) * | 1988-02-25 | 1988-12-20 | Texstyrene Plastics, Inc. | Novel particulate expandable styrene polymers having short minimum molding times and method for preparing same |
| US5317044A (en) * | 1989-05-16 | 1994-05-31 | J. M. Huber Corporation | Endothermic blowing agents for surface migration of components in foamed products, compositions and applications |
| US5112528A (en) * | 1990-06-25 | 1992-05-12 | The Dow Chemical Company | Antistatic polyolefin foams and films and method of making the foam and antistatic composition |
| US5071884A (en) * | 1990-06-25 | 1991-12-10 | The Dow Chemical Company | Antistatic polyolefin foams and films and method of making the foam and antistatic composition |
| US5110841A (en) * | 1990-06-25 | 1992-05-05 | The Dow Chemical Company | Antistatic polyolefin foams and films and method of making the foam and antistatic composition |
| JPH08863B2 (ja) * | 1990-12-27 | 1996-01-10 | 積水化成品工業株式会社 | ポリスチレン系樹脂発泡体の製造方法 |
| JPH05112665A (ja) | 1991-03-20 | 1993-05-07 | Hitachi Chem Co Ltd | 発泡性樹脂組成物、これを用いた熱可塑性発泡模型及び金属鋳造物の製造法 |
| IT1289606B1 (it) * | 1997-01-30 | 1998-10-15 | Enichem Spa | Procedimento per la produzione di particelle espandibili di polimeri stirenici |
| EP2230905A2 (en) * | 2007-12-21 | 2010-09-29 | Basf Se | Process for the production of insecticide-modified bead material composed of expandable polystyrene and insecticide-modified moldings obtainable therefrom |
| TW200934843A (en) * | 2007-12-21 | 2009-08-16 | Basf Se | Insecticide-modified bead material composed of expandable polystyrene and insecticide-modified moldings obtainable therefrom |
| BRPI0919713A2 (pt) * | 2008-10-22 | 2015-08-18 | Basf Se | Processo para produzir peças moldadas de espuma de poliestireno extrudada providas com inseticida, peça moldada de espuma de poliestireno extruturada, uso da mesma, e, processo para proteger uma construção contra cupins |
| EP3897131A1 (en) | 2018-12-18 | 2021-10-27 | Bayer Aktiengesellschaft | Insecticidal formulation for vector and pest control with increased contact efficacy |
-
0
- BE BE785883D patent/BE785883A/xx unknown
-
1971
- 1971-07-05 DE DE2133253A patent/DE2133253B2/de active Pending
-
1972
- 1972-06-22 NL NL7208559A patent/NL7208559A/xx unknown
- 1972-06-28 ES ES404365A patent/ES404365A1/es not_active Expired
- 1972-07-01 RO RO71458A patent/RO62307A/ro unknown
- 1972-07-03 IT IT26554/72A patent/IT962381B/it active
- 1972-07-03 AU AU44144/72A patent/AU460475B2/en not_active Expired
- 1972-07-03 US US00268831A patent/US3789028A/en not_active Expired - Lifetime
- 1972-07-03 DD DD164135A patent/DD97429A5/xx unknown
- 1972-07-04 PL PL1972156497A patent/PL85219B1/pl unknown
- 1972-07-04 AT AT572572A patent/AT315508B/de not_active IP Right Cessation
- 1972-07-04 DK DK332872AA patent/DK129852B/da unknown
- 1972-07-05 GB GB3143572A patent/GB1392467A/en not_active Expired
- 1972-07-05 FR FR7224304A patent/FR2144800A1/fr not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0109492A1 (de) | 1982-10-26 | 1984-05-30 | Hüls Aktiengesellschaft | Verfahren zur Herstellung von verbesserten Formmassen aus kleinteiligen blähfähigen Styrolpolymerisaten durch Beschichten und Verwenden des beschichteten Produktes |
Also Published As
| Publication number | Publication date |
|---|---|
| US3789028A (en) | 1974-01-29 |
| ES404365A1 (es) | 1975-06-01 |
| GB1392467A (en) | 1975-04-30 |
| AT315508B (de) | 1974-05-27 |
| DK129852B (da) | 1974-11-25 |
| BE785883A (fr) | 1973-01-05 |
| RO62307A (enExample) | 1977-09-15 |
| DD97429A5 (enExample) | 1973-05-05 |
| IT962381B (it) | 1973-12-20 |
| DE2133253A1 (de) | 1973-01-25 |
| FR2144800A1 (enExample) | 1973-02-16 |
| AU460475B2 (en) | 1975-04-24 |
| PL85219B1 (enExample) | 1976-04-30 |
| NL7208559A (enExample) | 1973-01-09 |
| AU4414472A (en) | 1974-01-10 |
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