DE2109028A1 - Verbesserte Polyvinylalkoholklebstoffe - Google Patents
Verbesserte PolyvinylalkoholklebstoffeInfo
- Publication number
- DE2109028A1 DE2109028A1 DE19712109028 DE2109028A DE2109028A1 DE 2109028 A1 DE2109028 A1 DE 2109028A1 DE 19712109028 DE19712109028 DE 19712109028 DE 2109028 A DE2109028 A DE 2109028A DE 2109028 A1 DE2109028 A1 DE 2109028A1
- Authority
- DE
- Germany
- Prior art keywords
- adhesive
- polyvinyl alcohol
- amount
- adhesives
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001070 adhesive effect Effects 0.000 title claims description 81
- 239000000853 adhesive Substances 0.000 title claims description 78
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims description 70
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims description 62
- 239000000203 mixture Substances 0.000 claims description 30
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 14
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 12
- 239000004927 clay Substances 0.000 claims description 12
- 239000004327 boric acid Substances 0.000 claims description 11
- 150000001639 boron compounds Chemical class 0.000 claims description 11
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 9
- 238000006460 hydrolysis reaction Methods 0.000 claims description 9
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 8
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 7
- 229920002678 cellulose Polymers 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 6
- 239000002313 adhesive film Substances 0.000 claims description 5
- 238000001879 gelation Methods 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000005304 joining Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 66
- 230000006872 improvement Effects 0.000 description 10
- 238000009472 formulation Methods 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001290 polyvinyl ester Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- -1 amino compound Chemical class 0.000 description 1
- SEGBQNJGOCXIGC-FHERZECASA-N benzyl n-[(2s)-1-[(4-hydroxyoxolan-3-yl)amino]-4-methyl-1-oxopentan-2-yl]carbamate Chemical compound N([C@@H](CC(C)C)C(=O)NC1C(COC1)O)C(=O)OCC1=CC=CC=C1 SEGBQNJGOCXIGC-FHERZECASA-N 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- RDMZIKMKSGCBKK-UHFFFAOYSA-N disodium;(9,11-dioxido-5-oxoboranyloxy-2,4,6,8,10,12,13-heptaoxa-1,3,5,7,9,11-hexaborabicyclo[5.5.1]tridecan-3-yl)oxy-oxoborane;tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].O1B(OB=O)OB(OB=O)OB2OB([O-])OB([O-])OB1O2 RDMZIKMKSGCBKK-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- VPOLVWCUBVJURT-UHFFFAOYSA-N pentadecasodium;pentaborate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] VPOLVWCUBVJURT-UHFFFAOYSA-N 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 239000011097 solid fiberboard Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/54—Inorganic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1409970A | 1970-02-25 | 1970-02-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2109028A1 true DE2109028A1 (de) | 1971-10-28 |
Family
ID=21763519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712109028 Pending DE2109028A1 (de) | 1970-02-25 | 1971-02-25 | Verbesserte Polyvinylalkoholklebstoffe |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3668166A (enExample) |
| CA (1) | CA928881A (enExample) |
| DE (1) | DE2109028A1 (enExample) |
| FR (1) | FR2079033A5 (enExample) |
| GB (1) | GB1337443A (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5670074A (en) * | 1979-11-13 | 1981-06-11 | Unitika Ltd | Cold-curing adhesive for polyvinyl alcohol parer |
| DE3235189A1 (de) * | 1982-09-23 | 1984-03-29 | Hoechst Ag, 6230 Frankfurt | Polymer-granulat, verfahren zu seiner herstellung und seine verwendung |
| JPH0662923B2 (ja) * | 1984-10-31 | 1994-08-17 | 株式会社クラレ | 段ボールの製造方法 |
| US5246752A (en) * | 1986-08-18 | 1993-09-21 | Technicon Instruments Corporation | Method and apparatus for drawing thermoplastic tubing |
| US5684068A (en) * | 1995-07-31 | 1997-11-04 | International Cellulose Corp. | Spray-on insulation |
| UA32305C2 (uk) * | 1999-03-10 | 2002-11-15 | Відкрите Акціонерне Товариство "Концерн Стирол" | Клейова композиція |
| ITPC20000006A1 (it) * | 2000-02-03 | 2000-05-03 | Grafiche Rekord Srl | Metodo per incollare etichette di plastica su contenitori idrorepellenti a mezzo di impianti per colle ad acqua. |
| TWI288168B (en) * | 2005-01-11 | 2007-10-11 | Optimax Tech Corp | Adhesive for polarizer |
| US20090178355A1 (en) * | 2008-01-12 | 2009-07-16 | Bill Pugh | Vapor-permeable, water-resistant sheathing and methods thereof |
| US20100144944A1 (en) * | 2008-12-05 | 2010-06-10 | Package Pavement Co., Inc. | joint filling composition |
| US20110009024A1 (en) * | 2009-07-01 | 2011-01-13 | Berry Plastics Corporation | Roof underlayment |
| DE102009036229B4 (de) | 2009-08-05 | 2015-02-12 | Skw Stickstoffwerke Piesteritz Gmbh | Antibackmittel für harnstoffbasierte Düngemittel, Düngemittelformulierungen mit diesem Antibackmittel und Verfahren zu deren Herstellung |
| US9562178B2 (en) * | 2013-10-31 | 2017-02-07 | Lg Chem, Ltd. | Polyvinylalcohol based resin adhesive for polarizing plate, polarizing plate including same, and an image display device |
| TWI530683B (zh) * | 2014-10-16 | 2016-04-21 | 國立清華大學 | 一種布基生化檢測裝置及其製作方法 |
| US9777472B2 (en) | 2015-10-28 | 2017-10-03 | Awi Licensing Llc | Scrim attachment system |
| US10717903B2 (en) | 2017-10-27 | 2020-07-21 | Blockhead Innovations, Llc | Polystyrene adhesive |
| CN111484808B (zh) * | 2020-04-29 | 2021-11-23 | 常州绿之源高分子材料有限公司 | 一种水溶性涂胶膜 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3087920A (en) * | 1959-10-12 | 1963-04-30 | Kurashiki Rayon Co | Cold-water-soluble polyvinyl alcohol |
| US3320200A (en) * | 1965-03-01 | 1967-05-16 | Du Pont | Polyvinyl alcohol adhesives containing boric acid and hexamethylenetetramine or triethylenediamine as additive to impart quick tack |
-
1970
- 1970-02-25 US US14099A patent/US3668166A/en not_active Expired - Lifetime
-
1971
- 1971-02-24 FR FR7106335A patent/FR2079033A5/fr not_active Expired
- 1971-02-24 CA CA106212A patent/CA928881A/en not_active Expired
- 1971-02-25 DE DE19712109028 patent/DE2109028A1/de active Pending
- 1971-04-19 GB GB2265871A patent/GB1337443A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3668166A (en) | 1972-06-06 |
| CA928881A (en) | 1973-06-19 |
| GB1337443A (en) | 1973-11-14 |
| FR2079033A5 (enExample) | 1971-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHA | Expiration of time for request for examination |