DE2104718A1 - Polyesterharze und deren Verwendung in Tagesleuchtpigmenten - Google Patents
Polyesterharze und deren Verwendung in TagesleuchtpigmentenInfo
- Publication number
- DE2104718A1 DE2104718A1 DE19712104718 DE2104718A DE2104718A1 DE 2104718 A1 DE2104718 A1 DE 2104718A1 DE 19712104718 DE19712104718 DE 19712104718 DE 2104718 A DE2104718 A DE 2104718A DE 2104718 A1 DE2104718 A1 DE 2104718A1
- Authority
- DE
- Germany
- Prior art keywords
- parts
- weight
- daytime
- polyester resins
- fluorescent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims description 19
- 229920001225 polyester resin Polymers 0.000 title claims description 9
- 239000004645 polyester resin Substances 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 239000012876 carrier material Substances 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 7
- 150000008064 anhydrides Chemical group 0.000 description 7
- 239000008096 xylene Substances 0.000 description 7
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 6
- 239000007850 fluorescent dye Substances 0.000 description 6
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 239000000976 ink Substances 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- HNGLTUSOZTYOMM-UHFFFAOYSA-N 12H-benzo[a]xanthene-3,4-dicarboxylic acid Chemical compound C1=CC(=C(C=2C=CC=3OC=4C=CC=CC4CC3C21)C(=O)O)C(=O)O HNGLTUSOZTYOMM-UHFFFAOYSA-N 0.000 description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- PUHANRYRPMENIL-UHFFFAOYSA-N 3-(hydrazinecarbonyl)-10-methoxy-12h-benzo[a]xanthene-4-carboxylic acid Chemical compound OC(=O)C1=C(C(=O)NN)C=CC2=C(CC=3C(=CC=C(C=3)OC)O3)C3=CC=C21 PUHANRYRPMENIL-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000001792 White test Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- -1 aliphatic mercaptans Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical class C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical class CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- VLHZUYUOEGBBJB-UHFFFAOYSA-N hydroxy stearic acid Natural products OCCCCCCCCCCCCCCCCCC(O)=O VLHZUYUOEGBBJB-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical class COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011044 quartzite Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712104718 DE2104718A1 (de) | 1971-02-02 | 1971-02-02 | Polyesterharze und deren Verwendung in Tagesleuchtpigmenten |
| NL7201176A NL7201176A (enExample) | 1971-02-02 | 1972-01-28 | |
| US00222309A US3785989A (en) | 1971-02-02 | 1972-01-31 | Novel daylight fluorescent pigments and process for preparing them |
| IT20054/72A IT954879B (it) | 1971-02-02 | 1972-01-31 | Pigmenti luminescenti alla luce diurna e procedimento per la loro preparazione |
| AT72772A AT316703B (de) | 1971-02-02 | 1972-01-31 | Verfahren zur Herstellung von neuen Tagesleuchtpigmenten |
| AU38485/72A AU467315B2 (en) | 1971-02-02 | 1972-02-01 | Novel daylight fluorescent pigments and process for preparing them |
| CH145472A CH550848A (de) | 1971-02-02 | 1972-02-01 | Verfahren zur herstellung neuer tagesleuchtpigmente. |
| BR000545/72*[A BR7200545D0 (pt) | 1971-02-02 | 1972-02-01 | Processo para a preparacao de novos pigmentos luminosos a luz do dia |
| GB467272A GB1384112A (en) | 1971-02-02 | 1972-02-01 | Daylight fluorescent pigments and process for preparing them |
| CA133,647A CA982806A (en) | 1971-02-02 | 1972-02-01 | Daylight fluorescent pigments and process for preparing them |
| FR7203452A FR2124384B1 (enExample) | 1971-02-02 | 1972-02-02 | |
| BE778876A BE778876A (fr) | 1971-02-02 | 1972-02-02 | Pigments fluorescents et leur preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712104718 DE2104718A1 (de) | 1971-02-02 | 1971-02-02 | Polyesterharze und deren Verwendung in Tagesleuchtpigmenten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2104718A1 true DE2104718A1 (de) | 1972-09-14 |
Family
ID=5797576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712104718 Pending DE2104718A1 (de) | 1971-02-02 | 1971-02-02 | Polyesterharze und deren Verwendung in Tagesleuchtpigmenten |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3785989A (enExample) |
| AT (1) | AT316703B (enExample) |
| AU (1) | AU467315B2 (enExample) |
| BE (1) | BE778876A (enExample) |
| BR (1) | BR7200545D0 (enExample) |
| CA (1) | CA982806A (enExample) |
| CH (1) | CH550848A (enExample) |
| DE (1) | DE2104718A1 (enExample) |
| FR (1) | FR2124384B1 (enExample) |
| GB (1) | GB1384112A (enExample) |
| IT (1) | IT954879B (enExample) |
| NL (1) | NL7201176A (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3922232A (en) * | 1973-11-23 | 1975-11-25 | Hercules Inc | Fluorescent colorants |
| IT1026778B (it) * | 1973-12-06 | 1978-10-20 | Hoechst Ag | Pigmenti luminescenti alla luce diurna processo per la loro preparazione e loro impiego |
| US4226760A (en) * | 1979-05-09 | 1980-10-07 | Tenneco Chemicals, Inc. | Colored rigid thermoplastic resin compositions and a process for their production |
| US4391648A (en) * | 1980-08-20 | 1983-07-05 | Ciba-Geigy Corporation | Particulate pigment compositions |
| US5239012A (en) * | 1991-02-21 | 1993-08-24 | Ppg Industries, Inc. | Ambient temperature curing compositions containing a hydroxy component and an anhydride component and an onium salt |
| SG47903A1 (en) * | 1991-11-12 | 1998-04-17 | Eastman Chem Co | Fluorescent pigment concentrates |
| DE4202911A1 (de) * | 1992-02-01 | 1993-08-05 | Cassella Ag | Farbstoffmischungen zum faerben von textilen hydrophoben fasermaterialien |
| US5498280A (en) * | 1994-11-14 | 1996-03-12 | Binney & Smith Inc. | Phosphorescent and fluorescent marking composition |
| US6531613B1 (en) | 2001-08-20 | 2003-03-11 | 3M Innovative Properties Company | Thioxanthone dyes with improved solubility |
| US6713636B2 (en) | 2001-08-20 | 2004-03-30 | 3M Innovative Properties Company | Thloxanthone dyes with improved solubility and a method of preparing 2-oxybenzanthrones as intermediate materials for making of these dyes |
| US6841236B2 (en) | 2001-08-20 | 2005-01-11 | 3M Innovative Properties Co. | Articles containing thioxanthone dyes |
-
1971
- 1971-02-02 DE DE19712104718 patent/DE2104718A1/de active Pending
-
1972
- 1972-01-28 NL NL7201176A patent/NL7201176A/xx unknown
- 1972-01-31 AT AT72772A patent/AT316703B/de not_active IP Right Cessation
- 1972-01-31 IT IT20054/72A patent/IT954879B/it active
- 1972-01-31 US US00222309A patent/US3785989A/en not_active Expired - Lifetime
- 1972-02-01 BR BR000545/72*[A patent/BR7200545D0/pt unknown
- 1972-02-01 CA CA133,647A patent/CA982806A/en not_active Expired
- 1972-02-01 AU AU38485/72A patent/AU467315B2/en not_active Expired
- 1972-02-01 GB GB467272A patent/GB1384112A/en not_active Expired
- 1972-02-01 CH CH145472A patent/CH550848A/xx not_active IP Right Cessation
- 1972-02-02 BE BE778876A patent/BE778876A/xx unknown
- 1972-02-02 FR FR7203452A patent/FR2124384B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BR7200545D0 (pt) | 1973-08-23 |
| FR2124384A1 (enExample) | 1972-09-22 |
| CH550848A (de) | 1974-06-28 |
| FR2124384B1 (enExample) | 1977-09-02 |
| GB1384112A (en) | 1975-02-19 |
| IT954879B (it) | 1973-09-15 |
| AT316703B (de) | 1974-07-25 |
| AU3848572A (en) | 1973-08-02 |
| US3785989A (en) | 1974-01-15 |
| CA982806A (en) | 1976-02-03 |
| NL7201176A (enExample) | 1972-08-04 |
| AU467315B2 (en) | 1973-08-02 |
| BE778876A (fr) | 1972-08-02 |
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