DE2054019A1 - Bleaching detergent - Google Patents
Bleaching detergentInfo
- Publication number
- DE2054019A1 DE2054019A1 DE19702054019 DE2054019A DE2054019A1 DE 2054019 A1 DE2054019 A1 DE 2054019A1 DE 19702054019 DE19702054019 DE 19702054019 DE 2054019 A DE2054019 A DE 2054019A DE 2054019 A1 DE2054019 A1 DE 2054019A1
- Authority
- DE
- Germany
- Prior art keywords
- enzyme
- hydrogen peroxide
- bleaching
- precursor
- chelate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 27
- 239000003599 detergent Substances 0.000 title claims description 24
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 38
- 102000004190 Enzymes Human genes 0.000 claims abstract description 36
- 108090000790 Enzymes Proteins 0.000 claims abstract description 36
- 239000002243 precursor Substances 0.000 claims abstract description 26
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 239000013522 chelant Substances 0.000 claims abstract description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 239000007844 bleaching agent Substances 0.000 claims abstract description 8
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000014469 Bacillus subtilis Nutrition 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 229960001922 sodium perborate Drugs 0.000 claims description 11
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 11
- 239000012459 cleaning agent Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 108091005804 Peptidases Proteins 0.000 claims description 5
- 239000004753 textile Substances 0.000 claims description 5
- 239000004365 Protease Substances 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical group CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 abstract 1
- 229940088598 enzyme Drugs 0.000 description 30
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 16
- 239000000843 powder Substances 0.000 description 14
- 238000005406 washing Methods 0.000 description 11
- 235000013336 milk Nutrition 0.000 description 9
- 239000008267 milk Substances 0.000 description 9
- 210000004080 milk Anatomy 0.000 description 9
- 244000269722 Thea sinensis Species 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 7
- 102000005158 Subtilisins Human genes 0.000 description 6
- 108010056079 Subtilisins Proteins 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000004965 peroxy acids Chemical class 0.000 description 5
- 235000014347 soups Nutrition 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 4
- 241000227653 Lycopersicon Species 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 235000015067 sauces Nutrition 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 235000013405 beer Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 235000014101 wine Nutrition 0.000 description 3
- CGRRUFNHHQCLDZ-UHFFFAOYSA-N 5-hydroxypyridine-2-carboxylic acid Chemical compound OC(=O)C1=CC=C(O)C=N1 CGRRUFNHHQCLDZ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- VIHYIVKEECZGOU-UHFFFAOYSA-N N-acetylimidazole Chemical compound CC(=O)N1C=CN=C1 VIHYIVKEECZGOU-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 241001092459 Rubus Species 0.000 description 2
- 244000299461 Theobroma cacao Species 0.000 description 2
- 235000009470 Theobroma cacao Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- JEGIFBGJZPYMJS-UHFFFAOYSA-N imidazol-1-yl(phenyl)methanone Chemical compound C1=CN=CN1C(=O)C1=CC=CC=C1 JEGIFBGJZPYMJS-UHFFFAOYSA-N 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000004967 organic peroxy acids Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229940081066 picolinic acid Drugs 0.000 description 2
- 235000020043 port wine Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- LNKRCPCURWJUAY-UHFFFAOYSA-N 2-(2-chloroacetyl)peroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1OOC(=O)CCl LNKRCPCURWJUAY-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- 102000010911 Enzyme Precursors Human genes 0.000 description 1
- 108010062466 Enzyme Precursors Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010037867 Rash macular Diseases 0.000 description 1
- 240000007651 Rubus glaucus Species 0.000 description 1
- 235000011034 Rubus glaucus Nutrition 0.000 description 1
- 235000009122 Rubus idaeus Nutrition 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004133 Sodium thiosulphate Substances 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 229960001138 acetylsalicylic acid Drugs 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 125000003071 maltose group Chemical group 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU60582 | 1970-03-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2054019A1 true DE2054019A1 (en) | 1971-10-07 |
Family
ID=19726308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702054019 Pending DE2054019A1 (en) | 1970-03-24 | 1970-11-03 | Bleaching detergent |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE2054019A1 (enrdf_load_stackoverflow) |
| LU (1) | LU60582A1 (enrdf_load_stackoverflow) |
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0272030A3 (en) * | 1986-12-13 | 1989-03-22 | Interox Chemicals Limited | Bleach activation |
| EP0392592A3 (en) * | 1989-04-13 | 1991-03-20 | Unilever N.V. | Bleach activation |
| EP0408131A3 (en) * | 1989-07-10 | 1991-04-10 | Unilever Nv | Bleach activation |
| WO1995027773A1 (en) * | 1994-04-07 | 1995-10-19 | The Procter & Gamble Company | Bleach compositions comprising bleach activators and bleach catalysts |
| EP0690122A2 (en) | 1994-06-30 | 1996-01-03 | The Procter & Gamble Company | Detergent compositions |
| EP0699745A2 (en) | 1994-08-31 | 1996-03-06 | The Procter & Gamble Company | Automatic dishwashing compositions comprising quaternary ammonium compounds bleach activators and quaternary ammonium |
| US5559261A (en) * | 1995-07-27 | 1996-09-24 | The Procter & Gamble Company | Method for manufacturing cobalt catalysts |
| US5581005A (en) * | 1995-06-16 | 1996-12-03 | The Procter & Gamble Company | Method for manufacturing cobalt catalysts |
| WO1997000311A1 (en) * | 1995-06-16 | 1997-01-03 | The Procter & Gamble Company | Bleach compositions comprising cobalt catalysts |
| US5622646A (en) * | 1994-04-07 | 1997-04-22 | The Procter & Gamble Company | Bleach compositions comprising metal-containing bleach catalysts and antioxidants |
| EP0778342A1 (en) | 1995-12-06 | 1997-06-11 | The Procter & Gamble Company | Detergent compositions |
| US5686014A (en) * | 1994-04-07 | 1997-11-11 | The Procter & Gamble Company | Bleach compositions comprising manganese-containing bleach catalysts |
| US5703034A (en) * | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
| US5705464A (en) * | 1995-06-16 | 1998-01-06 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt catalysts |
| US5798326A (en) * | 1995-02-02 | 1998-08-25 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt III catalysts |
| US5804542A (en) * | 1995-02-02 | 1998-09-08 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt catalysts |
| WO1999026508A1 (en) | 1997-11-21 | 1999-06-03 | The Procter & Gamble Company | Product applicator |
| US5939373A (en) * | 1995-12-20 | 1999-08-17 | The Procter & Gamble Company | Phosphate-built automatic dishwashing composition comprising catalysts |
| US6020294A (en) * | 1995-02-02 | 2000-02-01 | Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt chelated catalysts |
| US6143707A (en) * | 1996-03-19 | 2000-11-07 | The Procter & Gamble Company | Built automatic dishwashing compositions comprising blooming perfume |
| US6479450B1 (en) | 1997-05-26 | 2002-11-12 | Henkel Kommanditgesellschaft Auf Aktien | Bleaching system |
| WO2008125590A1 (de) * | 2007-04-12 | 2008-10-23 | Henkel Ag & Co. Kgaa | Biheteroaryl-metallkomplexe als bleichkatalysatoren |
| WO2008135337A1 (de) * | 2007-04-12 | 2008-11-13 | Henkel Ag & Co. Kgaa | Bis(hydroxychinolin)-metallkomplexe als bleichkatalysatoren |
| EP2545988A2 (en) | 2005-12-15 | 2013-01-16 | International Flavors & Fragrances, Inc. | Encapsulated active material with reduced formaldehyde potential |
| EP3075832A1 (en) | 2015-03-30 | 2016-10-05 | Dalli-Werke GmbH & Co. KG | Manganese-amino acid compounds in cleaning compositions |
| WO2018085315A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Leuco colorants as bluing agents in laundry care compositions, packaging, kits and methods thereof |
| WO2018085300A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Methods of using leuco colorants as bluing agents in laundry care compositions |
| WO2018140454A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Active agent-containing articles and product-shipping assemblies for containing the same |
| WO2018140472A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| WO2018140432A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| WO2018140431A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| EP3444328A1 (en) | 2017-08-18 | 2019-02-20 | The Procter & Gamble Company | Cleaning agent |
| WO2020123889A1 (en) | 2018-12-14 | 2020-06-18 | The Procter & Gamble Company | Foaming fibrous structures comprising particles and methods for making same |
| EP3719192A1 (en) | 2012-01-04 | 2020-10-07 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
| WO2021026556A1 (en) | 2019-08-02 | 2021-02-11 | The Procter & Gamble Company | Foaming compositions for producing a stable foam and methods for making same |
| WO2021097004A1 (en) | 2019-11-15 | 2021-05-20 | The Procter & Gamble Company | Graphic-containing soluble articles and methods for making same |
| WO2022251838A1 (en) | 2021-05-28 | 2022-12-01 | The Procter & Gamble Company | Natural polymer-based fibrous elements comprising a surfactant and methods for making same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8312185D0 (en) * | 1983-05-04 | 1983-06-08 | Unilever Plc | Bleaching and cleaning composition |
-
1970
- 1970-03-24 LU LU60582D patent/LU60582A1/xx unknown
- 1970-11-03 DE DE19702054019 patent/DE2054019A1/de active Pending
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| EP0272030A3 (en) * | 1986-12-13 | 1989-03-22 | Interox Chemicals Limited | Bleach activation |
| EP0392592A3 (en) * | 1989-04-13 | 1991-03-20 | Unilever N.V. | Bleach activation |
| US5114611A (en) * | 1989-04-13 | 1992-05-19 | Lever Brothers Company, Divison Of Conopco, Inc. | Bleach activation |
| EP0408131A3 (en) * | 1989-07-10 | 1991-04-10 | Unilever Nv | Bleach activation |
| US5686014A (en) * | 1994-04-07 | 1997-11-11 | The Procter & Gamble Company | Bleach compositions comprising manganese-containing bleach catalysts |
| US5622646A (en) * | 1994-04-07 | 1997-04-22 | The Procter & Gamble Company | Bleach compositions comprising metal-containing bleach catalysts and antioxidants |
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| CN1066194C (zh) * | 1994-04-07 | 2001-05-23 | 普罗格特-甘布尔公司 | 含有漂白活化剂和漂白催化剂的漂白组合物 |
| EP0690122A2 (en) | 1994-06-30 | 1996-01-03 | The Procter & Gamble Company | Detergent compositions |
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| US5703030A (en) * | 1995-06-16 | 1997-12-30 | The Procter & Gamble Company | Bleach compositions comprising cobalt catalysts |
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| US5581005A (en) * | 1995-06-16 | 1996-12-03 | The Procter & Gamble Company | Method for manufacturing cobalt catalysts |
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| US5703034A (en) * | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
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| US6479450B1 (en) | 1997-05-26 | 2002-11-12 | Henkel Kommanditgesellschaft Auf Aktien | Bleaching system |
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| EP2545988A2 (en) | 2005-12-15 | 2013-01-16 | International Flavors & Fragrances, Inc. | Encapsulated active material with reduced formaldehyde potential |
| WO2008125590A1 (de) * | 2007-04-12 | 2008-10-23 | Henkel Ag & Co. Kgaa | Biheteroaryl-metallkomplexe als bleichkatalysatoren |
| WO2008135337A1 (de) * | 2007-04-12 | 2008-11-13 | Henkel Ag & Co. Kgaa | Bis(hydroxychinolin)-metallkomplexe als bleichkatalysatoren |
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Also Published As
| Publication number | Publication date |
|---|---|
| LU60582A1 (enrdf_load_stackoverflow) | 1971-10-06 |
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