DE2038765A1 - Verfahren zur Trennung von Kohlendioxyd aus einer Mischung saeurefreier Gase - Google Patents
Verfahren zur Trennung von Kohlendioxyd aus einer Mischung saeurefreier GaseInfo
- Publication number
- DE2038765A1 DE2038765A1 DE19702038765 DE2038765A DE2038765A1 DE 2038765 A1 DE2038765 A1 DE 2038765A1 DE 19702038765 DE19702038765 DE 19702038765 DE 2038765 A DE2038765 A DE 2038765A DE 2038765 A1 DE2038765 A1 DE 2038765A1
- Authority
- DE
- Germany
- Prior art keywords
- carbon dioxide
- resin
- layer
- air
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 134
- 239000001569 carbon dioxide Substances 0.000 title claims description 67
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 67
- 239000007789 gas Substances 0.000 title claims description 47
- 238000000034 method Methods 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 12
- 230000008569 process Effects 0.000 title description 12
- 238000000926 separation method Methods 0.000 title description 9
- 239000011347 resin Substances 0.000 claims description 49
- 229920005989 resin Polymers 0.000 claims description 49
- 150000001412 amines Chemical class 0.000 claims description 8
- 239000003456 ion exchange resin Substances 0.000 claims description 6
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 6
- 229920000768 polyamine Polymers 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 claims description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- -1 nitrogen amine Chemical group 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 3
- 239000002775 capsule Substances 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 230000029058 respiratory gaseous exchange Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 description 16
- 230000009102 absorption Effects 0.000 description 15
- 238000010521 absorption reaction Methods 0.000 description 15
- 230000008929 regeneration Effects 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000009833 condensation Methods 0.000 description 11
- 230000005494 condensation Effects 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N divinylbenzene Substances C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000009103 reabsorption Effects 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 206010042674 Swelling Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 230000006012 detection of carbon dioxide Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/07—Processes using organic exchangers in the weakly basic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/206—Ion exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0454—Controlling adsorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84932069A | 1969-08-12 | 1969-08-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2038765A1 true DE2038765A1 (de) | 1971-02-25 |
Family
ID=25305553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702038765 Pending DE2038765A1 (de) | 1969-08-12 | 1970-08-04 | Verfahren zur Trennung von Kohlendioxyd aus einer Mischung saeurefreier Gase |
Country Status (3)
| Country | Link |
|---|---|
| CA (1) | CA934939A (enExample) |
| DE (1) | DE2038765A1 (enExample) |
| GB (1) | GB1296889A (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1307053B1 (it) * | 1999-09-23 | 2001-10-23 | Edison Termoelettrica Spa | Unita' di assorbimento dell'anidride carbonica e metodo dirigenerazione di tale unita'. |
| US6755892B2 (en) * | 2000-08-17 | 2004-06-29 | Hamilton Sundstrand | Carbon dioxide scrubber for fuel and gas emissions |
| WO2006023743A2 (en) | 2004-08-20 | 2006-03-02 | The Trustees Of Columbia University In The City Of New York | Laminar scrubber apparatus for capturing carbon dioxide from air and methods of use |
| US9266051B2 (en) | 2005-07-28 | 2016-02-23 | Carbon Sink, Inc. | Removal of carbon dioxide from air |
| US8088197B2 (en) * | 2005-07-28 | 2012-01-03 | Kilimanjaro Energy, Inc. | Removal of carbon dioxide from air |
| EP1998871A4 (en) | 2006-03-08 | 2010-07-21 | Global Res Technologies Llc | AIR COLLECTOR WITH MEMBRANE FOR THE EXCHANGE OF IONS FOR THE RECORDING OF THE AMBIENT CARBON DIOXIDE |
| CA2664464C (en) | 2006-10-02 | 2015-06-30 | Global Research Technologies, Llc | Method and apparatus for extracting carbon dioxide from air |
| MX2009011180A (es) * | 2007-04-17 | 2009-11-02 | Global Res Technologies Llc | Captura de dioxido de carbono (co2) del aire. |
| AU2008324818A1 (en) | 2007-11-05 | 2009-05-14 | Global Research Technologies, Llc | Removal of carbon dioxide from air |
| JP2011504140A (ja) | 2007-11-20 | 2011-02-03 | グローバル リサーチ テクノロジーズ，エルエルシー | 周囲ｃｏ２を捕捉するための機能性イオン交換膜を備えた空気収集機 |
| US20090232861A1 (en) | 2008-02-19 | 2009-09-17 | Wright Allen B | Extraction and sequestration of carbon dioxide |
| US8999279B2 (en) | 2008-06-04 | 2015-04-07 | Carbon Sink, Inc. | Laminar flow air collector with solid sorbent materials for capturing ambient CO2 |
| US9028590B2 (en) | 2009-10-19 | 2015-05-12 | Lanxess Deutschland Gmbh | Process and apparatus for carbon dioxide and carbonyl sulfide capture via ion exchange resins |
| WO2011049759A1 (en) * | 2009-10-19 | 2011-04-28 | Lanxess Sybron Chemicals, Inc. | Process and apparatus for carbon dioxide capture via ion exchange resins |
| EP3653282A1 (en) * | 2010-04-30 | 2020-05-20 | Peter Eisenberger | System and method for carbon dioxide capture and sequestration |
| DK2794062T3 (en) | 2011-12-22 | 2016-06-27 | Re-N Tech Aps | A method for processing a gas |
| CN104684636B (zh) * | 2012-08-31 | 2020-10-13 | 朗盛西比隆化学公司 | 通过离子交换树脂捕获硫化羰的方法 |
| JP5936517B2 (ja) * | 2012-10-24 | 2016-06-22 | 株式会社日立製作所 | Ｃｏ２回収システム |
| WO2014073004A2 (en) * | 2012-11-08 | 2014-05-15 | Airef Engineers Pvt. Ltd. | Carbondioxide removal system |
| WO2016005226A1 (en) | 2014-07-10 | 2016-01-14 | Climeworks Ag | Steam assisted vacuum desorption process for carbon dioxide capture |
| CA3091524A1 (en) | 2018-02-16 | 2019-08-22 | Carbon Sink, Inc. | Fluidized bed extractors for capture of co2 from ambient air |
| CA3098613A1 (en) | 2018-06-14 | 2019-12-19 | Climeworks Ag | Efficient method and device for adsorption/desorption of carbon dioxide from gas streams |
| CA3179546A1 (en) | 2020-05-27 | 2021-12-02 | Climeworks Ag | Methods and devices for steam driven carbon dioxide capture |
| WO2021239748A1 (en) | 2020-05-27 | 2021-12-02 | Climeworks Ag | Atmospheric steam desorption for direct air capture |
| CA3175191A1 (en) | 2020-05-29 | 2021-12-02 | Alexander SPITERI | Method for capture of carbon dioxide from ambient air and corresponding adsorber structures with a plurality of parallel surfaces |
| WO2024002881A1 (en) | 2022-06-28 | 2024-01-04 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
| KR20250050946A (ko) | 2022-08-15 | 2025-04-15 | 더블유. 엘. 고어 앤드 어소시에이트스, 인코포레이티드 | 주위 공기로부터 이산화탄소의 포집을 향상시키기 위한 구조 및 방법 |
| WO2024132899A1 (en) | 2022-12-21 | 2024-06-27 | Climeworks Ag | Uses of amino sorbents for capturing of co2 from gas streams |
| WO2025008318A1 (en) | 2023-07-05 | 2025-01-09 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
| WO2025114104A2 (en) | 2023-11-27 | 2025-06-05 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
| WO2025228763A1 (en) | 2024-04-30 | 2025-11-06 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
-
1970
- 1970-07-17 CA CA088522A patent/CA934939A/en not_active Expired
- 1970-07-22 GB GB1296889D patent/GB1296889A/en not_active Expired
- 1970-08-04 DE DE19702038765 patent/DE2038765A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| GB1296889A (enExample) | 1972-11-22 |
| CA934939A (en) | 1973-10-09 |
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