DE1965177A1 - Verfahren zur Oxydation von schwefelhaltigen Verbindungen und insbesondere von Mercaptanen zu Disulfiden in Anwesenheit fester katalytischer Massen - Google Patents

Verfahren zur Oxydation von schwefelhaltigen Verbindungen und insbesondere von Mercaptanen zu Disulfiden in Anwesenheit fester katalytischer Massen

Info

Publication number
DE1965177A1
DE1965177A1 DE19691965177 DE1965177A DE1965177A1 DE 1965177 A1 DE1965177 A1 DE 1965177A1 DE 19691965177 DE19691965177 DE 19691965177 DE 1965177 A DE1965177 A DE 1965177A DE 1965177 A1 DE1965177 A1 DE 1965177A1
Authority
DE
Germany
Prior art keywords
phthalocyanine
sulfur
mercaptans
containing compounds
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19691965177
Other languages
German (de)
English (en)
Inventor
Rene Laleuf
Jacqueline Nechtschein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of DE1965177A1 publication Critical patent/DE1965177A1/de
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
    • C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE19691965177 1968-12-31 1969-12-27 Verfahren zur Oxydation von schwefelhaltigen Verbindungen und insbesondere von Mercaptanen zu Disulfiden in Anwesenheit fester katalytischer Massen Pending DE1965177A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR183002 1968-12-31

Publications (1)

Publication Number Publication Date
DE1965177A1 true DE1965177A1 (de) 1970-08-20

Family

ID=8659880

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19691965177 Pending DE1965177A1 (de) 1968-12-31 1969-12-27 Verfahren zur Oxydation von schwefelhaltigen Verbindungen und insbesondere von Mercaptanen zu Disulfiden in Anwesenheit fester katalytischer Massen

Country Status (10)

Country Link
US (1) US3686094A (fi)
BE (1) BE743654A (fi)
BG (1) BG17627A3 (fi)
CH (1) CH503001A (fi)
DE (1) DE1965177A1 (fi)
ES (1) ES375072A1 (fi)
FR (1) FR1602191A (fi)
GB (1) GB1260030A (fi)
LU (1) LU60087A1 (fi)
NL (1) NL6919643A (fi)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3923645A (en) * 1973-09-07 1975-12-02 Ashland Oil Inc Method for oxidizing mercaptans occurring in petroleum refining streams
US4113604A (en) * 1977-05-23 1978-09-12 Uop Inc. Process for treating a sour petroleum distillate with anion exchange resin and with metal phthalocyanine catalyst
AU530970B2 (en) * 1978-07-24 1983-08-04 Uop Inc. Catalytic composite
US4234455A (en) * 1979-04-09 1980-11-18 Uop Inc. Catalyst preparation
US4250022A (en) * 1979-08-15 1981-02-10 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate
US4411776A (en) * 1981-04-04 1983-10-25 Uop Inc. Method for treating mercaptans contained in a sour petroleum distillate
US4556547A (en) * 1982-02-01 1985-12-03 Takeda Chemical Industries, Ltd. Process for treatment of gases
FR2524818A1 (fr) * 1982-04-09 1983-10-14 Raffinage Cie Francaise Nouveau catalyseur d'oxydation de mercaptans en disulfures, son procede de preparation et son application a l'adoucissement des distillats petroliers
US4498978A (en) * 1983-11-29 1985-02-12 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate
FR2586253B1 (fr) * 1985-08-13 1988-08-26 Inst Francais Du Petrole Procede ameliore d'adoucissement de coupes petrolieres
FR2594136B2 (fr) * 1985-08-13 1988-11-04 Inst Francais Du Petrole Procede ameliore d'adoucissement de coupes petrolieres
FR2601263B1 (fr) * 1986-07-11 1988-11-25 Total France Nouveau produit composite catalytique pour l'oxydation des mercaptans et son utilisation pour l'adoucissement des coupes petrolieres.
GB8709060D0 (en) * 1987-04-15 1987-05-20 Shell Int Research Preparation of disulphides
FR2651791B1 (fr) * 1989-09-08 1994-05-20 Total France Cie Raffinage Distr Procede d'adoucissement en lit fixe de coupes petrolieres.
US20100010285A1 (en) * 2008-06-26 2010-01-14 Lumimove, Inc., D/B/A Crosslink Decontamination system

Also Published As

Publication number Publication date
CH503001A (fr) 1971-02-15
BG17627A3 (bg) 1973-11-10
BE743654A (fi) 1970-05-28
ES375072A1 (es) 1972-08-16
GB1260030A (en) 1972-01-12
US3686094A (en) 1972-08-22
NL6919643A (fi) 1970-07-02
FR1602191A (fi) 1970-10-19
LU60087A1 (fi) 1970-02-23

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