DE1956908C3 - Herstellung einer Hydroxylammoniumsalzlösung - Google Patents
Herstellung einer HydroxylammoniumsalzlösungInfo
- Publication number
- DE1956908C3 DE1956908C3 DE1956908A DE1956908A DE1956908C3 DE 1956908 C3 DE1956908 C3 DE 1956908C3 DE 1956908 A DE1956908 A DE 1956908A DE 1956908 A DE1956908 A DE 1956908A DE 1956908 C3 DE1956908 C3 DE 1956908C3
- Authority
- DE
- Germany
- Prior art keywords
- absorption
- ions
- nitric acid
- circulating
- nitrous gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 title claims description 20
- 238000002360 preparation method Methods 0.000 title claims description 3
- 239000012266 salt solution Substances 0.000 title claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 54
- 239000007789 gas Substances 0.000 claims description 33
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical group O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 21
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 20
- 230000015572 biosynthetic process Effects 0.000 claims description 18
- 229910002651 NO3 Inorganic materials 0.000 claims description 14
- -1 nitrate ions Chemical class 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 150000002500 ions Chemical class 0.000 description 15
- 239000007788 liquid Substances 0.000 description 12
- 239000000376 reactant Substances 0.000 description 10
- 230000015556 catabolic process Effects 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 150000002923 oximes Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000006146 oximation reaction Methods 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 239000000337 buffer salt Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical compound O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/02—Preparation of nitrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
- C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/08—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reaction of hydroxylamines with carbonyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrostatic Separation (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6816074A NL6816074A (enExample) | 1968-11-12 | 1968-11-12 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1956908A1 DE1956908A1 (de) | 1970-06-18 |
| DE1956908B2 DE1956908B2 (de) | 1978-07-20 |
| DE1956908C3 true DE1956908C3 (de) | 1979-03-22 |
Family
ID=19805122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1956908A Expired DE1956908C3 (de) | 1968-11-12 | 1969-11-12 | Herstellung einer Hydroxylammoniumsalzlösung |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US3655760A (enExample) |
| AT (1) | AT303698B (enExample) |
| BE (1) | BE741515A (enExample) |
| BG (1) | BG25509A3 (enExample) |
| CH (1) | CH529730A (enExample) |
| CS (1) | CS159254B2 (enExample) |
| DE (1) | DE1956908C3 (enExample) |
| ES (1) | ES373410A1 (enExample) |
| FR (1) | FR2023122A1 (enExample) |
| GB (1) | GB1287302A (enExample) |
| NL (2) | NL6816074A (enExample) |
| NO (1) | NO123936B (enExample) |
| PL (1) | PL82107B1 (enExample) |
| SE (2) | SE364705B (enExample) |
| SU (1) | SU370767A3 (enExample) |
| YU (1) | YU33185B (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3125920A1 (de) | 1981-07-01 | 1983-01-20 | Basf Ag, 6700 Ludwigshafen | "verfahren zur herstellung von sulfiden" |
| NL9201064A (nl) * | 1992-06-16 | 1994-01-17 | Dsm Nv | Werkwijze voor de bereiding en verwerking van een hydroxylammoniumzoutoplossing. |
| JP2012505138A (ja) * | 2008-10-10 | 2012-03-01 | ディーエスエム アイピー アセッツ ビー．ブイ． | アンモニウムイオンの分解 |
-
0
- NL NL135678D patent/NL135678C/xx active
-
1968
- 1968-11-12 NL NL6816074A patent/NL6816074A/xx unknown
-
1969
- 1969-11-10 CH CH1670369A patent/CH529730A/de not_active IP Right Cessation
- 1969-11-10 BE BE741515D patent/BE741515A/xx unknown
- 1969-11-11 GB GB55238/69A patent/GB1287302A/en not_active Expired
- 1969-11-11 YU YU2822/69A patent/YU33185B/xx unknown
- 1969-11-11 ES ES373410A patent/ES373410A1/es not_active Expired
- 1969-11-11 NO NO4476/69A patent/NO123936B/no unknown
- 1969-11-11 SU SU1376599A patent/SU370767A3/ru active
- 1969-11-11 PL PL1969136838A patent/PL82107B1/pl unknown
- 1969-11-12 FR FR6938825A patent/FR2023122A1/fr not_active Withdrawn
- 1969-11-12 US US875724A patent/US3655760A/en not_active Expired - Lifetime
- 1969-11-12 BG BG6900013342A patent/BG25509A3/xx unknown
- 1969-11-12 SE SE15548/69A patent/SE364705B/xx unknown
- 1969-11-12 DE DE1956908A patent/DE1956908C3/de not_active Expired
- 1969-11-12 SE SE15547/69A patent/SE364508B/xx unknown
- 1969-11-12 AT AT1061469A patent/AT303698B/de not_active IP Right Cessation
- 1969-11-12 CS CS745869A patent/CS159254B2/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH529730A (de) | 1972-10-31 |
| DE1956908B2 (de) | 1978-07-20 |
| NL135678C (enExample) | 1900-01-01 |
| CS159254B2 (enExample) | 1974-12-27 |
| FR2023122A1 (enExample) | 1970-08-07 |
| NL6816074A (enExample) | 1970-05-14 |
| BG25509A3 (en) | 1978-10-10 |
| GB1287302A (en) | 1972-08-31 |
| YU33185B (en) | 1976-06-30 |
| ES373410A1 (es) | 1972-02-01 |
| US3655760A (en) | 1972-04-11 |
| SU370767A3 (enExample) | 1973-02-15 |
| SE364508B (enExample) | 1974-02-25 |
| PL82107B1 (enExample) | 1975-10-31 |
| SE364705B (enExample) | 1974-03-04 |
| BE741515A (enExample) | 1970-05-11 |
| YU282269A (en) | 1975-12-31 |
| NO123936B (enExample) | 1972-02-07 |
| AT303698B (de) | 1972-12-11 |
| DE1956908A1 (de) | 1970-06-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |