DE19521308A1 - Gasturbine zur Verbrennung eines Brenngases - Google Patents
Gasturbine zur Verbrennung eines BrenngasesInfo
- Publication number
- DE19521308A1 DE19521308A1 DE19521308A DE19521308A DE19521308A1 DE 19521308 A1 DE19521308 A1 DE 19521308A1 DE 19521308 A DE19521308 A DE 19521308A DE 19521308 A DE19521308 A DE 19521308A DE 19521308 A1 DE19521308 A1 DE 19521308A1
- Authority
- DE
- Germany
- Prior art keywords
- gas
- fuel gas
- combustion
- catalytic
- gas turbine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007789 gas Substances 0.000 title claims abstract description 33
- 239000002737 fuel gas Substances 0.000 title claims description 42
- 238000007084 catalytic combustion reaction Methods 0.000 claims abstract description 12
- 230000003197 catalytic effect Effects 0.000 claims abstract description 9
- 239000000567 combustion gas Substances 0.000 claims abstract 7
- 239000003054 catalyst Substances 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 3
- 241001026509 Kata Species 0.000 claims description 2
- 239000010970 precious metal Substances 0.000 claims description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 42
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 19
- 238000002485 combustion reaction Methods 0.000 abstract description 12
- 239000003345 natural gas Substances 0.000 abstract description 6
- 239000000446 fuel Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 230000005611 electricity Effects 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 229910001930 tungsten oxide Inorganic materials 0.000 description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012813 ignitable substance Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
- F23R3/34—Feeding into different combustion zones
- F23R3/343—Pilot flames, i.e. fuel nozzles or injectors using only a very small proportion of the total fuel to insure continuous combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
- F02C3/26—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension
- F02C3/28—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension using a separate gas producer for gasifying the fuel before combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/40—Continuous combustion chambers using liquid or gaseous fuel characterised by the use of catalytic means
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19521308A DE19521308A1 (de) | 1995-06-12 | 1995-06-12 | Gasturbine zur Verbrennung eines Brenngases |
| PCT/DE1996/001018 WO1996041990A1 (de) | 1995-06-12 | 1996-06-11 | Katalytische gasturbinenbrenner |
| DE59604547T DE59604547D1 (de) | 1995-06-12 | 1996-06-11 | Katalytische gasturbinenbrenner |
| EP96915990A EP0832397B1 (de) | 1995-06-12 | 1996-06-11 | Katalytische gasturbinenbrenner |
| RU98100425A RU2142566C1 (ru) | 1995-06-12 | 1996-06-11 | Газовая турбина для сжигания горючего газа |
| JP9502489A JPH11507428A (ja) | 1995-06-12 | 1996-06-11 | 燃料ガスを燃焼するガスタービン |
| ES96915990T ES2143760T3 (es) | 1995-06-12 | 1996-06-11 | Quemador catalitico para turbinas de gas. |
| IN1092CA1996 IN189223B (forum.php) | 1995-06-12 | 1996-06-12 | |
| US08/990,033 US5904040A (en) | 1995-06-12 | 1997-12-12 | Gas turbine for the combustion of reformed fuel gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19521308A DE19521308A1 (de) | 1995-06-12 | 1995-06-12 | Gasturbine zur Verbrennung eines Brenngases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19521308A1 true DE19521308A1 (de) | 1996-12-19 |
Family
ID=7764160
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19521308A Withdrawn DE19521308A1 (de) | 1995-06-12 | 1995-06-12 | Gasturbine zur Verbrennung eines Brenngases |
| DE59604547T Expired - Fee Related DE59604547D1 (de) | 1995-06-12 | 1996-06-11 | Katalytische gasturbinenbrenner |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59604547T Expired - Fee Related DE59604547D1 (de) | 1995-06-12 | 1996-06-11 | Katalytische gasturbinenbrenner |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5904040A (forum.php) |
| EP (1) | EP0832397B1 (forum.php) |
| JP (1) | JPH11507428A (forum.php) |
| DE (2) | DE19521308A1 (forum.php) |
| ES (1) | ES2143760T3 (forum.php) |
| IN (1) | IN189223B (forum.php) |
| RU (1) | RU2142566C1 (forum.php) |
| WO (1) | WO1996041990A1 (forum.php) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998007652A3 (en) * | 1996-08-22 | 1998-06-11 | Amoco Corp | Process for abatement of nitrogen oxides in exhaust from gas turbine power generation |
| DE10164097A1 (de) * | 2001-12-24 | 2003-07-03 | Alstom Switzerland Ltd | Vormischbrenner mit hoher Flammenstabilität |
| US6834504B2 (en) | 2001-07-26 | 2004-12-28 | Alstom Technology Ltd | Premix burner with high flame stability having a net-like structure within the mixing section |
| DE10160837B4 (de) * | 2001-12-12 | 2006-03-02 | Daimlerchrysler Ag | Verfahren der Mischung von heißen Brennergasen mit Sekundärluft zur Temperaturbegrenzung |
| EP1650499A3 (en) * | 2004-10-20 | 2009-05-06 | United Technologies Corporation | Method and system for rich-lean catalytic combustion |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2791415B1 (fr) * | 1999-03-25 | 2001-06-15 | Sunkiss Aeronautique | Procede de combustion catalytique emettant un rayonnement infrarouge, avec controle de la puissance de ce dernier |
| JP4167039B2 (ja) * | 2002-04-10 | 2008-10-15 | 三菱重工業株式会社 | ガスタービン単独プラントの改造方法、触媒の再利用方法 |
| US7007487B2 (en) * | 2003-07-31 | 2006-03-07 | Mes International, Inc. | Recuperated gas turbine engine system and method employing catalytic combustion |
| EP1510761A1 (de) | 2003-08-13 | 2005-03-02 | Siemens Aktiengesellschaft | Verfahren zur Verbrennung eines fluidischen Brennstoffs sowie Brenner, insbesondere für eine Gasturbine, zur Durchführung des Verfahrens |
| US20050144961A1 (en) * | 2003-12-24 | 2005-07-07 | General Electric Company | System and method for cogeneration of hydrogen and electricity |
| RU2342601C1 (ru) * | 2007-06-14 | 2008-12-27 | Федеральное государственное унитарное предприятие "Центральный институт авиационного моторостроения имени П.И. Баранова" | Газотурбинная установка регенеративного цикла с каталитической камерой сгорания |
| CN101307915B (zh) * | 2008-06-24 | 2010-06-02 | 北京航空航天大学 | 一种燃用乙醇燃料的燃气轮机预蒸发燃烧室 |
| US8381531B2 (en) | 2008-11-07 | 2013-02-26 | Solar Turbines Inc. | Gas turbine fuel injector with a rich catalyst |
| US20120055168A1 (en) | 2010-09-08 | 2012-03-08 | General Electric Company | System and method for producing hydrogen rich fuel |
| CN103154446B (zh) | 2010-10-19 | 2015-05-27 | 阿尔斯通技术有限公司 | 用于运行带有热电联产的联合循环动力设备的方法以及用于实施该方法的联合循环动力设备 |
| US8869502B2 (en) | 2011-01-13 | 2014-10-28 | General Electric Company | Fuel reformer system for a turbomachine system |
| US20130305738A1 (en) * | 2012-05-17 | 2013-11-21 | General Electric Company | System and method for producing hydrogen rich fuel |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3741887A1 (de) * | 1987-12-10 | 1989-06-22 | Asea Brown Boveri | Katalysator und verfahren zu seiner herstellung |
| US5048284A (en) * | 1986-05-27 | 1991-09-17 | Imperial Chemical Industries Plc | Method of operating gas turbines with reformed fuel |
| DE4133337A1 (de) * | 1990-10-08 | 1992-04-09 | Riken Kk | Abgasreiniger und verfahren zum reinigen von abgasen |
| GB2268694A (en) * | 1992-07-14 | 1994-01-19 | Rolls Royce Plc | A catalytic combustion chamber |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB209128A (en) * | 1922-08-01 | 1924-01-01 | Clarence Parshall Byrnes | Improved manufacture of liquid fuel |
| US2839892A (en) * | 1947-10-04 | 1958-06-24 | Rosenthal Henry | Gas turbine cycle employing secondary fuel as a coolant, and utilizing the turbine exhaust gases in chemical reactions |
| DE2260515A1 (de) * | 1972-12-11 | 1974-06-12 | Siemens Ag | Gasturbine mit gleichmaessiger, vollstaendiger verbrennung des ihr zugefuehrten brennstoffes |
| FR2228535A1 (en) * | 1973-05-08 | 1974-12-06 | Engelhard Min & Chem | Adiabatic combustion of carbonaceous fuels - e.g. used I.C. engine and gas turbines |
| US4185456A (en) * | 1976-07-02 | 1980-01-29 | Cummings Donald Ray | Providing energy from the combustion of methanol |
| US4202169A (en) * | 1977-04-28 | 1980-05-13 | Gulf Research & Development Company | System for combustion of gases of low heating value |
| SU1214583A1 (ru) * | 1983-05-26 | 1986-02-28 | Азербайджанский Институт Нефти И Химии Им.М.Азизбекова | Способ очистки газа от сероводорода |
| JPS6153425A (ja) * | 1984-08-24 | 1986-03-17 | Hitachi Ltd | ガスタ−ビン用の燃焼器並びにその燃焼方法 |
| US4811556A (en) * | 1986-10-14 | 1989-03-14 | General Electric Company | Multiple-propellant air vehicle and propulsion system |
| RU2015380C1 (ru) * | 1990-01-17 | 1994-06-30 | Вилен Вагаршевич Азатян | Способ работы газотурбинной установки |
| DE19536836C2 (de) * | 1995-10-02 | 2003-11-13 | Alstom | Verfahren zum Betrieb einer Kraftwerksanlage |
-
1995
- 1995-06-12 DE DE19521308A patent/DE19521308A1/de not_active Withdrawn
-
1996
- 1996-06-11 JP JP9502489A patent/JPH11507428A/ja not_active Ceased
- 1996-06-11 WO PCT/DE1996/001018 patent/WO1996041990A1/de active IP Right Grant
- 1996-06-11 EP EP96915990A patent/EP0832397B1/de not_active Expired - Lifetime
- 1996-06-11 RU RU98100425A patent/RU2142566C1/ru not_active IP Right Cessation
- 1996-06-11 ES ES96915990T patent/ES2143760T3/es not_active Expired - Lifetime
- 1996-06-11 DE DE59604547T patent/DE59604547D1/de not_active Expired - Fee Related
- 1996-06-12 IN IN1092CA1996 patent/IN189223B/en unknown
-
1997
- 1997-12-12 US US08/990,033 patent/US5904040A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5048284A (en) * | 1986-05-27 | 1991-09-17 | Imperial Chemical Industries Plc | Method of operating gas turbines with reformed fuel |
| DE3741887A1 (de) * | 1987-12-10 | 1989-06-22 | Asea Brown Boveri | Katalysator und verfahren zu seiner herstellung |
| DE4133337A1 (de) * | 1990-10-08 | 1992-04-09 | Riken Kk | Abgasreiniger und verfahren zum reinigen von abgasen |
| GB2268694A (en) * | 1992-07-14 | 1994-01-19 | Rolls Royce Plc | A catalytic combustion chamber |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998007652A3 (en) * | 1996-08-22 | 1998-06-11 | Amoco Corp | Process for abatement of nitrogen oxides in exhaust from gas turbine power generation |
| US6834504B2 (en) | 2001-07-26 | 2004-12-28 | Alstom Technology Ltd | Premix burner with high flame stability having a net-like structure within the mixing section |
| DE10160837B4 (de) * | 2001-12-12 | 2006-03-02 | Daimlerchrysler Ag | Verfahren der Mischung von heißen Brennergasen mit Sekundärluft zur Temperaturbegrenzung |
| DE10164097A1 (de) * | 2001-12-24 | 2003-07-03 | Alstom Switzerland Ltd | Vormischbrenner mit hoher Flammenstabilität |
| EP1650499A3 (en) * | 2004-10-20 | 2009-05-06 | United Technologies Corporation | Method and system for rich-lean catalytic combustion |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59604547D1 (de) | 2000-04-06 |
| EP0832397A1 (de) | 1998-04-01 |
| EP0832397B1 (de) | 2000-03-01 |
| US5904040A (en) | 1999-05-18 |
| ES2143760T3 (es) | 2000-05-16 |
| RU2142566C1 (ru) | 1999-12-10 |
| WO1996041990A1 (de) | 1996-12-27 |
| IN189223B (forum.php) | 2003-02-01 |
| JPH11507428A (ja) | 1999-06-29 |
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