DE1294378B - Stabilisierung von Trialkylboranen gegen spontanes Entflammen - Google Patents
Stabilisierung von Trialkylboranen gegen spontanes EntflammenInfo
- Publication number
- DE1294378B DE1294378B DEK62362A DEK0062362A DE1294378B DE 1294378 B DE1294378 B DE 1294378B DE K62362 A DEK62362 A DE K62362A DE K0062362 A DEK0062362 A DE K0062362A DE 1294378 B DE1294378 B DE 1294378B
- Authority
- DE
- Germany
- Prior art keywords
- trialkylboranes
- stabilization
- spontaneous ignition
- against spontaneous
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000002269 spontaneous effect Effects 0.000 title claims description 4
- 230000006641 stabilisation Effects 0.000 title claims description 4
- 238000011105 stabilization Methods 0.000 title claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 6
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 6
- -1 alkyl mercaptans Chemical class 0.000 claims description 4
- VRBQPEMNFYBEJJ-UHFFFAOYSA-N 2-(2-ethoxy-2-oxoethyl)sulfanylacetic acid Chemical compound CCOC(=O)CSCC(O)=O VRBQPEMNFYBEJJ-UHFFFAOYSA-N 0.000 claims description 3
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- CMHHITPYCHHOGT-UHFFFAOYSA-N tributylborane Chemical compound CCCCB(CCCC)CCCC CMHHITPYCHHOGT-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- UYANAUSDHIFLFQ-UHFFFAOYSA-N borinic acid Chemical class OB UYANAUSDHIFLFQ-UHFFFAOYSA-N 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical class CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- GAYUSSOCODCSNF-UHFFFAOYSA-N 1-(dodecyldisulfanyl)dodecane Chemical compound CCCCCCCCCCCCSSCCCCCCCCCCCC GAYUSSOCODCSNF-UHFFFAOYSA-N 0.000 description 1
- AXWKRUFUAGYTHB-UHFFFAOYSA-N 2-butylbenzenethiol Chemical group CCCCC1=CC=CC=C1S AXWKRUFUAGYTHB-UHFFFAOYSA-N 0.000 description 1
- ITOLXGQFDAFXMV-UHFFFAOYSA-N 2-sulfanyltetradecanoic acid Chemical class CCCCCCCCCCCCC(S)C(O)=O ITOLXGQFDAFXMV-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CETBSQOFQKLHHZ-UHFFFAOYSA-N Diethyl disulfide Chemical compound CCSSCC CETBSQOFQKLHHZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 150000003139 primary aliphatic amines Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK62362A DE1294378B (de) | 1967-05-24 | 1967-05-24 | Stabilisierung von Trialkylboranen gegen spontanes Entflammen |
| CH715668A CH494773A (de) | 1967-05-24 | 1968-05-14 | Verfahren zum Verhindern des Entflammens von Trialkylboranen |
| AT473468A AT282643B (de) | 1967-05-24 | 1968-05-16 | Stabilisierungsmittel zum Verhindern des Entflammens von Trialkylboranen |
| NL6807124A NL6807124A (en:Method) | 1967-05-24 | 1968-05-20 | |
| SE6890/68A SE345131B (en:Method) | 1967-05-24 | 1968-05-21 | |
| US731263A US3558718A (en) | 1967-05-24 | 1968-05-22 | Process of stabilizing trialkyl boranes |
| FR1567499D FR1567499A (en:Method) | 1967-05-24 | 1968-05-22 | |
| DK237868AA DK119054B (da) | 1967-05-24 | 1968-05-22 | Fremgangsmåde til stabilisering af trialkylboraner mod spontan antændelse. |
| GB25085/68A GB1152421A (en) | 1967-05-24 | 1968-05-24 | A process of preventing inflammation of trialkyl boranes |
| BE715658D BE715658A (en:Method) | 1967-05-24 | 1968-05-24 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK62362A DE1294378B (de) | 1967-05-24 | 1967-05-24 | Stabilisierung von Trialkylboranen gegen spontanes Entflammen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1294378B true DE1294378B (de) | 1969-05-08 |
Family
ID=7230567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEK62362A Pending DE1294378B (de) | 1967-05-24 | 1967-05-24 | Stabilisierung von Trialkylboranen gegen spontanes Entflammen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3558718A (en:Method) |
| AT (1) | AT282643B (en:Method) |
| BE (1) | BE715658A (en:Method) |
| CH (1) | CH494773A (en:Method) |
| DE (1) | DE1294378B (en:Method) |
| DK (1) | DK119054B (en:Method) |
| FR (1) | FR1567499A (en:Method) |
| GB (1) | GB1152421A (en:Method) |
| NL (1) | NL6807124A (en:Method) |
| SE (1) | SE345131B (en:Method) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0002142A1 (fr) * | 1977-10-01 | 1979-05-30 | Société d'Expansion Scientifique Expansia | Complexes de boranes, leur préparation et leur utilisation dans des réactions d'hydroboration et de réduction |
| WO1993021238A3 (en) * | 1992-04-14 | 1994-01-20 | Minnesota Mining & Mfg | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| EP0751175B2 (de) † | 1995-06-26 | 2010-06-09 | Elotex AG | Dispersionspulver mit erhöhter Selbstentzündungstemperatur |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3207263A1 (de) * | 1982-03-01 | 1983-09-08 | Henkel KGaA, 4000 Düsseldorf | Organo-borverbindungen enthaltende stoffgemische, verfahren zu ihrer herstellung und ihre verwendung |
-
1967
- 1967-05-24 DE DEK62362A patent/DE1294378B/de active Pending
-
1968
- 1968-05-14 CH CH715668A patent/CH494773A/de not_active IP Right Cessation
- 1968-05-16 AT AT473468A patent/AT282643B/de not_active IP Right Cessation
- 1968-05-20 NL NL6807124A patent/NL6807124A/xx unknown
- 1968-05-21 SE SE6890/68A patent/SE345131B/xx unknown
- 1968-05-22 DK DK237868AA patent/DK119054B/da unknown
- 1968-05-22 FR FR1567499D patent/FR1567499A/fr not_active Expired
- 1968-05-22 US US731263A patent/US3558718A/en not_active Expired - Lifetime
- 1968-05-24 BE BE715658D patent/BE715658A/xx unknown
- 1968-05-24 GB GB25085/68A patent/GB1152421A/en not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| None * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0002142A1 (fr) * | 1977-10-01 | 1979-05-30 | Société d'Expansion Scientifique Expansia | Complexes de boranes, leur préparation et leur utilisation dans des réactions d'hydroboration et de réduction |
| WO1993021238A3 (en) * | 1992-04-14 | 1994-01-20 | Minnesota Mining & Mfg | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| EP0751175B2 (de) † | 1995-06-26 | 2010-06-09 | Elotex AG | Dispersionspulver mit erhöhter Selbstentzündungstemperatur |
Also Published As
| Publication number | Publication date |
|---|---|
| SE345131B (en:Method) | 1972-05-15 |
| AT282643B (de) | 1970-07-10 |
| BE715658A (en:Method) | 1968-10-16 |
| DK119054B (da) | 1970-11-09 |
| FR1567499A (en:Method) | 1969-05-16 |
| GB1152421A (en) | 1969-05-21 |
| CH494773A (de) | 1970-08-15 |
| NL6807124A (en:Method) | 1968-11-25 |
| US3558718A (en) | 1971-01-26 |
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