DE1263713B - Verfahren zur Herstellung eines Katalysators zur Polymerisation von Butadien-1, 3 - Google Patents
Verfahren zur Herstellung eines Katalysators zur Polymerisation von Butadien-1, 3Info
- Publication number
- DE1263713B DE1263713B DEU12139A DEU0012139A DE1263713B DE 1263713 B DE1263713 B DE 1263713B DE U12139 A DEU12139 A DE U12139A DE U0012139 A DEU0012139 A DE U0012139A DE 1263713 B DE1263713 B DE 1263713B
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- butadiene
- polymerization
- cadmium
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 20
- 238000006116 polymerization reaction Methods 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 17
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 6
- 239000003849 aromatic solvent Substances 0.000 claims description 6
- 229910052793 cadmium Inorganic materials 0.000 claims description 6
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229940065285 cadmium compound Drugs 0.000 claims description 3
- 150000001662 cadmium compounds Chemical class 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000000243 solution Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000005062 Polybutadiene Substances 0.000 description 5
- -1 bis-triphenylphosphine-cadmium chloride Chemical compound 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000003679 aging effect Effects 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40833564A | 1964-11-02 | 1964-11-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1263713B true DE1263713B (de) | 1968-03-21 |
Family
ID=23615841
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEU12139A Pending DE1263713B (de) | 1964-11-02 | 1965-10-22 | Verfahren zur Herstellung eines Katalysators zur Polymerisation von Butadien-1, 3 |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1263713B (enrdf_load_stackoverflow) |
| GB (1) | GB1050828A (enrdf_load_stackoverflow) |
| NL (2) | NL6513432A (enrdf_load_stackoverflow) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT213051B (de) * | 1958-04-24 | 1961-01-25 | Montedison Spa | Verfahren zum Polymerisieren von Diolefinen mit wenigstens einer Vinyldoppelbindung |
-
0
- NL NL126768D patent/NL126768C/xx active
- GB GB1050828D patent/GB1050828A/en active Active
-
1965
- 1965-10-18 NL NL6513432A patent/NL6513432A/xx unknown
- 1965-10-22 DE DEU12139A patent/DE1263713B/de active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT213051B (de) * | 1958-04-24 | 1961-01-25 | Montedison Spa | Verfahren zum Polymerisieren von Diolefinen mit wenigstens einer Vinyldoppelbindung |
Also Published As
| Publication number | Publication date |
|---|---|
| NL126768C (enrdf_load_stackoverflow) | |
| GB1050828A (enrdf_load_stackoverflow) | |
| NL6513432A (enrdf_load_stackoverflow) | 1966-05-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2157405C3 (de) | Verfahren zur Herstellung von polymeren Kohlenwasserstoffen mit reaktiven SiIyIe ndgruppen | |
| EP0305909B1 (de) | Bifunktionelle Alkaliverbindungen, Verfahren zu ihrer Herstellung und Verwendung als Polymerisationsinitiatoren | |
| DE1945358C3 (de) | Niedermolekulare Polyalkenamere und Verfahren zu deren Herstellung | |
| DE2105161A1 (de) | Polyalkenamere und Verfahren zu deren Herstellung | |
| DE2053484A1 (de) | Verfahren zur Herstellung von flussi gem Polybutadien | |
| DE2605247A1 (de) | Metallhaltige polymere, ihre herstellung und verwendung | |
| DE1263713B (de) | Verfahren zur Herstellung eines Katalysators zur Polymerisation von Butadien-1, 3 | |
| DE69416552T2 (de) | Alkylierte Harze aus polycyclischen aromatischen Verbindungen | |
| DE2131355A1 (de) | Verfahren zur herstellung von copolyalkenameren | |
| DE1668300A1 (de) | Neue organometallische Komplexe und ihre Anwendung bei der Herstellung von Katalysatoren fuer die Oligomerisation,Polymerisation und Copolymerisation von ungesaettigten Kohlenwasserstoffen | |
| DE2127621C3 (de) | Verfahren zur Herstellung von Polybutadien mit überwiegend cis-l,4-Struktur | |
| DE2433904C3 (de) | Katalysatorsystem für die Polymerisation von Äthylen und dessen Verwendung zur Polymerisation von Äthylen | |
| DE1186631B (de) | Verfahren zur Herstellung von niedermolekularem niedrigviskosem cis-1, 4-Polybutadien | |
| EP0212153B1 (de) | Niedermolekulare Polyalkenamere und deren Verwendung | |
| DE1251029B (de) | Verfah ren zur Polymerisation \on Isopren | |
| DE1620931A1 (de) | Verfahren zur Polymerisation und Mischpolymerisation konjugierter Diene | |
| DE1520444B2 (de) | Verfahren zur Polymerisation von Kthylen | |
| DE2263312C3 (de) | Verfahren zur Polymerisation von gegebenenfalls substituierten Cycloolefinen | |
| DE1118461B (de) | Verfahren zur Herstellung von Polymeren aus Propylen, Butadien, Isopren oder Chloropren | |
| DE2537385C3 (de) | Verfahren zur Herstellung von thermostabilen, bromierten Oligomerisaten monovinylaromatischer Verbindungen | |
| DE2102964C3 (de) | Verfahren zur Herstellung von cis-1,4-Polyisopren und Katalysatorsystem zur Durchführung dieses Verfahrens | |
| AT215428B (de) | Verfahren zur Herstellung von neuen kristallisierbaren organometallischen Komplexen | |
| DE1770545C (de) | Verfahren zur Herstellung von 1,2 Polybutadien | |
| DE2102964B2 (de) | Verfahren zur herstellung von cis- 1,4-polyisopren und katalysatorsystem zur durchfuehrung dieses verfahrens | |
| DE2620597A1 (de) | Verfahren zur polymerisation von olefinen |