DE1222676B - Verfahren und Vorrichtung zur Polymerisation von Monoolefinen - Google Patents
Verfahren und Vorrichtung zur Polymerisation von MonoolefinenInfo
- Publication number
- DE1222676B DE1222676B DEB67195A DEB0067195A DE1222676B DE 1222676 B DE1222676 B DE 1222676B DE B67195 A DEB67195 A DE B67195A DE B0067195 A DEB0067195 A DE B0067195A DE 1222676 B DE1222676 B DE 1222676B
- Authority
- DE
- Germany
- Prior art keywords
- stirrer
- parts
- monoolefins
- fluidized bed
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 15
- 150000005673 monoalkenes Chemical class 0.000 title claims description 15
- 238000006116 polymerization reaction Methods 0.000 title claims description 15
- 239000003054 catalyst Substances 0.000 claims description 32
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
- 239000005977 Ethylene Substances 0.000 claims description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 6
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- 229910000423 chromium oxide Inorganic materials 0.000 claims 1
- -1 polyethylene Polymers 0.000 description 23
- 239000004698 Polyethylene Substances 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- NZMAJUHVSZBJHL-UHFFFAOYSA-N n,n-dibutylformamide Chemical compound CCCCN(C=O)CCCC NZMAJUHVSZBJHL-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical class NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SBOJXQVPLKSXOG-UHFFFAOYSA-N o-amino-hydroxylamine Chemical class NON SBOJXQVPLKSXOG-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
- B01J8/382—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it with a rotatable device only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE632184D BE632184A (en, 2012) | 1962-05-11 | ||
| DEB67195A DE1222676B (de) | 1962-05-11 | 1962-05-11 | Verfahren und Vorrichtung zur Polymerisation von Monoolefinen |
| GB17931/63A GB1037103A (en) | 1962-05-11 | 1963-05-07 | Process and apparatus for the polymerisation of monoolefines |
| US279222A US3300457A (en) | 1962-05-11 | 1963-05-09 | Process and apparatus for the polymerization of monoolefines |
| JP2379063A JPS41597B1 (en, 2012) | 1962-05-11 | 1963-05-10 | |
| FR934511A FR1363459A (fr) | 1962-05-11 | 1963-05-11 | Procédé et dispositif pour la polymérisation de monooléfines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB67195A DE1222676B (de) | 1962-05-11 | 1962-05-11 | Verfahren und Vorrichtung zur Polymerisation von Monoolefinen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1222676B true DE1222676B (de) | 1966-08-11 |
Family
ID=6975425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB67195A Pending DE1222676B (de) | 1962-05-11 | 1962-05-11 | Verfahren und Vorrichtung zur Polymerisation von Monoolefinen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3300457A (en, 2012) |
| JP (1) | JPS41597B1 (en, 2012) |
| BE (1) | BE632184A (en, 2012) |
| DE (1) | DE1222676B (en, 2012) |
| GB (1) | GB1037103A (en, 2012) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3669948A (en) * | 1970-09-04 | 1972-06-13 | Chisso Corp | Method for producing poly{60 -olefins |
| US4098979A (en) * | 1970-12-29 | 1978-07-04 | Sumitomo Chemical Company, Limited | Method for preparing easily processable polyolefin granule |
| CH543546A (fr) * | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| DE2331103C2 (de) * | 1973-06-19 | 1983-12-08 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen kleinteiliger Homo- oder Copolymerisate des Äthylens |
| US3965083A (en) * | 1974-12-16 | 1976-06-22 | Standard Oil Company | Process for the vapor phase polymerization of monomers in a horizontal, quench-cooled, stirred-bed reactor using essentially total off-gas recycle and melt finishing |
| CA1053846A (en) * | 1974-12-16 | 1979-05-01 | The Standard Oil Company | Horizontal reactor for the vapor phase polymerization of monomers |
| US4021599A (en) * | 1975-08-04 | 1977-05-03 | Gulf Research & Development Company | Olefin polymerization process and catalyst |
| DE2539103C2 (de) * | 1975-09-03 | 1985-06-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Wärmeabfuhr bei der Homo- oder Mischpolymerisation von Äthylen in der Gasphase |
| US4256866A (en) * | 1976-06-16 | 1981-03-17 | Standard Oil Company (Indiana) | Polymerization process |
| EP0067607B1 (en) * | 1981-06-02 | 1987-01-21 | Asahi Kasei Kogyo Kabushiki Kaisha | A catalyst for polymerization of olefins |
| US4543399A (en) * | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) * | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US5225458A (en) * | 1986-10-02 | 1993-07-06 | Bp Chemicals Limited | Powder of (co)polymer of one or more 1-olefins blended with pulverulent inorganic material |
| KR0140525B1 (ko) * | 1989-02-03 | 1998-06-01 | 미다 가쓰시게 | 고점성물질의 제조장치 및 제조방법 |
| TW203062B (en, 2012) * | 1990-11-15 | 1993-04-01 | Sumitomo Chemical Co | |
| US6384156B1 (en) | 1994-08-02 | 2002-05-07 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization process |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US6113862A (en) * | 1997-04-23 | 2000-09-05 | Union Carbide Chemicals & Plastics Technology Corporation | Fluidized bed polymerization reactor with multiple fluidization grids |
| US6117399A (en) * | 1997-04-23 | 2000-09-12 | Union Carbide Chemicals & Plastics Technology Corporation | Fluidized bed polymerization reactor with multiple fluidization grids |
| JP2004532909A (ja) * | 2001-03-27 | 2004-10-28 | ユニオン・カーバイド・ケミカルズ・アンド・プラスチックス・テクノロジー・コーポレーション | 第４族金属錯体触媒を用いるポリマーの気相製造方法 |
| JP3465708B1 (ja) * | 2002-06-26 | 2003-11-10 | Ｊｆｅエンジニアリング株式会社 | 粉状廃棄物の加熱処理装置 |
| US7829512B2 (en) * | 2003-10-17 | 2010-11-09 | Exxonmobil Research And Engineering Company | Method and equipment for making a complex lithium grease |
| CN104096519B (zh) * | 2014-07-28 | 2017-09-12 | 中国科学院宁波材料技术与工程研究所 | 流化床反应器及其应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2936303A (en) * | 1958-04-25 | 1960-05-10 | Phillips Petroleum Co | Olefin polymerization |
| US3002963A (en) * | 1957-04-22 | 1961-10-03 | Phillips Petroleum Co | Gas phase polymerization utilizing a free-settling, fluidized catalyst and reactor system therefor |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2245029A (en) * | 1939-10-24 | 1941-06-10 | Western Electric Co | Mixing device |
| US2592709A (en) * | 1950-02-25 | 1952-04-15 | Universal Oil Prod Co | Mixing and homogenizing apparatus |
| DE1064718B (de) * | 1955-02-04 | 1959-09-03 | Gelsenberg Benzin Ag | Verfahren zur Polymerisation von Olefinen oder olefinhaltigen Gasen |
| BE546871A (en, 2012) * | 1955-04-09 | |||
| US2860127A (en) * | 1957-02-06 | 1958-11-11 | Phillips Petroleum Co | Start-up of a polymerization process |
| US2996492A (en) * | 1957-10-01 | 1961-08-15 | Exxon Research Engineering Co | Recovery process for high molecular weight polymers |
-
0
- BE BE632184D patent/BE632184A/xx unknown
-
1962
- 1962-05-11 DE DEB67195A patent/DE1222676B/de active Pending
-
1963
- 1963-05-07 GB GB17931/63A patent/GB1037103A/en not_active Expired
- 1963-05-09 US US279222A patent/US3300457A/en not_active Expired - Lifetime
- 1963-05-10 JP JP2379063A patent/JPS41597B1/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3002963A (en) * | 1957-04-22 | 1961-10-03 | Phillips Petroleum Co | Gas phase polymerization utilizing a free-settling, fluidized catalyst and reactor system therefor |
| US2936303A (en) * | 1958-04-25 | 1960-05-10 | Phillips Petroleum Co | Olefin polymerization |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1037103A (en) | 1966-07-27 |
| BE632184A (en, 2012) | |
| JPS41597B1 (en, 2012) | 1966-01-21 |
| US3300457A (en) | 1967-01-24 |
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