DE1220135B - Verfahren zur Herstellung kaeltebestaendiger Polyvinylesterlatices - Google Patents
Verfahren zur Herstellung kaeltebestaendiger PolyvinylesterlaticesInfo
- Publication number
- DE1220135B DE1220135B DES84749A DES0084749A DE1220135B DE 1220135 B DE1220135 B DE 1220135B DE S84749 A DES84749 A DE S84749A DE S0084749 A DES0084749 A DE S0084749A DE 1220135 B DE1220135 B DE 1220135B
- Authority
- DE
- Germany
- Prior art keywords
- dispersion
- ethylene oxide
- cold
- sample
- polyvinyl ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 14
- 229920001290 polyvinyl ester Polymers 0.000 title claims description 9
- 229920000126 latex Polymers 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000006185 dispersion Substances 0.000 claims description 46
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920001567 vinyl ester resin Polymers 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- 239000000523 sample Substances 0.000 description 18
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 16
- 230000008014 freezing Effects 0.000 description 10
- 238000007710 freezing Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 229910002567 K2S2O8 Inorganic materials 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 235000019394 potassium persulphate Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- VTWGIDKXXZRLGH-HJWRWDBZSA-N (z)-4-octoxy-4-oxobut-2-enoic acid Chemical compound CCCCCCCCOC(=O)\C=C/C(O)=O VTWGIDKXXZRLGH-HJWRWDBZSA-N 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000012520 frozen sample Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000008029 phthalate plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT773562 | 1962-04-20 | ||
| FR932139A FR1382085A (fr) | 1962-04-20 | 1963-04-19 | Procédé pour la production de latex synthétiques d'esters polyvinyliques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1220135B true DE1220135B (de) | 1966-06-30 |
Family
ID=26200894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES84749A Pending DE1220135B (de) | 1962-04-20 | 1963-04-18 | Verfahren zur Herstellung kaeltebestaendiger Polyvinylesterlatices |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE631142A (en, 2012) |
| DE (1) | DE1220135B (en, 2012) |
| FR (1) | FR1382085A (en, 2012) |
| GB (1) | GB1044915A (en, 2012) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0363319A1 (de) * | 1988-10-03 | 1990-04-11 | Ciba-Geigy Ag | Wasserlösliche oder in Wasser dispergierbare Pfropfpolymerisate, deren Herstellung und Verwendung |
| US5002587A (en) * | 1988-10-03 | 1991-03-26 | Ciba-Geigy Corporation | Copolymers which are water-soluble or dispersible in water, their preparation and use |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1064700A (fr) * | 1950-08-12 | 1954-05-17 | Du Pont | Perfectionnements à la polymérisation en émulsion |
-
0
- BE BE631142D patent/BE631142A/xx unknown
-
1963
- 1963-04-18 GB GB1531763A patent/GB1044915A/en not_active Expired
- 1963-04-18 DE DES84749A patent/DE1220135B/de active Pending
- 1963-04-19 FR FR932139A patent/FR1382085A/fr not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1064700A (fr) * | 1950-08-12 | 1954-05-17 | Du Pont | Perfectionnements à la polymérisation en émulsion |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0363319A1 (de) * | 1988-10-03 | 1990-04-11 | Ciba-Geigy Ag | Wasserlösliche oder in Wasser dispergierbare Pfropfpolymerisate, deren Herstellung und Verwendung |
| US4975524A (en) * | 1988-10-03 | 1990-12-04 | Ciba-Geigy Corporation | Graft polymers which are water-soluble or dispersible in water, their preparation and use |
| US5002587A (en) * | 1988-10-03 | 1991-03-26 | Ciba-Geigy Corporation | Copolymers which are water-soluble or dispersible in water, their preparation and use |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1382085A (fr) | 1964-12-18 |
| BE631142A (en, 2012) | |
| GB1044915A (en) | 1966-10-05 |
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