DE1139981B - Verfahren zur Trennung von Nickel und Kupfer - Google Patents
Verfahren zur Trennung von Nickel und KupferInfo
- Publication number
- DE1139981B DE1139981B DEJ21254A DEJ0021254A DE1139981B DE 1139981 B DE1139981 B DE 1139981B DE J21254 A DEJ21254 A DE J21254A DE J0021254 A DEJ0021254 A DE J0021254A DE 1139981 B DE1139981 B DE 1139981B
- Authority
- DE
- Germany
- Prior art keywords
- copper
- nickel
- sulfide
- sodium
- molten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 68
- 239000010949 copper Substances 0.000 title claims description 62
- 229910052802 copper Inorganic materials 0.000 title claims description 60
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 59
- 238000000034 method Methods 0.000 title claims description 32
- 229910052759 nickel Inorganic materials 0.000 title claims description 31
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 28
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 15
- 239000011780 sodium chloride Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 238000000638 solvent extraction Methods 0.000 claims description 12
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 238000000926 separation method Methods 0.000 claims description 10
- 238000000622 liquid--liquid extraction Methods 0.000 claims description 6
- YFLLTMUVNFGTIW-UHFFFAOYSA-N nickel;sulfanylidenecopper Chemical compound [Ni].[Cu]=S YFLLTMUVNFGTIW-UHFFFAOYSA-N 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- UGXULBLHMWXISM-UHFFFAOYSA-N disodium sulfide hydrochloride Chemical compound [S-2].[Na+].Cl.[Na+] UGXULBLHMWXISM-UHFFFAOYSA-N 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims 4
- 239000007791 liquid phase Substances 0.000 claims 1
- 239000012768 molten material Substances 0.000 claims 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 27
- 239000002904 solvent Substances 0.000 description 10
- 238000000605 extraction Methods 0.000 description 9
- 159000000000 sodium salts Chemical class 0.000 description 7
- 239000004575 stone Substances 0.000 description 7
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 229910000863 Ferronickel Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- ZIALXKMBHWELGF-UHFFFAOYSA-N [Na].[Cu] Chemical compound [Na].[Cu] ZIALXKMBHWELGF-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- IXEKHPUXRYGMRM-UHFFFAOYSA-L calcium;potassium;dichloride Chemical compound [Cl-].[Cl-].[K+].[Ca+2] IXEKHPUXRYGMRM-UHFFFAOYSA-L 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/01—Preparation or separation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/006—Pyrometallurgy working up of molten copper, e.g. refining
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/025—Obtaining nickel or cobalt by dry processes with formation of a matte or by matte refining or converting into nickel or cobalt, e.g. by the Oxford process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/06—Refining
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83943159A | 1959-09-11 | 1959-09-11 | |
| US51438A US3069254A (en) | 1960-08-23 | 1960-08-23 | Autogenous pyrometallurgical production of nickel from sulfide ores |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1139981B true DE1139981B (de) | 1962-11-22 |
| DE1139981C2 DE1139981C2 (en, 2012) | 1963-06-06 |
Family
ID=26729419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEJ21254A Granted DE1139981B (de) | 1959-09-11 | 1960-09-12 | Verfahren zur Trennung von Nickel und Kupfer |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1139981B (en, 2012) |
| FR (1) | FR1274967A (en, 2012) |
| GB (2) | GB960699A (en, 2012) |
| NL (4) | NL6412531A (en, 2012) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110983043B (zh) * | 2019-11-28 | 2021-11-23 | 武汉科技大学 | 一种用中低品位红土镍矿制备高品位镍铁的方法 |
| CN111961881B (zh) * | 2020-08-27 | 2022-05-24 | 西安建筑科技大学 | 一种应用于镍闪速炉熔炼过程中的添加剂及其使用方法 |
| CN114921661B (zh) * | 2022-05-30 | 2024-01-02 | 金川集团股份有限公司 | 一种生产水淬合金的工艺方法 |
-
0
- NL NL120731D patent/NL120731C/xx active
- NL NL255774D patent/NL255774A/xx unknown
- NL NL129554D patent/NL129554C/xx active
-
1960
- 1960-09-08 FR FR838143A patent/FR1274967A/fr not_active Expired
- 1960-09-12 GB GB31368/60A patent/GB960699A/en not_active Expired
- 1960-09-12 DE DEJ21254A patent/DE1139981B/de active Granted
- 1960-09-12 GB GB31367/60A patent/GB960698A/en not_active Expired
-
1964
- 1964-10-28 NL NL6412531A patent/NL6412531A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6412531A (en, 2012) | 1964-12-28 |
| NL129554C (en, 2012) | |
| DE1139981C2 (en, 2012) | 1963-06-06 |
| GB960698A (en) | 1964-06-17 |
| NL255774A (en, 2012) | |
| NL120731C (en, 2012) | |
| GB960699A (en) | 1964-06-17 |
| FR1274967A (fr) | 1961-11-03 |
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