DE1113785B - Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen OElen - Google Patents

Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen OElen

Info

Publication number
DE1113785B
DE1113785B DEU4409A DEU0004409A DE1113785B DE 1113785 B DE1113785 B DE 1113785B DE U4409 A DEU4409 A DE U4409A DE U0004409 A DEU0004409 A DE U0004409A DE 1113785 B DE1113785 B DE 1113785B
Authority
DE
Germany
Prior art keywords
grease
lubricating grease
mineral
animal
synthetic oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEU4409A
Other languages
English (en)
Inventor
Ted Symon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of DE1113785B publication Critical patent/DE1113785B/de
Pending legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R17/00—Measuring arrangements involving comparison with a reference value, e.g. bridge
    • G01R17/10—AC or DC measuring bridges
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0042—Preserving by using additives, e.g. anti-oxidants containing nitrogen
    • C11B5/005—Amines or imines
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R17/00—Measuring arrangements involving comparison with a reference value, e.g. bridge
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/105—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066—Arylene diamines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/067—Polyaryl amine alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/20—Containing nitrogen-to-oxygen bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/20—Containing nitrogen-to-oxygen bonds
    • C10M2215/206—Containing nitrogen-to-oxygen bonds hydroxylamines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/086—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/108—Phenothiazine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/02—Esters of silicic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/043—Siloxanes with specific structure containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/044—Siloxanes with specific structure containing silicon-to-hydrogen bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/06—Groups 3 or 13
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/04—Oxidation, e.g. ozonisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)

Description

DEUTSCHES
PATENTAMT
U4409IVc/23c
ANMELDETAG: 7. MARZ 1957
BEKANNTMACHUNG
DER ANMELDUNG
UNDAUSGABE DER
AUSLEGESCHRIFT: 14. SEPTEMBER 1961
Die Erfindung hat ein Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen ölen zum Gegenstand, das einen besonderen Verhinderer zur Verzögerung oxydativen Verderbens enthält.
Synthetische Schmierfette werden im allgemeinen als solche auf Lithiumbasis, Natriumbasis, Calciumbasis, Bariumbasis, Strontiumbasis, Aluminiumbasis, u. dgl. bezeichnet. Diese Schmierfette sind feste oder halbfeste Gele und werden im allgemeinen hergestellt, indem man Mineralöle oder synthetische Öle mit in Kohlenwasserstoff löslichen Metallseifen oder Salzen höherer Fettsäuren, z. B. Lithiumstearat, Calciumstearat oder Aluminiumnaphthenat, vermengt. Das Schmierfett kann Verdickungsmittel, ζ. Β. Kieselsäure, Ruß, Polyakrylate oder Talk, enthalten. Eine andere Schmierfettart wird aus oxydiertem Petrolwachs durch Vermengen und Verarbeiten mit der verseifbaren Grundlage und der geeigneten Menge des gewünschten Verseifungsmittels zubereitet. Andere Schmierfettarten sind Petrolfett, Walfett, Wollfett und Fette, die aus nicht eßbaren Fetten, Talg, Schlächtereiabfall und ähnlichen Rohstoffen hergestellt sind. Zu den künstlichen Schmierfetten gehören auch aliphatische Ester, Polyalkylenoxyde (Polymere von Olefinoxyden) und hochfluorsubstituierte Kohlenwasserstoffe. Von den aliphatischen Estern wird Di-(2-äthylhexyl)-sebacinat in verhältnismäßig großem Maßstab verwendet. Andere Beispiele aliphatischer Ester sind Dialkylazelate, Dialkylsuberate, Dialkylpimelate, Dialkyladipate und Dialkylglutarate. Beispiele der Polyalkylenoxyde und ihrer Derivate sind Polyisopropylenoxyddiester. Beispiele der Silicone sind Methylsilicon und Methylphenylsilicon, und ein Beispiel der Silikate ist Tetraisooktylsilikat. Kennzeichnende Beispiele der hochfluorierten Kohlenwasserstoffe sind fluoriertes öl und Perfluorkohlenwasserstoffe.
Gegenstand der Erfindung ist ein Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen ölen, das einen Gehalt an einem gegebenenfalls am Stickstoffatom alkylsubstituierten 2,4'-Diaminodiphenyläther oder 2,4'-Diaminodiphenylsulfid aufweist. Vorzugsweise hat der Alkylsubstituent 1 bis 20 Kohlenstoffatome.
Als Zusätze zu Schmiermitteln sind gegebenenfalls durch Alkyl-, Oxalkyl- oder Cyclohexylgruppen kernsubstituierte Benzidinverbindungen bekannt, deren Aminogruppen durch je mindestens einen Cyclohexylrest substituiert sind. Vergleichsversuche, über die im Beispiel 4 berichtet wird, zeigen jedoch, daß diese Benzidinverbindungen eine beträchtlich kleinere Haltbarkeitsverlängerung liefern als die Zusätze gemäß der Erfindung.
Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen Ölen
Anmelder:
Universal Oil Products Company,
organisiert 1958,
Des Piaines, 111. (V. St. A.)
Vertreter: Dr. H. H. Willrath, Patentanwalt,
Wiesbaden, Hildastr. 32
Beanspruchte Priorität:
V. St. v. Amerika vom 9. März 1956
Ted Symon, Elmhurst, 111. (V. St. Α.),
ist als Erfinder genannt worden
Als Oxydationsverhinderer für Krackbenzin sind außerdem Di-tert-alkylphenyldiamine, insbesondere N,N'-Di-tert-butyl-p-phenylendiamin beschrieben worden. Es kann jedoch von einer Haltbarkeitssteigerung bei Benzinen nicht unmittelbar auf eine Verhinderung der oxydativen Zersetzung von Schmierfetten geschlossen werden.
Gemäß einer bevorzugten erfindungsgemäßen Ausführungsform besitzt ein Schmierfett gemäß der Erfindung einen Gehalt von 0,1 bis 5 Gewichtsprozent, bezogen auf die Gesamtschmierfettmenge, an den gegebenenfalls am N-Atom alkylsubstituierten 2,4'-Diaminodiphenyläthern oder Diaminodiphenylsulfiden. Bevorzugt haben hierbei die Alkylgruppen sekundäre Konfiguration, d. h., die Alkylgruppe ist an das Stickstoffatom mit einem mittelständigen Kohlenstoffatom der Alkylgruppe angelagert. Hierzu gehören 2,4'-Diisopropylaminodiphenyläther und die entsprechenden 2,4'-Di-sec-alkylaminodiphenyläther sowie 2,4'-Dialkylaminodiphenylsulfide, wie 2,4'-Diisopropylaminodiphenylsulfid und die entsprechenden 2,4'-Di-secalkylaminodiphenylsulfide, bei welchen die Alkylgruppe jeweils 4 bis 20 C-Atome aufweist.
Obgleich Verbindungen mit sekundären Alkylgruppen bevorzugt werden, ist zu beachten, daß geeignete Verbindungen mit n-Alkylsubstituenten verwendet werden können, jedoch nicht unbedingt mit ge-
109 688/195
nau denselben Ergebnissen. Zur Erläuterung für diese Verbindungsklasse seien 2,4'-Dimethylaminodiphenyläther, 2,4'-Diäthylaminodiphenyläther und die 2,4'-Din-alkylaminodiphenyläther mit 3 bis 12 Kohlenstoffatomen in der geraden Alkylgruppenkette genannt.
Im allgemeinen soll vorzugsweise der 2,4'-Dialkylaminodiphenyläther und das 2,4'-Dialkylaminodiphenylsulfid eine symmetrische Verbindung sein, d. h., die Alkylgruppen haben dieselbe Konfiguration und Kettenlänge. In einigen Fällen können jedoch die Alkylgruppen entweder hinsichtlich der Zahl der Kohlenstoffatome oder hinsichtlich ihrer Konfiguration bzw. auch in beiden Hinsichten verschieden sein, vorzugsweise werden sie aus den vorstehenden genauer aufgeführten Alkylgruppen ausgewählt.
Es sei bemerkt, daß auch ein Gemisch der erfindungsgemäßen Zusätze verwendet werden kann, wobei die jeweiligen Verbindungen vorzugsweise aus denjenigen ausgewählt werden, die vorstehend im einzelnen genannt wurden. In einigen Fällen wird während der Herstellung des Zusatzes ein Isomerengemisch erzeugt, und gewünschtenfalls wird das Gemisch als solches benutzt, wodurch man zusätzlichen Aufwand an Zeit und Kosten für die Trennung der Mischungsbestandteile vermeidet.
Im allgemeinen wird der Zusatz in einer Konzentration im Bereich von 0,0001 bis 5 Gewichtsprozent, bezogen auf das Gesamtschmierfett, verwendet. Die zu benutzende genaue Konzentration wird von der jeweils zu behandelnden organischen Substanz abhängen. In den meisten Fällen wird man Konzentrationen von etwa 0,01 bis etwa 3 Gewichtsprozent verwenden.
Der erfindungsgemäße Zusatz kann zusammen mit anderen bekannten Zusatzstoffen verwendet werden, beispielsweise Verhinderer zusammen mit höheren Alkoholen, Estern, organischen Aminen, Polybuten, geschwefelten fetten Stoffen, Schwefelchlorverbindungen, Farbstoffen, Geruchstoffen oder Füllstoffen. In einigen Fällen kann es vorteilhaft sein, auch einen Metalldesaktivator, z. B. Disalicylaldiaminopropan oder Äthylendiamintetraessigsäuretetranatriumsalz, bzw. andere Zusatzstoffe wie Trikresylphosphat, Trialkylphenole einschließlich 2,6-Di-tert-butyl-4-methylphenol, 2,4-Di-methyl-6-tert-butylphenol, alkylierte Diphenylamine, Phenylnapthylamine, Dialkylphenylendiamine, Phenothiazin, organische Selenverbindungen sowie Korrosionsverhinderer, Hochdruckzusätze oder Viskositätsindexverbesserer hinzufügen.
Der erfindungsgemäße Zusatz kann in das Schmierfett als organischer Stoff in irgendeiner geeigneten Weise und während irgendeiner geeigneten Herstellungsstufe eingebracht werden.
10
Beispiel 1
2,4'-Diaminodiphenyläther wurde als Verhinderer in einem Lithiumfett benutzt. Das Schmierfett wurde zubereitet, indem man 91 % emes pennsylvanischen Brightstock mit 8°/o Lithiumstearat vermischte. Das Gemisch wurde auf etwa 230°C unter gleichzeitigem Rühren erhitzt. Anschließend wurde das Fett unter Rühren auf 16O0C abgekühlt, und bei dieser Temperatur wurde 1% 2,4'-Diaminodiphenyläther zugesetzt. Das Rühren wurde fortgesetzt, und die Mischung wurde auf etwa 1210C abkühlen gelassen, worauf das Schmierfett langsam weiter auf Zimmertemperatur abkühlte.
Die Beständigkeit des Schmierfettes wurde gemäß der modifizierten Norma-Hoffman-Methode (ASTM D 942-50) geprüft, bei der eine Probe des Schmierfettes in eine Bombe in Gegenwart von Messingscheiben gebracht wurde, die als Oxydationskatalysator wirkten. In die Bombe wurde Sauerstoff eingeführt. Dann wurde sie auf 100°C erhitzt, und die zur Erreichung eines Druckabfalles von 0,34 Atm erforderliehe Zeit wurde als Induktionsperiode angenommen. Bei diesem Versuch hatte eine Kontrollprobe des Schmierfettes (ohne diesen Zusatzstoff) eine Induktionsperiode von 10,5 Stunden. Andererseits hatte eine Probe des Schmierfettes mit 1 Gewichtsprozent 2,4'-Diaminodiphenyläther eine Induktionsperiode von 260 Stunden. Im Gegensatz hierzu hatte eine Probe desselben Schmierfettes, die mit 1 Gewichtsprozent 4,4'-Diaminodiphenyläther stabilisiert war, eine Induktionsperiode von nur 106 Stunden. Es ist also zu bemerken, daß der gemäß der Erfindung benutzte Verhinderer überraschend und außergewöhnlich wirksam hinsichtlich der Verbesserung der Stabilität des Schmierfettes war.
Die Herstellung der in der nachfolgenden Tabelle angegebenen Schmierfette erfolgte gemäß Beispiel 1.
Beispiel Ölbasis »/ο - Verdicker V. Zusatz, °/o
*)		 Induktionszeit
Stunden
* ί
3 { 		Midcontinent SAE 30
Di-2-äthylhexylsebacat 		1 92
J 91
1 88
J 87		 Li-Stearat
Li-Stearat
Li-Stearat
Li-Stearat		 8
8
12
12		 1
1		 10,5
370
17
318 Druck
abfall 0,068 Atm.
*) 2,4'-Diaminodiphenyläther
Beispiel 4
Das in diesem Beispiel benutzte Schmierfett wurde im wesentlichen, wie in den Beispielen 1 und 2 beschrieben, zubereitet, jedoch wurde ein Mittelkontinent-Schmieröl mit einer SAE-Viskosität 20 mit 8 Gewichtsprozent Lithiumstearat vermischt.
Eine Kontrollprobe dieses Schmierfettes, d. h. eine Probe, die keinen Verhinderer enthielt, hatte eine Induktionsperiode von 8 Stunden nach dem bei 121° C unter einem Anfangssauerstoffdruck von 8,5 Atm.
durchgeführten Norma - Hoffman - Haltbarkeitstest. Gemäß der folgenden Tabelle hatten Proben dieses Schmierfettes mit 0,1 bzw. 0,3 Gewichtsprozent 2,4'-Diaminodiphenyläther und 2,4'-Diaminodiphenylsulfid eine beträchtlich längere Haltbarkeitsdauer, als sie bei Vergleichsversuchen an anderen Proben desselben Ausgangsschmierfettes, jedoch in ähnlicher Weise mit 0,1 bzw. 0,3 Gewichtsprozent eines der bekannten Zusatzstoffe, N3N'-Dicyclohexyl-3,3'-dimethoxybenzidin und N,N'-Dicyclohexyl-3,3'-dimethylbenzidin, vermischt beobachtet wurden.
5 6
Tabelle Haltbarkeitsdauer nach Norma-Hoffman-Sauerstoffhaltbarkeitstest
Haltbarkeit in Stunden 0,3 Gewichtsprozent
Zusatzstoff bei dem Schmierfett mit Zusatzstoff 121
0,1 Gewichtsprozent 85
2,4'-Diaminodiphenyläther 68 89
2-Amino-4'-sec.-butylaminodiphenyläther 35 95
2-sec.-Butylamino-4'-Aminodiphenyläther 39 105
2-Amino-4'-Diisopropylaminodiphenyläther 68 15
2,4'-Diaminodiphenylsulfid 65 14
HN'-Dicyclohexyl-S^'-dimethoxybenzidin 27
N,N'-Dicyclohexyl-3,3'-dimethylbenzidin 20

Claims (3)

PATENTANSPRÜCHE:
1. Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen ölen, gekennzeichnet durch einen Gehalt an einem gegebenenfalls am Stickstoffatom alkylsubstituierten 2,4'-Diaminodiphenyläther oder 2,4'-Diaminodiphenylsulfid.
2. Schmierfett nach Anspruch 1, dadurch gekennzeichnet, daß der Alkylsubstituent 1 bis 20 Kohlenstoffatome enthält.
3. Schmierfett nach Anspruch 1 und 2, gekennzeichnet durch einen Gehalt von 0,1 bis 5 Gewichtsprozent, bezogen auf das Gesamtschmierfett, des Diaminodiphenyläthers oder Diaminodiphenylsulfids.
In Betracht gezogene Druckschriften:
Deutsche Patentschrift Nr. 929 385;
USA.-Patentschrift Nr. 2 692 288.
© 109 688/195 9.61
DEU4409A 1956-03-09 1957-03-07 Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen OElen Pending DE1113785B (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US570420A US2910437A (en) 1956-03-09 1956-03-09 Stabilization of lubricants

Publications (1)

Publication Number Publication Date
DE1113785B true DE1113785B (de) 1961-09-14

Family

ID=24279577

Family Applications (1)

Application Number Title Priority Date Filing Date
DEU4409A Pending DE1113785B (de) 1956-03-09 1957-03-07 Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen OElen

Country Status (6)

Country Link
US (1) US2910437A (de)
DE (1) DE1113785B (de)
ES (1) ES234133A1 (de)
FR (1) FR1172914A (de)
GB (1) GB819024A (de)
NL (1) NL102710C (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2982729A (en) * 1958-04-02 1961-05-02 Universal Oil Prod Co High temperature lubricating grease containing a p, p'-diaminodiphenylether
US3169926A (en) * 1961-11-29 1965-02-16 Universal Oil Prod Co Stabilization of organic substances
US3208944A (en) * 1962-11-19 1965-09-28 Universal Oil Prod Co Stabilization of lubricants
US3240706A (en) * 1963-01-24 1966-03-15 Universal Oil Prod Co Stabilization of organic substances
DE1248936B (de) * 1966-03-16 1967-08-31
US4380497A (en) * 1981-05-12 1983-04-19 Uop Inc. Amines of alkoxydiphenyl esthers as antioxidants and lubricating oils and greases containing same
US4386002A (en) * 1981-05-12 1983-05-31 Uop Inc. Imines of aminodiphenyl esthers as antioxidants and lubricating oils and greases containing same
US4378298A (en) * 1981-05-12 1983-03-29 Uop Inc. Imines of 2,4-diaminodiphenyl ethers as antioxidants for lubricating oils and greases
CN114892176B (zh) * 2022-05-12 2024-03-26 中山大学 有机硒在抑制碳钢在酸性溶液中腐蚀的应用和碳钢缓蚀剂

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2692288A (en) * 1951-03-29 1954-10-19 Eastman Kodak Co Production of n-tertiary alkylated aromatic secondary diamines
DE929385C (de) * 1952-04-23 1955-06-27 Bayer Ag Zusaetze fuer Schmiermittel

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2048362A (en) * 1934-05-04 1936-07-21 Dow Chemical Co Acid composition for treatment of deep wells
US2269265A (en) * 1939-12-14 1942-01-06 Socony Vacuum Oil Co Inc Stabilized refined petroleum product
US2290860A (en) * 1940-04-26 1942-07-28 Standard Oil Co Beneficiation of lubricating oils
US2367264A (en) * 1940-09-30 1945-01-16 Standard Oil Co Beneficiating lubricants, etc.
US2350746A (en) * 1941-11-26 1944-06-06 Socony Vacuum Oil Co Inc Mineral oil composition
US2440530A (en) * 1944-11-04 1948-04-27 Shell Dev Stabilized organic compositions
US2523100A (en) * 1947-05-17 1950-09-19 Standard Oil Dev Co Mineral oil composition and additive therefor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2692288A (en) * 1951-03-29 1954-10-19 Eastman Kodak Co Production of n-tertiary alkylated aromatic secondary diamines
DE929385C (de) * 1952-04-23 1955-06-27 Bayer Ag Zusaetze fuer Schmiermittel

Also Published As

Publication number Publication date
FR1172914A (fr) 1959-02-17
GB819024A (en) 1959-08-26
US2910437A (en) 1959-10-27
NL102710C (de)
ES234133A1 (es) 1957-08-16

Similar Documents

Publication Publication Date Title
US2566793A (en) Grease compositions
DE10084148B4 (de) Schmierfettzusammensetzung für Gleichlaufgelenke
DE1594551A1 (de) Piperdion-(2)-Derivate und ihre Verwendung als Zusatz zu Schmiermittel
DE1806899C3 (de) Schmiermittel
DE2650580C2 (de)
DE69528100T2 (de) Verwendung von organischen Bismuthverbindungen in Hochdruckschmierfettzusammensetzungen für Wälzlager mit erhöhter Lebensdauer
DE1113785B (de) Schmierfett auf der Basis von mineralischen, tierischen oder synthetischen OElen
DE3876432T2 (de) Hydraulische fluessigkeiten.
DE1074794B (de) Schmierölzusatz und diesen Zusatz enthaltende Mineralschmieröle
DE850049C (de) Tieftemperatur-Schmierfette
US2605224A (en) Metalworking lubricant
DE2310590A1 (de) Schmierfette
DE874940C (de) Schmierfette
US3133020A (en) Extreme pressure lubricants
DE1150170B (de) Schmiermittel
US2964479A (en) Stabilizing mixture of 4, 4'-diaminodiphenyl ether and 2, 4'-diaminodiphenyl ether
DE1084863B (de) Schmiermittel und hydraulische Fluessigkeit auf der Basis einer Wasser-in-OEl-Emulsion
DE941634C (de) Schmierfett und Verfahren zu seiner Herstellung
DE2810389A1 (de) Schmierfettzusammensetzungen
DE2902982C2 (de)
DE2125094C3 (de) Schmierfette
DE69001462T2 (de) Schmieroelzusammensetzung.
DE1160967B (de) Schmiermittel
DE2235608C2 (de) Schmiermittel
US3032502A (en) Lubricant compositions