GB819024A - Improvements in or relating to the stabilizing of lubricating greases - Google Patents

Improvements in or relating to the stabilizing of lubricating greases

Info

Publication number
GB819024A
GB819024A GB7219/57A GB721957A GB819024A GB 819024 A GB819024 A GB 819024A GB 7219/57 A GB7219/57 A GB 7219/57A GB 721957 A GB721957 A GB 721957A GB 819024 A GB819024 A GB 819024A
Authority
GB
United Kingdom
Prior art keywords
lubricating
lithium
diaminodiphenyl ether
grease
sulphide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7219/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB819024A publication Critical patent/GB819024A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R17/00Measuring arrangements involving comparison with a reference value, e.g. bridge
    • G01R17/10AC or DC measuring bridges
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/48Separation; Purification; Stabilisation; Use of additives
    • C07C67/62Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00Preserving by using additives, e.g. anti-oxidants
    • C11B5/0042Preserving by using additives, e.g. anti-oxidants containing nitrogen
    • C11B5/005Amines or imines
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R17/00Measuring arrangements involving comparison with a reference value, e.g. bridge
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
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    • C10M2201/10Compounds containing silicon
    • C10M2201/105Silica
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
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    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/16Naphthenic acids
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    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
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    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/20Containing nitrogen-to-oxygen bonds
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    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
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    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/042Metal salts thereof
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
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    • C10N2060/00Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/04Oxidation, e.g. ozonisation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)

Abstract

Lubricating greases are stabilized against oxidative deterioration by the addition of 0.0001-5 per cent by weight of a 2,41-diaminodiphenyl ether or 2,41-diaminodiphenyl sulphide. The lubricating greases may comprise mineral or synthetic lubricating oils thickened with soaps (e.g. lithium, sodium, calcium, or aluminium soaps, such as lithium or calcium stearate, or aluminium naphthenate and soaps prepared from whale oil, wool grease, inedible fats or tallow), silica, carbon black, polyacrylates or talc. The lubricating grease may contain additional additives such as alcohols, esters, polybutane, sulphurized fatty materials, sulphur- and chlorine-containing compounds, dyes, perfumes, fillers, metal deactivators (e.g. disalicylal diamino propane or ethylene diamine tetra-acetic acid tetra-sodium salt), tricresyl phosphate, trialkyl phenols, alkylated diphenylamines, phenyl naphthyl amines, dialkyl phenylene diamines, phenothiazine, organic selenium compounds, corrosion inhibitors, extreme pressure additives and viscosity index improvers. Instead of the 2,41-diaminodiphenyl ether or sulphide, there may be employed a 2,41-dialkylaminodiphenyl ether or sulphide or a corresponding compound wherein one or both of the substituents attached to the nitrogen atoms are alkenyl, cycloalkyl, cycloalkenyl, aryl, alkaryl or aralkyl groups. In examples, 2,41-diaminodiphenyl ether is added to a lubricating grease consisting of lubricating oil (mineral lubricating oil, bright stock or di-2-ethylhexyl sebacate) thickened with lithium stearate. For comparison purposes, the effect of 4,41-diaminodiphenyl ether as a stabilizer for lithium grease is described.
GB7219/57A 1956-03-09 1957-03-05 Improvements in or relating to the stabilizing of lubricating greases Expired GB819024A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US570420A US2910437A (en) 1956-03-09 1956-03-09 Stabilization of lubricants

Publications (1)

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GB819024A true GB819024A (en) 1959-08-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB7219/57A Expired GB819024A (en) 1956-03-09 1957-03-05 Improvements in or relating to the stabilizing of lubricating greases

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US (1) US2910437A (en)
DE (1) DE1113785B (en)
ES (1) ES234133A1 (en)
FR (1) FR1172914A (en)
GB (1) GB819024A (en)
NL (1) NL102710C (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2982729A (en) * 1958-04-02 1961-05-02 Universal Oil Prod Co High temperature lubricating grease containing a p, p'-diaminodiphenylether
US3169926A (en) * 1961-11-29 1965-02-16 Universal Oil Prod Co Stabilization of organic substances
US3208944A (en) * 1962-11-19 1965-09-28 Universal Oil Prod Co Stabilization of lubricants
US3240706A (en) * 1963-01-24 1966-03-15 Universal Oil Prod Co Stabilization of organic substances
DE1248936B (en) * 1966-03-16 1967-08-31
US4378298A (en) * 1981-05-12 1983-03-29 Uop Inc. Imines of 2,4-diaminodiphenyl ethers as antioxidants for lubricating oils and greases
US4386002A (en) * 1981-05-12 1983-05-31 Uop Inc. Imines of aminodiphenyl esthers as antioxidants and lubricating oils and greases containing same
US4380497A (en) * 1981-05-12 1983-04-19 Uop Inc. Amines of alkoxydiphenyl esthers as antioxidants and lubricating oils and greases containing same
CN114892176B (en) * 2022-05-12 2024-03-26 中山大学 Application of organic selenium in inhibiting corrosion of carbon steel in acid solution and carbon steel corrosion inhibitor

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2048362A (en) * 1934-05-04 1936-07-21 Dow Chemical Co Acid composition for treatment of deep wells
US2269265A (en) * 1939-12-14 1942-01-06 Socony Vacuum Oil Co Inc Stabilized refined petroleum product
US2290860A (en) * 1940-04-26 1942-07-28 Standard Oil Co Beneficiation of lubricating oils
US2367264A (en) * 1940-09-30 1945-01-16 Standard Oil Co Beneficiating lubricants, etc.
US2350746A (en) * 1941-11-26 1944-06-06 Socony Vacuum Oil Co Inc Mineral oil composition
US2440530A (en) * 1944-11-04 1948-04-27 Shell Dev Stabilized organic compositions
US2523100A (en) * 1947-05-17 1950-09-19 Standard Oil Dev Co Mineral oil composition and additive therefor
US2692288A (en) * 1951-03-29 1954-10-19 Eastman Kodak Co Production of n-tertiary alkylated aromatic secondary diamines
DE929385C (en) * 1952-04-23 1955-06-27 Bayer Ag Additives for lubricants

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DE1113785B (en) 1961-09-14
US2910437A (en) 1959-10-27
ES234133A1 (en) 1957-08-16
NL102710C (en)
FR1172914A (en) 1959-02-17

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