DE10247633A1 - Mischungen von chiralen Monophosphor-Verbindungen als Ligandensysteme für die asymmetrische Übergangsmetallkatalyse - Google Patents

Mischungen von chiralen Monophosphor-Verbindungen als Ligandensysteme für die asymmetrische Übergangsmetallkatalyse Download PDF

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DE10247633A1
DE10247633A1 DE10247633A DE10247633A DE10247633A1 DE 10247633 A1 DE10247633 A1 DE 10247633A1 DE 10247633 A DE10247633 A DE 10247633A DE 10247633 A DE10247633 A DE 10247633A DE 10247633 A1 DE10247633 A1 DE 10247633A1
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Prior art keywords
chiral
ligands
atoms
independently
transition metal
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DE10247633A
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German (de)
English (en)
Inventor
Manfred T. Reetz
Thorsten Sell
Andreas Meiswinkel
Gerlinde Mehler
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Studiengesellschaft Kohle gGmbH
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Studiengesellschaft Kohle gGmbH
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Priority to DE10247633A priority Critical patent/DE10247633A1/de
Priority to US10/530,818 priority patent/US7704912B2/en
Priority to DK03750375.2T priority patent/DK1558384T3/en
Priority to CA2501373A priority patent/CA2501373C/en
Priority to JP2004543948A priority patent/JP4805577B2/ja
Priority to AU2003269835A priority patent/AU2003269835A1/en
Priority to EP03750375.2A priority patent/EP1558384B1/de
Priority to PCT/DE2003/003226 priority patent/WO2004035208A1/de
Publication of DE10247633A1 publication Critical patent/DE10247633A1/de
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
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    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
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US10/530,818 US7704912B2 (en) 2002-10-11 2003-09-26 Mixtures of chiral monophosphorus compounds used as ligand systems for asymmetric transition metal catalysis
DK03750375.2T DK1558384T3 (en) 2002-10-11 2003-09-26 Mixtures of chiral monophosphorus compounds as ligand systems for asymmetric transition metal catalysis
CA2501373A CA2501373C (en) 2002-10-11 2003-09-26 Mixtures of chiral monophosphorus compounds used as ligand systems for asymmetric transition metal catalysis
JP2004543948A JP4805577B2 (ja) 2002-10-11 2003-09-26 キラル遷移金属触媒、及び該触媒を用いるキラル有機化合物の接触製造法
AU2003269835A AU2003269835A1 (en) 2002-10-11 2003-09-26 Mixtures of chiral monophosphorus compounds used as ligand systems for asymmetric transition metal catalysis
EP03750375.2A EP1558384B1 (de) 2002-10-11 2003-09-26 Mischungen von chiralen monophosphor-verbindungen als liganden-systeme für die asymmetriche übergangsmetall-katalyse
PCT/DE2003/003226 WO2004035208A1 (de) 2002-10-11 2003-09-26 Mischungen von chiralen monophosphor-verbindungen als liganden-systeme für die asymmetriche übergangsmetall-katalyse

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AT501193A1 (de) * 2004-12-27 2006-07-15 Dsm Fine Chem Austria Gmbh Verfahen zur übergangsmetall - katalysierten asymmetrischen hydrierung von acrylsäurederivaten
AT501193B1 (de) * 2004-12-27 2007-03-15 Dsm Fine Chem Austria Gmbh Verfahen zur übergangsmetall - katalysierten asymmetrischen hydrierung von acrylsäurederivaten

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