CS212706B2 - Method of improving the permeability of silicon steel with goss orientation - Google Patents
Method of improving the permeability of silicon steel with goss orientation Download PDFInfo
- Publication number
- CS212706B2 CS212706B2 CS741487A CS148774A CS212706B2 CS 212706 B2 CS212706 B2 CS 212706B2 CS 741487 A CS741487 A CS 741487A CS 148774 A CS148774 A CS 148774A CS 212706 B2 CS212706 B2 CS 212706B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- silicon steel
- annealing
- final
- steel
- sulfur
- Prior art date
Links
- 229910000976 Electrical steel Inorganic materials 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims description 24
- 230000035699 permeability Effects 0.000 title claims description 19
- 238000000137 annealing Methods 0.000 claims abstract description 63
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 21
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 19
- 239000010959 steel Substances 0.000 claims abstract description 19
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 239000011593 sulfur Substances 0.000 claims description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000395 magnesium oxide Substances 0.000 claims description 12
- 239000010703 silicon Substances 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 11
- 229910052796 boron Inorganic materials 0.000 claims description 11
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000012298 atmosphere Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 150000003464 sulfur compounds Chemical class 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 5
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000011669 selenium Substances 0.000 claims description 4
- 239000003966 growth inhibitor Substances 0.000 claims description 3
- 229940065287 selenium compound Drugs 0.000 claims description 3
- 150000003343 selenium compounds Chemical class 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 9
- 238000005098 hot rolling Methods 0.000 abstract description 8
- 238000005097 cold rolling Methods 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 4
- -1 1-6% of S Chemical class 0.000 abstract description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001639 boron compounds Chemical class 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000005554 pickling Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000161 steel melt Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- RRZKHZBOZDIQJG-UHFFFAOYSA-N azane;manganese Chemical compound N.[Mn] RRZKHZBOZDIQJG-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/68—Temporary coatings or embedding materials applied before or during heat treatment
- C21D1/70—Temporary coatings or embedding materials applied before or during heat treatment while heating or quenching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1261—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1272—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
- C21D8/1283—Application of a separating or insulating coating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electromagnetism (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Soft Magnetic Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US337073A US3873381A (en) | 1973-03-01 | 1973-03-01 | High permeability cube-on-edge oriented silicon steel and method of making it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS212706B2 true CS212706B2 (en) | 1982-03-26 |
Family
ID=23319003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS741487A CS212706B2 (en) | 1973-03-01 | 1974-02-28 | Method of improving the permeability of silicon steel with goss orientation |
Country Status (17)
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE430794B (sv) * | 1974-09-16 | 1983-12-12 | Allegheny Ludlum Steel | Kallvalsat kiseljernflatmaterial och sett att framstella dylikt |
| US3957546A (en) * | 1974-09-16 | 1976-05-18 | General Electric Company | Method of producing oriented silicon-iron sheet material with boron and nitrogen additions |
| US3925115A (en) * | 1974-11-18 | 1975-12-09 | Allegheny Ludlum Ind Inc | Process employing cooling in a static atmosphere for high permeability silicon steel comprising copper |
| US3929522A (en) * | 1974-11-18 | 1975-12-30 | Allegheny Ludlum Ind Inc | Process involving cooling in a static atmosphere for high permeability silicon steel comprising copper |
| US4000015A (en) * | 1975-05-15 | 1976-12-28 | Allegheny Ludlum Industries, Inc. | Processing for cube-on-edge oriented silicon steel using hydrogen of controlled dew point |
| DE2531536C2 (de) * | 1975-07-17 | 1986-10-16 | Allegheny Ludlum Steel Corp., Pittsburgh, Pa. | Verfahren zum Herstellen eines kornorientierten Siliziumstahlbleches |
| SE7703456L (sv) * | 1976-04-15 | 1977-10-16 | Gen Electric | Tunnplat av kiseljern med bortillsats samt forfarande for framstellning derav |
| US4102713A (en) * | 1976-06-17 | 1978-07-25 | Allegheny Ludlum Industries, Inc. | Silicon steel and processing therefore |
| US4030950A (en) * | 1976-06-17 | 1977-06-21 | Allegheny Ludlum Industries, Inc. | Process for cube-on-edge oriented boron-bearing silicon steel including normalizing |
| US4054471A (en) * | 1976-06-17 | 1977-10-18 | Allegheny Ludlum Industries, Inc. | Processing for cube-on-edge oriented silicon steel |
| US4179315A (en) * | 1976-06-17 | 1979-12-18 | Allegheny Ludlum Industries, Inc. | Silicon steel and processing therefore |
| US4054470A (en) * | 1976-06-17 | 1977-10-18 | Allegheny Ludlum Industries, Inc. | Boron and copper bearing silicon steel and processing therefore |
| ZA773084B (en) * | 1976-06-17 | 1978-04-26 | Allegheny Ludlum Ind Inc | Silicon steel and processing therefor |
| US4168189A (en) * | 1977-05-20 | 1979-09-18 | Armco Inc. | Process of producing an electrically insulative film |
| US4115161A (en) * | 1977-10-12 | 1978-09-19 | Allegheny Ludlum Industries, Inc. | Processing for cube-on-edge oriented silicon steel |
| US4157925A (en) * | 1978-04-12 | 1979-06-12 | Allegheny Ludlum Industries, Inc. | Texture annealing silicon steel |
| JPS5920731B2 (ja) * | 1978-06-16 | 1984-05-15 | 新日本製鐵株式会社 | 磁気特性の優れた電気鉄板の製造法 |
| US4337101A (en) * | 1980-08-18 | 1982-06-29 | Allegheny Ludlum Steel Corporation | Processing for cube-on-edge oriented silicon steel |
| CA1166804A (en) * | 1982-05-06 | 1984-05-08 | Michael H. Haselkorn | Stable slurry of inactive magnesia and method therefor |
| US4456812A (en) | 1982-07-30 | 1984-06-26 | Armco Inc. | Laser treatment of electrical steel |
| MX167814B (es) * | 1987-06-04 | 1993-04-13 | Allegheny Ludlum Corp | Metodo para producir acero al silicio orientado engrano con adiciones pequeñas de boro |
| DE19816158A1 (de) * | 1998-04-09 | 1999-10-14 | G K Steel Trading Gmbh | Verfahren zur Herstellung von korn-orientierten anisotropen, elektrotechnischen Stahlblechen |
| KR101349152B1 (ko) * | 2013-02-12 | 2014-01-16 | 윤정석 | 자석 블록 완구 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3347718A (en) * | 1964-01-20 | 1967-10-17 | Armco Steel Corp | Method for improving the magnetic properties of ferrous sheets |
| US3333991A (en) * | 1965-05-19 | 1967-08-01 | Armco Steel Corp | Production of cube-on-edge oriented silicon-iron |
| US3636579A (en) * | 1968-04-24 | 1972-01-25 | Nippon Steel Corp | Process for heat-treating electromagnetic steel sheets having a high magnetic induction |
| US3632456A (en) * | 1968-04-27 | 1972-01-04 | Nippon Steel Corp | Method for producing an electromagnetic steel sheet of a thin sheet thickness having a high-magnetic induction |
| US3575739A (en) * | 1968-11-01 | 1971-04-20 | Gen Electric | Secondary recrystallization of silicon iron with nitrogen |
| US3700506A (en) * | 1968-12-10 | 1972-10-24 | Nippon Steel Corp | Method for reducing an iron loss of an oriented magnetic steel sheet having a high magnetic induction |
| US3725143A (en) * | 1971-02-03 | 1973-04-03 | Steel Corp | Aging resistant cold rolled sheet products |
| BE790798A (fr) * | 1971-11-04 | 1973-02-15 | Armco Steel Corp | Procédé de fabrication de fer au silicium à orientation cube-sur-arete à partir de brames coulées |
-
1973
- 1973-03-01 US US337073A patent/US3873381A/en not_active Expired - Lifetime
-
1974
- 1974-02-19 CA CA192,894A patent/CA1021671A/en not_active Expired
- 1974-02-22 ZA ZA00741175A patent/ZA741175B/xx unknown
- 1974-02-22 GB GB807874A patent/GB1452699A/en not_active Expired
- 1974-02-27 IN IN414/CAL/1974A patent/IN141411B/en unknown
- 1974-02-27 BE BE141426A patent/BE811618A/xx not_active IP Right Cessation
- 1974-02-27 NL NL7402637A patent/NL7402637A/xx not_active Application Discontinuation
- 1974-02-28 JP JP2370974A patent/JPS5423332B2/ja not_active Expired
- 1974-02-28 CS CS741487A patent/CS212706B2/cs unknown
- 1974-02-28 SE SE7402698A patent/SE393126B/xx unknown
- 1974-02-28 FR FR7406932A patent/FR2219980B1/fr not_active Expired
- 1974-02-28 AR AR252571A patent/AR203191A1/es active
- 1974-03-01 ES ES423800A patent/ES423800A1/es not_active Expired
- 1974-03-01 DE DE2409895A patent/DE2409895C3/de not_active Expired
- 1974-03-01 RO RO7477875A patent/RO69745A/ro unknown
- 1974-03-01 IT IT48823/74A patent/IT1003625B/it active
- 1974-03-01 BR BR1511/74A patent/BR7401511D0/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES423800A1 (es) | 1976-05-16 |
| DE2409895B2 (de) | 1981-02-05 |
| US3873381A (en) | 1975-03-25 |
| JPS501025A (enrdf_load_stackoverflow) | 1975-01-08 |
| DE2409895A1 (de) | 1974-09-12 |
| BR7401511D0 (pt) | 1974-10-29 |
| CA1021671A (en) | 1977-11-29 |
| ZA741175B (en) | 1975-01-29 |
| BE811618A (fr) | 1974-06-17 |
| IT1003625B (it) | 1976-06-10 |
| SE393126B (sv) | 1977-05-02 |
| IN141411B (enrdf_load_stackoverflow) | 1977-02-26 |
| DE2409895C3 (de) | 1981-09-24 |
| AU6594374A (en) | 1975-08-28 |
| FR2219980A1 (enrdf_load_stackoverflow) | 1974-09-27 |
| GB1452699A (en) | 1976-10-13 |
| JPS5423332B2 (enrdf_load_stackoverflow) | 1979-08-13 |
| NL7402637A (enrdf_load_stackoverflow) | 1974-09-03 |
| AR203191A1 (es) | 1975-08-22 |
| FR2219980B1 (enrdf_load_stackoverflow) | 1976-12-10 |
| RO69745A (ro) | 1981-11-04 |
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