CO7101237A2 - Proceso optimizado para mejorar bioaceites en combustibles de hidrocarburo - Google Patents

Proceso optimizado para mejorar bioaceites en combustibles de hidrocarburo

Info

Publication number
CO7101237A2
CO7101237A2 CO14224583A CO14224583A CO7101237A2 CO 7101237 A2 CO7101237 A2 CO 7101237A2 CO 14224583 A CO14224583 A CO 14224583A CO 14224583 A CO14224583 A CO 14224583A CO 7101237 A2 CO7101237 A2 CO 7101237A2
Authority
CO
Colombia
Prior art keywords
hydroforming
bio
stage
feed
oil
Prior art date
Application number
CO14224583A
Other languages
English (en)
Inventor
Antoine Daudin
Alain Quignard
Olivier Thinon
Original Assignee
IFP Energies Nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles filed Critical IFP Energies Nouvelles
Publication of CO7101237A2 publication Critical patent/CO7101237A2/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00—Macromolecular compounds derived from lignocellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención se refiere a un proceso para la producción de productos de hidrocarburo a partir de una alimentación que comprende al menos un bioaceite no pre-tratado, tal alimentación siendo introducida en al menos un primer paso para hidroformar en presencia de hidrógeno y un catalizador de hidroformado que comprende al menos un metal de transición seleccionado de los elementos de los grupos 3 a12 de la clasificación periódica de los elementos y al menos un soporte seleccionado de carbón activado, carburos de silicio, sílices, alúminas de transición, sílice-alúminas, óxido de circonio, óxido de cerlo, óxido de titanio y aluminatos de metales de transición, usados solos o como una mezcla, con el fin de obtener al menos un efluente líquido que comprende al menos una etapa acuosa y almenos una etapa orgánica, un segundo paso para hidrotratamiento y/o hidrocraqueo de al menos una porción de la etapa orgánica del efluente obtenido del primer pasode hidroformado con el fin de obtener un efluente de hidrocarburo, en el que al menos una parte de la etapa orgánica del efluente obtenido del primer paso de hidroformado se recicle en el primer paso de hidroformado como una mezcla con dicha alimentación que comprende al menos un bioaceite, con una relación de reciclado igual a la relación de la tasa de flujo másico de dicha etapa orgánica a la tasa de flujo másico del bioaceite no pre-tratado en el rango de 0,05 a 2 y en el que el efluente de hidrocarburo obtenido del paso de hidrotratamiento y/o hidrocraqueo no se recicle en dicho primer paso de hidroformado.
CO14224583A 2012-03-12 2014-10-09 Proceso optimizado para mejorar bioaceites en combustibles de hidrocarburo CO7101237A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1200744A FR2987842B1 (fr) 2012-03-12 2012-03-12 Procede optimise pour la valorisation de bio-huiles en carburants hydrocarbones

Publications (1)

Publication Number Publication Date
CO7101237A2 true CO7101237A2 (es) 2014-10-31

Family

ID=48014063

Family Applications (1)

Application Number Title Priority Date Filing Date
CO14224583A CO7101237A2 (es) 2012-03-12 2014-10-09 Proceso optimizado para mejorar bioaceites en combustibles de hidrocarburo

Country Status (10)

Country Link
US (1) US9644154B2 (es)
EP (1) EP2825617B1 (es)
CN (1) CN104411802B (es)
AR (1) AR090304A1 (es)
AU (1) AU2013234159B2 (es)
CA (1) CA2863900A1 (es)
CO (1) CO7101237A2 (es)
FR (1) FR2987842B1 (es)
MY (1) MY169812A (es)
WO (1) WO2013135986A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3012467B1 (fr) * 2013-10-24 2015-12-18 IFP Energies Nouvelles Procede optimise de conversion de la biomasse pour la fabrication de bases petrochimiques
FR3024156B1 (fr) * 2014-07-25 2016-07-29 Ifp Energies Now Procede optimise pour la valorisation de bio-huiles en carburants hydrocarbones
US10266774B2 (en) * 2014-10-03 2019-04-23 Southwest Research Institute Feedstock conversion to fuel on high pressure circulating fluidized bed
FR3034099B1 (fr) * 2015-03-27 2019-05-10 IFP Energies Nouvelles Procede optimise de conversion de bio-huile avec stabilisation de la charge
EP3138892A1 (en) * 2015-09-03 2017-03-08 Synthopetrol Use of multifunctional magnetic catalysts for the transformation of biomass
CN108085037B (zh) * 2016-11-21 2020-06-16 北京华石联合能源科技发展有限公司 一种生物质液化生产轻质油的方法
US10961459B2 (en) * 2018-08-20 2021-03-30 Marc A. Seidner System for production of a renewable liquid fuel
CN111468097B (zh) * 2020-03-24 2023-03-03 福州大学化肥催化剂国家工程研究中心 一种催化裂化催化剂及其制备方法和应用
FR3122661B1 (fr) * 2021-05-04 2024-05-17 Ifp Energies Now Procede optimise d'hydrotraitement et d’hydroconversion de charges issues de sources renouvelables
CN113403105B (zh) * 2021-06-10 2022-12-27 克拉玛依市先能科创重油开发有限公司 乙烯裂解焦油为原料的悬浮床加氢装置的开工进油方法

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Publication number Priority date Publication date Assignee Title
US4411768A (en) 1979-12-21 1983-10-25 The Lummus Company Hydrogenation of high boiling hydrocarbons
US4308411A (en) 1980-08-28 1981-12-29 Occidental Research Corporation Process for converting oxygenated hydrocarbons into hydrocarbons
US4795841A (en) 1987-04-02 1989-01-03 Elliott Douglas C Process for upgrading biomass pyrolyzates
GB9426066D0 (en) 1994-12-22 1995-02-22 Radlein Desmond S G Method of upgrading biomass pyrolysis liquids for use as fuels and as a source of chemicals by reaction with alcohols
US5820640A (en) 1997-07-09 1998-10-13 Natural Resources Canada Pyrolysis liquid-in-diesel oil microemulsions
FR2863913B1 (fr) 2003-12-23 2006-12-29 Inst Francais Du Petrole Catalyseur zeolithique,support a base de matrice silico-aluminique et de zeolithe, et procede d'hydrocraquage de charges hydrocarbonees
US7578927B2 (en) 2006-08-31 2009-08-25 Uop Llc Gasoline and diesel production from pyrolytic lignin produced from pyrolysis of cellulosic waste
ITMI20062193A1 (it) * 2006-11-15 2008-05-16 Eni Spa Processo per produrre frazioni idrocarburiche da miscele di origine biologica
US8329968B2 (en) * 2008-04-06 2012-12-11 Uop Llc Production of blended gasoline aviation and diesel fuels from renewable feedstocks
JP2011517470A (ja) 2008-04-06 2011-06-09 ユーオーピー エルエルシー バイオマス由来熱分解油からの燃料および燃料ブレンド成分
EP2504412B1 (en) * 2009-11-24 2015-09-23 Shell Internationale Research Maatschappij B.V. Process for catalytic hydrotreatment of a pyrolysis oil
EP2638129A2 (en) * 2010-09-14 2013-09-18 IFP Energies nouvelles Methods of upgrading biooil to transportation grade hydrocarbon fuels

Also Published As

Publication number Publication date
AR090304A1 (es) 2014-11-05
AU2013234159A1 (en) 2014-10-16
EP2825617B1 (fr) 2018-11-07
CN104411802A (zh) 2015-03-11
CA2863900A1 (fr) 2013-09-19
US20150065764A1 (en) 2015-03-05
US9644154B2 (en) 2017-05-09
AU2013234159B2 (en) 2017-03-16
FR2987842A1 (fr) 2013-09-13
WO2013135986A1 (fr) 2013-09-19
FR2987842B1 (fr) 2015-02-27
MY169812A (en) 2019-05-16
CN104411802B (zh) 2018-01-02
EP2825617A1 (fr) 2015-01-21

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