CN202716503U - Machinable glass ceramic composite board with three-dimensional pattern - Google Patents

Machinable glass ceramic composite board with three-dimensional pattern Download PDF

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Publication number
CN202716503U
CN202716503U CN 201220398431 CN201220398431U CN202716503U CN 202716503 U CN202716503 U CN 202716503U CN 201220398431 CN201220398431 CN 201220398431 CN 201220398431 U CN201220398431 U CN 201220398431U CN 202716503 U CN202716503 U CN 202716503U
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China
Prior art keywords
layer
glass
pattern
adobe
glass ceramic
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Expired - Lifetime
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CN 201220398431
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Chinese (zh)
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谢东生
杜贵平
吕卫华
邓文锋
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GUANGDONG JINPAI CERAMIC CO Ltd
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GUANGDONG JINPAI CERAMIC CO Ltd
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Abstract

The utility model provides a machinable glass ceramic composite board with a three-dimensional pattern. The machinable glass ceramic composite board comprises a green brick layer, a ground coat enamel layer, a printed layer and glass ceramic layer from bottom to top. The machinable glass ceramic composite board is characterized in that a convex-concave pattern is positioned on the upper surface of the green brick layer, and the ground coat enamel layer and the printed layer fluctuate along with the convex-concave pattern on the upper surface of the green brick layer. Pattern and color combination between the convex-concave pattern on the upper surface of the green brick layer and the printed layer enables products to be attractive. Simultaneously, convex-concave surface texture is continuous and natural in transition. Pattern effects can be combined multiply, designable space is large, color and gloss collocation decoration effects are rich, and optical refraction of the surface of the glass ceramic layer enables products to be strong in three-dimensional sense.

Description

A kind of glass-ceramic clad plate with space pattern
Technical field
The utility model provides a kind of glass-ceramic clad plate with space pattern, belongs to the inorganic composite materials field.
Background technology
Glass-ceramic clad plate also claims compound microlite, and compound microlite is to be the composite board that the devitrified glass of 1~5mm is compounded in the ceramics vitrified brick surface with thickness.Because its surface is glass-ceramic layer, thus fully antifouling, maintenance convenient for cleaning; It has avoided the radiological hazard of lithotome in addition, belongs to "dead" product, is ornamental desirable green building material.Color and luster is natural, sparkling and crystal-clear penetrating, will never fade characteristics, has the decorative effect of nature jade, is the first-selection of present high-grade wall ground brick product.Blemish in an otherwise perfect thing be that present glass-ceramic clad plate or the decorative effect of two dimensional surface is main, this is not so that the floral designs on the brick have solid layer feeling.Then can fill up above blank if can produce the glass-ceramic clad plate with stereoeffect, give product more high-grade decorative effect, obtain larger profit margin.
Summary of the invention
For addressing the above problem, the utility model provides a kind of glass-ceramic clad plate product with space pattern.
A kind of glass-ceramic clad plate with space pattern, it comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, and wherein adobe layer upper surface has relief pattern, and ground glaze layer, printed layer rise and fall with the relief pattern of adobe layer upper surface.
Above-mentioned glass-ceramic clad plate with space pattern, the distance D between the datum level of the high spot of wherein said relief pattern and recess and adobe layer upper surface is 0.2~1mm.
More preferably, above-mentioned glass-ceramic clad plate with space pattern, the distance D between the datum level of the high spot of wherein said relief pattern and recess and adobe layer upper surface is 0.2~0.5mm.
Above-mentioned glass-ceramic clad plate with space pattern, wherein ground glaze layer thickness is 0.05~0.2mm.
Above-mentioned glass-ceramic clad plate with space pattern, wherein printed layer thickness is 0.01~0.1mm.
Above-mentioned glass-ceramic clad plate with space pattern, wherein the thickness of glass-ceramic layer is 1~3mm.
More preferably, above-mentioned glass-ceramic clad plate with space pattern, wherein the thickness of glass-ceramic layer is 1.5~1.8mm.
Above-mentioned glass-ceramic clad plate with space pattern can be by the method manufacturing that comprises the steps:
(1) the conventional composition of raw materials of Ceramics brick is made powder, powder is pressed into the entire body adobe or comprises initial bed and the adobe of precoat by instead playing the cloth backlash, the die cavity of employed diel has relief pattern in this step, between the datum level of the high spot of relief pattern and recess and die cavity is 0.22~1.1mm apart from d, and the upper surface of adobe also has relief pattern in contrast like this;
(2) behind the brick blank drying, clean its surface, execute ground-coat enamel and form ground glaze layer, carry out again the printed layer that ink-jet printed formation has set pattern;
(3) enter roller kilns and carry out burning till the first time, 1210~1230 ℃ of firing temperatures, firing period 90~180 minutes;
(4) dispensing glass ceramics frit through the adobe surface of burning till for the first time;
(5) enter roller kilns and carry out burning till the second time, 1000~1100 ℃ of firing temperatures, firing period 100~300 minutes;
(6) burn till for the second time after, carry out edging and polishing, obtaining the glass-ceramic layer upper surface is that mirror finish effect, lower surface are the glass-ceramic clad plate product with 3D space pattern.
In the said method, the ground glaze layer thickness described in the step (2) is 0.05~0.2mm, and printed layer thickness is 0.01~0.1mm, and ground glaze layer and printed layer rise and fall with the relief pattern of adobe layer upper surface.
In the said method, preferably, step (3) preferably firing temperature is 1220 ℃, and firing period is 150 minutes.
In the said method, the formation glass-ceramic layer of glass ceramics frit consumption after to burn can cover the relief pattern in the adobe fully and can form thickness after melting and be advisable as 2~5mm flat surface in the step (4), and the granularity of glass ceramics frit particle is 30~40 orders.
In the said method, preferably, firing temperature is 1050 ℃ in the step (5), and firing period is 180 minutes.
In the said method, the rear devitrified glass layer thickness of polishing is 1~3mm in the step (6).
Because the refractive index of glass-ceramic layer is 1.4~1.5, devitrified glass layer thickness 1.5~1.8mm more preferably after the polishing, under this thickness, the sense that more has levels of the floral designs of printed layer, stereoeffect is more true to nature.
This programme has following advantage:
1, can make product have more aesthetic by the relief pattern of adobe upper surface and pattern, the color scheme of printed layer, simultaneously convex-concave surface texture transition is continuous, nature, pattern effect can have Multiple Combination, but the design space is large, have abundant color, gloss collocation decorative effect, the light refraction of surperficial glass-ceramic layer makes product have more third dimension.
2, the production technology of this product is to reform on the basis of existing maturation process, the technique simple and stable, and quality percentage is high.
Description of drawings
The adobe cross sectional representation of accompanying drawing 1 for after the male and female mold punching press, forming;
Accompanying drawing 2 is adobe layer cross sectional representation in the final products, has wherein indicated datum level and D;
Accompanying drawing 3 forms the cross sectional representation behind the ground glaze layer for adobe is surperficial;
Accompanying drawing 4 forms the cross sectional representation after ground glaze layer and the printed layer for adobe is surperficial;
Accompanying drawing 5 is the cross sectional representation of final products.
Drawing reference numeral explanation: 101-adobe layer; 201-ground glaze layer; 301-printed layer; 401-glass-ceramic layer; The datum level of 501-adobe layer upper surface; Distance between the datum level of the high spot of D-relief pattern and recess and adobe layer upper surface.
The specific embodiment
The technical solution of the utility model with reference to accompanying drawing, and provide following specific embodiment in order better to illustrate, by following description, those skilled in the art can well understand this programme, and the easier advantage that it brings.Need to prove that the accompanying drawing content only is the schematic diagram of explanation technical scheme, is not to draw according to actual ratio, wherein for some feature is described, can zoom in or out local feature.Simultaneously in order to save the specification length, the technology of mentioning in known or some background patents for those skilled in the art will be done some omissions.
Embodiment 1
(1) punching press forms adobe
In this step, conventional formulation gets final product in the Ceramics production technology.Namely the raw material take conventional raw materials such as feldspar, quartz, clay, talcums as main component by the spray drying tower spray-drying, is made powder through ball milling, deironing, old homogenizing, and the powder moisture content is 3~7%; By instead beat the cloth system cloth (instead beat adobe upper surface when being punching press under distributing mode), send into the press punching press behind the cloth, the formation adobe.The die cavity of diel has relief pattern, and between the datum level of the high spot of relief pattern and recess and die cavity is 0.22~1.1mm apart from d.The upper surface that punching press forms rear adobe also has relief pattern in contrast, the cross section of adobe as shown in Figure 1, the composition of relief pattern is preferably designer's design and arranges in pairs or groups mutually with the floral designs of follow-up formation printed layer and be advisable.Adobe after the punching press enters the dry kiln oven dry, makes dry ceramic adobe.
(2) execute ground-coat enamel, formation printed layer
As shown in Figure 3, through the adobe of step 1 drying, the cleaning billet surface, through long conveyer belt, glaze formation ground glaze layer is drenched through bell jar in the surface thereon, and ground-coat enamel is that well-known components gets final product, and selects the ground glaze layer of white in the present embodiment, ground glaze layer thickness is 0.1mm, certainly thickness can have certain floating, in force mainly by control single-piece base substrate consume ground-coat enamel quality control thickness, in the present embodiment, adobe is 920 * 920mm, and the ground-coat enamel consumption is about 300 g/pieces.Then form printed layer, the floral designs of printed layer are to arrange in pairs or groups mutually with adobe upper surface relief pattern layer, and printed layer is the formed trash ice crystal pattern of inkjet printing pattern in the present embodiment, and relief pattern is the pattern corresponding with the lines in the trash ice crystalline substance.Ink-jet print system is the four look ceramic ink jet printing machines of wishing that ceramic machinery Co., Ltd produces, and ink is palm fibre, Huang, indigo plant, brown four chromatic inks that Spain Yi Dajia (esmaglassitaca) company produces.The printed layer thickness that inkjet printing forms is 0.01~0.1mm.As shown in Figure 4, because of ground glaze layer and stamp very thin thickness, so its relief pattern with adobe layer upper surface rises and falls.
(3) burn till for the first time
Burn till the selection roller kilns, firing temperature is 1220 ℃ in the present embodiment, firing period 150 minutes.After burning till for the first time, the adobe porcelain.
(4) dispense glass ceramics frit
Select transparent glass-ceramics frit commonly used in the industry in the present embodiment, the formation glass-ceramic layer of glass ceramics frit consumption after to burn can cover the relief pattern in the adobe fully and can form thickness after melting and be advisable as 2~5mm flat surface, be specially 3~4kg/ sheet, the granularity of glass ceramics frit is 30~40 orders.
(5) burn till for the second time
Burn till the selection roller kilns, firing temperature is 1050 ℃ in the present embodiment, firing period 180 minutes.Behind the twice firing, the devitrified glass melting forms glass-ceramic layer.
(6) edging, polishing
Goods to twice firing carry out edging, polishing, and the acquisition size is regular, the glass-ceramic layer upper surface is that mirror finish effect, lower surface are the glass-ceramic clad plate product with 3D space pattern.The devitrified glass layer thickness is 1~3mm after the polishing, is more preferably 1.5~1.8mm.
Embodiment 2
The present embodiment difference from Example 1 is:
1, the relief pattern that forms on the adobe surface in the step (1) is that having of similar natural rosin jade is radial, the acicular crystal cleavage, and between the datum level of the high spot of relief pattern and recess and die cavity is 0.22~0.55mm apart from d;
2, decalcomania is radial, the acicular crystal cleavage pattern that has of the similar natural rosin jade corresponding with step 1 in the step (2), and color is take brown coffee color as main;
3, the once-firing temperature is 1230 ℃ in the step (3), and firing period is 100 minutes;
4, the twice firing temperature is 1110 ℃ in the step (5), firing period 110 minutes.
It should be noted that at last, above embodiment is only in order to describe the technical solution of the utility model rather than the present technique method is limited, the utility model can extend to other modification, variation, application and embodiment on using, and therefore thinks that all such modifications, variation, application, embodiment are in spirit of the present utility model and teachings.

Claims (7)

1. glass-ceramic clad plate with space pattern, it comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, it is characterized in that, adobe layer upper surface has relief pattern, and ground glaze layer, printed layer rise and fall with the relief pattern of adobe layer upper surface.
2. the glass-ceramic clad plate with space pattern as claimed in claim 1 is characterized in that, the distance D between the datum level of the high spot of described relief pattern and recess and adobe layer upper surface is 0.2~1mm.
3. the glass-ceramic clad plate with space pattern as claimed in claim 2 is characterized in that, the distance D between the datum level of the high spot of described relief pattern and recess and adobe layer upper surface is 0.2~0.5mm.
4. the glass-ceramic clad plate with space pattern as claimed in claim 1 is characterized in that, the thickness of described ground glaze layer is 0.05~0.2mm.
5. the glass-ceramic clad plate with space pattern as claimed in claim 1 is characterized in that, the thickness of described printed layer is 0.01~0.1mm.
6. the glass-ceramic clad plate with space pattern as claimed in claim 1 is characterized in that, the thickness of described glass-ceramic layer is 1~3mm.
7. the glass-ceramic clad plate with space pattern as claimed in claim 6 is characterized in that, the thickness of described glass-ceramic layer is 1.5~1.8mm.
CN 201220398431 2012-08-13 2012-08-13 Machinable glass ceramic composite board with three-dimensional pattern Expired - Lifetime CN202716503U (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106396426A (en) * 2016-11-02 2017-02-15 佛山市梦唐装饰材料有限公司 5D dynamic micro-crystal composite ceramic product and manufacturing method thereof
CN110981553A (en) * 2019-12-17 2020-04-10 佛山欧神诺陶瓷有限公司 Transparent amber-like ceramic tile and preparation method thereof
CN112449515A (en) * 2019-08-27 2021-03-05 Oppo广东移动通信有限公司 Shell and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106396426A (en) * 2016-11-02 2017-02-15 佛山市梦唐装饰材料有限公司 5D dynamic micro-crystal composite ceramic product and manufacturing method thereof
CN112449515A (en) * 2019-08-27 2021-03-05 Oppo广东移动通信有限公司 Shell and manufacturing method thereof
CN110981553A (en) * 2019-12-17 2020-04-10 佛山欧神诺陶瓷有限公司 Transparent amber-like ceramic tile and preparation method thereof
CN110981553B (en) * 2019-12-17 2021-12-17 佛山欧神诺陶瓷有限公司 Transparent amber-like ceramic tile and preparation method thereof

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Granted publication date: 20130206

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