CN202716504U - Machinable glass ceramic composite board - Google Patents
Machinable glass ceramic composite board Download PDFInfo
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- CN202716504U CN202716504U CN 201220398445 CN201220398445U CN202716504U CN 202716504 U CN202716504 U CN 202716504U CN 201220398445 CN201220398445 CN 201220398445 CN 201220398445 U CN201220398445 U CN 201220398445U CN 202716504 U CN202716504 U CN 202716504U
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Abstract
The utility model provides a machinable glass ceramic composite board which comprises a green brick layer, a ground coat enamel layer, a printed layer and glass ceramic layer from bottom to top. Dispersive noctilucent areas are arranged in the glass ceramic layer. When the environment turns dark from bright, long afterflow fluorescent materials in the noctilucent areas can release absorbed photon energy to send out fluorescence. Due to that fact that doping ions mixed in the long afterflow fluorescent materials are different, fluorescence colors are different. Natural strange landscapes of bright twinkling star rivers, gorgeous baffling nebulas and the like can be presented in bricks so as to greatly enrich product decoration effects.
Description
Technical field
The utility model provides a kind of glass-ceramic clad plate, belongs to the inorganic composite materials field.
Background technology
Glass-ceramic clad plate also claims compound microlite, and compound microlite is to be the composite board that the devitrified glass of 1～5mm is compounded in the ceramics vitrified brick surface with thickness.Because its surface is glass-ceramic layer, thus fully antifouling, maintenance convenient for cleaning; It has avoided the radiological hazard of lithotome in addition, belongs to "dead" product, is ornamental desirable green building material.Color and luster is natural, sparkling and crystal-clear penetrating, will never fade characteristics, has the decorative effect of nature jade, is the first-selection of present high-grade wall ground brick product.Yet turned in the dark process by bright at environment, the color of product, pattern also thicken unclear gradually.If break above-mentioned restriction, provide a kind of and turned in the dark process not by other illuminations by bright at environment, also have the product of decorative effect, and this decorative effect of tool is in a ratio of different brand-new styles with existing product, then can enrich the product strain, obtain larger profit margin.
Summary of the invention
For addressing the above problem, the utility model provides a kind of glass-ceramic clad plate product.By before dispensing glass ceramics frit, dispensing first long-afterglow fluorescent material or containing the frit particle of long-afterglow fluorescent material, after the glass ceramics frit melting, in glass-ceramic layer, form the noctilucence zone, so externally environment is turned in the dark process by bright, long-afterglow fluorescent material in the noctilucence zone discharges its photon energy that absorbs, send fluorescence, fluorescence color is different because of the doping ion in the long-afterglow fluorescent material.
A kind of glass-ceramic clad plate, it comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, and the noctilucence zone of dispersion is wherein arranged in glass-ceramic layer.
Above-mentioned glass-ceramic clad plate, wherein the noctilucence zone is distributed as random distribution in glass-ceramic layer.
More preferably, above-mentioned glass-ceramic clad plate, wherein the noctilucence zone distributes along printed layer pattern lines in glass-ceramic layer.
Preferred, above-mentioned glass-ceramic clad plate, wherein adobe layer upper surface has relief pattern, and ground glaze layer, printed layer rise and fall with the relief pattern of adobe layer upper surface.
Above-mentioned glass-ceramic clad plate, wherein the noctilucence area distribution is at the recess of relief pattern.
Above-mentioned glass-ceramic clad plate can be made by the following method:
(1) the conventional composition of raw materials of Ceramics brick is made powder, and powder is pressed into the entire body adobe or comprises initial bed and the adobe of precoat by instead playing the cloth backlash.
(2) behind the brick blank drying, clean its surface, execute ground-coat enamel and form ground glaze layer, carry out again the printed layer that ink-jet printed formation has set pattern;
(3) enter roller kilns and carry out burning till the first time, 1210～1230 ℃ of firing temperatures, firing period 90～180 minutes;
(4) dispense long-afterglow fluorescent material or contain the frit particle of above-mentioned long-afterglow fluorescent material;
(5) dispense glass ceramics frit;
(6) enter roller kilns and carry out burning till the second time, form noctilucence layer and the glass-ceramic layer on noctilucence layer, 1000～1100 ℃ of firing temperatures, firing period 100～300 minutes;
(7) burn till for the second time after, carry out edging and polishing.
In the said method, the long-afterglow fluorescent material that dispenses or the frit particle that contains above-mentioned long-afterglow fluorescent material are random distribution.
In the said method, preferably, the long-afterglow fluorescent material that dispenses or the frit particle that contains above-mentioned long-afterglow fluorescent material are for to distribute along printed layer pattern lines.
In the said method, preferably, step (3) preferably firing temperature is 1220 ℃, and firing period is 150 minutes.
In the said method, preferably, firing temperature is 1050 ℃ in the step (6), and firing period is 180 minutes.
Preferably, the die cavity of the employed diel of step 1 has relief pattern, and between the datum level of the high spot of relief pattern and recess and die cavity is 0.22～1.1mm apart from d.More preferably, slight vibrations adobe after step (4) dispenses long-afterglow fluorescent material or contains the frit particle of above-mentioned long-afterglow fluorescent material, the frit that makes long-afterglow fluorescent material or contain above-mentioned long-afterglow fluorescent material mainly falls into the recess of its region.
Above-mentioned relief pattern is preferably corresponding with printed layer pattern master texture, and can make like this noctilucence zone is that main texture along with the brick face moves towards to distribute haply, has levels and the train of thought sense.
This programme has following advantage:
1, when environment by bright turn dark after, long-afterglow fluorescent material in the noctilucence layer discharges its photon energy that absorbs, send fluorescence, fluorescence color is different different because of the doping ion in the long-afterglow fluorescent material, can present in every brick the natures such as nebula of bright twinkLing stars river, bright-colored change are magical.
2, the production technology of this product is to reform on the basis of existing maturation process, the technique simple and stable, and quality percentage is high.
Description of drawings
Accompanying drawing 1 is the cross sectional representation of the utility model embodiment 1 corresponding product;
Accompanying drawing 2 is the cross sectional representation of the utility model embodiment 3 corresponding products.
The drawing reference numeral explanation:
101-adobe layer; 201-ground glaze layer; 301-printed layer; 401-noctilucence zone; 501-glass-ceramic layer.
The specific embodiment
The technical solution of the utility model with reference to accompanying drawing, and provide following specific embodiment in order better to illustrate, by following description, those skilled in the art can well understand this programme, and the easier advantage that it brings.Need to prove that the accompanying drawing content only is the schematic diagram of explanation technical scheme, is not to draw according to actual ratio, wherein for some feature is described, can local feature be zoomed in or out, and the cross section of accompanying drawing 1 and accompanying drawing 2 corresponding diverse locations can be different.Simultaneously in order to save the specification length, the technology of mentioning in known or some backgrounds for those skilled in the art will be done some omissions.
Embodiment 1
With reference to accompanying drawing 1, the product of this practical embodiment comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, and the noctilucence zone of dispersion is wherein arranged in glass-ceramic layer, and above-mentioned noctilucence zone is distributed as random distribution in glass-ceramic layer.
Its preparation method is as follows:
(1) punching press forms adobe
In this step, conventional formulation gets final product in the Ceramics production technology.Namely the raw material take conventional raw materials such as feldspar, quartz, clay, talcums as main component by the spray drying tower spray-drying, is made powder through ball milling, deironing, old homogenizing, and the powder moisture content is 3～7%; Send into the press punching press behind the cloth, form adobe.Adobe after the punching press enters the dry kiln oven dry, makes dry ceramic adobe.
(2) execute ground-coat enamel, formation printed layer
As shown in Figure 3, through the adobe of step 1 drying, the cleaning billet surface, through long conveyer belt, glaze formation ground glaze layer is drenched through bell jar in the surface thereon, and ground-coat enamel is that well-known components gets final product, and selects the ground glaze layer of white in the present embodiment, ground glaze layer thickness is 0.1mm, certainly thickness can have certain floating, in force mainly by control single-piece base substrate consume ground-coat enamel quality control thickness, in the present embodiment, adobe is 920 * 920mm, and the ground-coat enamel consumption is about 300 g/pieces.Then form printed layer, printed layer is the formed trash ice crystal pattern of inkjet printing pattern in the present embodiment.Ink-jet print system is the four look ceramic ink jet printing machines of wishing that ceramic machinery Co., Ltd produces, and ink is palm fibre, Huang, indigo plant, brown four chromatic inks that Spain Yi Dajia (esmaglassitaca) company produces.The printed layer thickness that inkjet printing forms is 0.01～0.1mm.
(3) burn till for the first time
Burn till the selection roller kilns, firing temperature is 1220 ℃ in the present embodiment, firing period 150 minutes.After burning till for the first time, the adobe porcelain.
(4) dispense long-afterglow fluorescent material or contain the frit particle of long-afterglow fluorescent material
Select the frit particle that contains long-afterglow fluorescent material in the present embodiment, it is blue series that long-afterglow fluorescent material is selected twilight sunset.The complete all standing printed layer that needs of the frit of charity, above-mentioned frit granularity is 3～30 orders, consumption is about 30～50g/ sheet in the present embodiment;
(5) dispense glass ceramics frit
Select transparent glass-ceramics frit commonly used in the industry in the present embodiment, the formation glass-ceramic layer of glass ceramics frit consumption after to burn can cover the relief pattern in the adobe fully and can form thickness after melting and be advisable as 2～5mm flat surface, the glass ceramics frit consumption is 4～5kg/ sheet in the present embodiment, and the granularity of glass ceramics frit is 30～40 orders.
(6) burn till for the second time
Burn till the selection roller kilns, firing temperature is 1050 ℃ in the present embodiment, firing period 180 minutes.Behind the twice firing, the devitrified glass melting forms glass-ceramic layer.
(7) edging, polishing
Goods to twice firing carry out edging, polishing, obtain size regular, the product of surfacing.The devitrified glass layer thickness is about 1.5mm after the polishing.
Goods are turned in the dark process by bright in external environment, and long-afterglow fluorescent material discharges the photon energy that absorbs, and the product surface subregion has nattier blue radiance, brings out the best in each other with the printed layer pattern, enhances each other's beauty, if the bright Milky Way has an array of stars indistinct.
Embodiment 2
The product of the present embodiment comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, and the noctilucence zone of dispersion is wherein arranged in glass-ceramic layer, and above-mentioned noctilucence zone distributes along printed layer pattern lines in glass-ceramic layer.
The production technology of the present embodiment product and embodiment 1 are described basic identical, dispense along printed layer pattern lines when institute's difference is to dispense in the step 4 the frit particle that contains long-afterglow fluorescent material.
Embodiment 3
The product of the present embodiment comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, adobe layer upper surface has relief pattern, ground glaze layer, printed layer rise and fall with the relief pattern of adobe layer upper surface, and wherein the noctilucence area distribution is at the recess of relief pattern.
Its preparation technology is with enforcement 1 difference:
1, the die cavity of employed diel has relief pattern in the step (1),, acicular crystal cleavage radial for having of similar natural rosin jade, high spot and the datum level of recess and die cavity between be 0.22～1.1mm apart from d;
2, decalcomania is radial, the acicular crystal cleavage pattern that has of the similar natural rosin jade corresponding with step 1 in the step (2), and color is take brown coffee color as main;
3, main lines radial along having of rosin jade in the step (4), acicular crystal cleavage pattern dispenses the frit particle that contains long-afterglow fluorescent material, and it is orange red colour system that long-afterglow fluorescent material is selected twilight sunset.The frit grain graininess is 3～30 orders, and the frit consumption is 30～60g/ sheet.Slightly shake adobe after dispensing frit, make the frit particle that contains above-mentioned long-afterglow fluorescent material mainly fall into the recess of its region.
Goods are turned in the dark process by bright in external environment, long-afterglow fluorescent material discharges the photon energy that absorbs, the product surface subregion has orange-red radiance, these twilight sunset mainly concentrate on the main texture place of the similar natural rosin jade of printed layer simultaneously, the combination of twilight sunset and patterned layer makes goods have magical effect as the nebula of bright-colored change.
It should be noted that at last, above embodiment is only in order to describe the technical solution of the utility model rather than the present technique method is limited, the utility model can extend to other modification, variation, application and embodiment on using, and therefore thinks that all such modifications, variation, application, embodiment are in spirit of the present utility model and teachings.
Claims (5)
1. glass-ceramic clad plate, it comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, it is characterized in that, the noctilucence zone of dispersion is arranged in glass-ceramic layer.
2. glass-ceramic clad plate as claimed in claim 1 is characterized in that, described noctilucence zone is distributed as random distribution in glass-ceramic layer.
3. glass-ceramic clad plate as claimed in claim 1 is characterized in that, described noctilucence zone distributes along printed layer pattern lines in glass-ceramic layer.
4. glass-ceramic clad plate as claimed in claim 1 is characterized in that, described adobe layer upper surface has relief pattern, and ground glaze layer, printed layer rise and fall with the relief pattern of adobe layer upper surface.
5. glass-ceramic clad plate as claimed in claim 4 is characterized in that, described noctilucence area distribution is at the recess of relief pattern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220398445 CN202716504U (en) | 2012-08-13 | 2012-08-13 | Machinable glass ceramic composite board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220398445 CN202716504U (en) | 2012-08-13 | 2012-08-13 | Machinable glass ceramic composite board |
Publications (1)
| Publication Number | Publication Date |
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| CN202716504U true CN202716504U (en) | 2013-02-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201220398445 Expired - Lifetime CN202716504U (en) | 2012-08-13 | 2012-08-13 | Machinable glass ceramic composite board |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108623332A (en) * | 2018-04-16 | 2018-10-09 | 佛山市三水新明珠建陶工业有限公司 | A kind of production method with fluorescence falsification preventing mark Ceramic Tiles |
| CN113233921A (en) * | 2021-05-18 | 2021-08-10 | 广东宏海陶瓷实业发展有限公司 | Preparation method of mold texture ceramic tile and ceramic tile |
-
2012
- 2012-08-13 CN CN 201220398445 patent/CN202716504U/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108623332A (en) * | 2018-04-16 | 2018-10-09 | 佛山市三水新明珠建陶工业有限公司 | A kind of production method with fluorescence falsification preventing mark Ceramic Tiles |
| CN108623332B (en) * | 2018-04-16 | 2021-08-10 | 佛山市三水新明珠建陶工业有限公司 | Production method of ceramic tile with fluorescent anti-counterfeiting mark |
| CN113233921A (en) * | 2021-05-18 | 2021-08-10 | 广东宏海陶瓷实业发展有限公司 | Preparation method of mold texture ceramic tile and ceramic tile |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20130206 |
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| CX01 | Expiry of patent term |