CN102775074A - Method for producing microcrystal glass ceramics composite board - Google Patents

Method for producing microcrystal glass ceramics composite board Download PDF

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Publication number
CN102775074A
CN102775074A CN2012102858906A CN201210285890A CN102775074A CN 102775074 A CN102775074 A CN 102775074A CN 2012102858906 A CN2012102858906 A CN 2012102858906A CN 201210285890 A CN201210285890 A CN 201210285890A CN 102775074 A CN102775074 A CN 102775074A
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China
Prior art keywords
glass
layer
production technique
ceramic clad
convex pattern
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Pending
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CN2012102858906A
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Chinese (zh)
Inventor
谢东生
杜贵平
吕卫华
邓文锋
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GUANGDONG JINPAI CERAMIC CO Ltd
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GUANGDONG JINPAI CERAMIC CO Ltd
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Priority to CN2012102858906A priority Critical patent/CN102775074A/en
Publication of CN102775074A publication Critical patent/CN102775074A/en
Pending legal-status Critical Current

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Abstract

The invention provides a method for producing a microcrystal glass ceramics composite board. The method comprises the following steps of: 1) applying powder and stamping to form a green brick; 2) forming a ground coat layer and a printing layer; 3) carrying out primary firing; 4) dispersing microcrystal glass fusion blocks; 5) carrying out secondary firing; and 6) edging and polishing, wherein a die cavity of a stamping mould used in step 1) has a concave-convex pattern, and the distance d between the raised place of the concave-convex pattern and the reference surface of the die cavity and the distance d between the recessed place of the concave-convex pattern and the reference surface of the die cavity are 0.22-1.1mm. The concave-convex pattern, the pattern of the printing layer and the color combination on the upper surface of a green brick layer of the glass ceramics composite board endow the product with an aesthetic feeling, the concave-convex surface texture transition is continuous and natural, the pattern effect can be combined in multiple ways, the designable space is large, abundant color and gloss matching decorating effects are provided, and the optical refraction of the surface crystallite glass layer ensures that the product has a three-dimensional feeling.

Description

A kind of production technique of making glass-ceramic clad plate
Technical field
The present invention provides a kind of production technique of making glass-ceramic clad plate, belongs to the inorganic materials field.
Background technology
Glass-ceramic clad plate is also claimed compound microlite, and compound microlite is to be the NEW TYPE OF COMPOSITE sheet material that the sytull of 1~5mm is compounded in the ceramics vitrified brick surface with thickness.Because its surface is a glass-ceramic layer, thus antifouling fully, maintenance convenient for cleaning; It has avoided the radiological hazard of lithotome in addition, belongs to "dead" product, is ornamental desirable green building material.Color and luster is natural, sparkling and crystal-clear penetrating, will never fade characteristics, has the decorative effect of nature jade, is the first-selection of present high-grade wall ground brick product.Blemish in an otherwise perfect thing be that the present glass-ceramic clad plate or the decorative effect of two dimensional surface is main, this makes the floral designs on the brick not have three-dimensional gradation sense.If can produce the glass-ceramic clad plate with stereoeffect then can fill up above blank, give product more high-grade decorative effect, obtain bigger profit margin.
Summary of the invention
For addressing the above problem; The present invention provides a kind of glass-ceramic clad plate; It comprises adobe layer, ground glaze layer, printed layer, glass-ceramic layer from bottom to top, and wherein adobe layer upper surface has concavo-convex pattern, and ground glaze layer, printed layer rise and fall with the concavo-convex pattern of adobe layer upper surface.
Above-mentioned glass-ceramic clad plate, the distance B between the reference plane of the high spot of wherein said concavo-convex pattern and recess and adobe layer upper surface is 0.2~1mm.
More preferably, above-mentioned glass-ceramic clad plate, the distance B between the reference plane of the high spot of wherein said concavo-convex pattern and recess and adobe layer upper surface is 0.2~0.5mm.
Above-mentioned glass-ceramic clad plate, wherein ground glaze layer thickness is 0.05~0.2mm.
Above-mentioned glass-ceramic clad plate, wherein printed layer thickness is 0.01~0.1mm.
Above-mentioned glass-ceramic clad plate, wherein the thickness of glass-ceramic layer is 1~3mm.
More preferably, above-mentioned glass-ceramic clad plate, wherein the thickness of glass-ceramic layer is 1.5~1.8mm.
Above-mentioned glass-ceramic clad plate wherein has the noctilucence of stochastic distribution regional in the glass-ceramic layer.
Above-mentioned noctilucence zone passage dispenses the frit particle that dispenses long-afterglow fluorescent material earlier before the glass ceramics frit or contain above-mentioned materials and forms in production technique.
The present invention also provides the production technique of making above-mentioned glass-ceramic clad plate, comprises the steps:
The punching press of step 1) charity powder forms adobe;
Step 2) forms ground glaze layer, form printed layer then;
Step 3) is burnt till for the first time;
Step 4) dispenses glass ceramics frit;
Step 5) is burnt till for the second time;
Step 6) edging, polishing;
Wherein the die cavity of the employed press tool of punching press formation adobe has concavo-convex pattern in the step 1), and between the reference plane of the high spot of concavo-convex pattern and recess and die cavity is 0.22~1.1mm apart from d.
The upper surface of adobe also has concavo-convex pattern in contrast like this.
Step 2) printed layer in forms through ink-jet printed mode.
Preferably, step 2) the ground glaze layer thickness described in is 0.05~0.2mm, and printed layer thickness is 0.01~0.1mm, and ground glaze layer and printed layer rise and fall with the concavo-convex pattern of adobe layer upper surface.
Preferably, burn till 1210~1230 ℃ of firing temperatures, firing period 90~180 minutes for the first time in the step 3);
In the aforesaid method, more preferably, burn till for the first time in the step 3), firing temperature is 1220 ℃, and firing period is 150 minutes.
In the aforesaid method; Can to cover the concavo-convex pattern in the adobe fully and can after fusion, form thickness with the formation glass-ceramic layer after burning be that 2~5mm flat surface is advisable to the glass ceramics frit consumption in the step 4), and the glass ceramics frit grain graininess is 14~60 orders.
Preferably, burn till 1000~1100 ℃ of firing temperatures, firing period 100~300 minutes for the second time in the step 5).
In the aforesaid method, more preferably, burn till for the second time in the step 5), firing temperature is 1050 ℃, and firing period is 180 minutes.
In the aforesaid method, polishing back sytull layer thickness is 1~3mm in the step 6).
Because the specific refractory power of glass-ceramic layer is 1.4~1.5, polishing back sytull layer thickness is 1.5~1.8mm more preferably, under this thickness, and the sense that more has levels of the floral designs of printed layer, stereoeffect is more true to nature.
Preferably, before step 4) dispenses glass ceramics frit, dispense the frit particle that contains long-afterglow fluorescent material along printed layer pattern master texture earlier.
The above-mentioned frit grain graininess that contains long-afterglow fluorescent material is 3~30 orders.
So externally environment is by in the dark process of bright commentaries on classics; Long-afterglow fluorescent material in the noctilucence zone discharges the photon energy that it absorbed; Send fluorescence; Fluorescence color is different because of the dopant ion in the long-afterglow fluorescent material, and fluorescence sends in the adobe with solid pattern, can present the magical wonder of natures such as nebula of bright twinkLing stars river, bright-colored change.Solution because of outside atmosphere by in the dark process of bright commentaries on classics, the color of glass-ceramic clad plate, the pattern unclear technical problem that also thickens gradually.
This programme has following advantage:
1, can make product have more aesthetic through the concavo-convex pattern of adobe upper surface and pattern, the color scheme of printed layer; Continuous, the nature of convex-concave surface texture transition simultaneously; Pattern effect can have Multiple Combination; But the design space is big, has abundant colors, gloss collocation decorative effect, and the light refraction of surperficial glass-ceramic layer makes product have more stereoscopic sensation.
2, the production technique of this product is on the basis of existing maturation process, to reform, the technology simple and stable, and quality percentage is high.
Description of drawings
The adobe cross sectional representation of accompanying drawing 1 for after the male and female mold punching press, forming;
Accompanying drawing 2 is an adobe layer cross sectional representation in the finished product, has wherein indicated reference plane and D;
Accompanying drawing 3 forms the cross sectional representation behind the ground glaze layer for adobe is surperficial;
Accompanying drawing 4 forms the cross sectional representation after ground glaze layer and the printed layer for adobe is surperficial;
Accompanying drawing 5 is the cross sectional representation of embodiment 1 or 2 products;
Accompanying drawing 6 is the cross sectional representation of the embodiment of the invention 3 said explained hereafter products.
Drawing reference numeral explanation: 101-adobe layer; 201-ground glaze layer; 301-printed layer; 401-glass-ceramic layer; The reference plane of 501-adobe layer upper surface; 601-noctilucence zone; Distance between the reference plane of the high spot of D-concavo-convex pattern and recess and adobe layer upper surface.
Embodiment
Technical scheme of the present invention with reference to accompanying drawing, and following specific embodiment is provided in order better to explain, through following description, those skilled in the art can well understand this programme, and easier its advantage of bringing.Need to prove that the accompanying drawing content only is the synoptic diagram of explanation technical scheme, is not to draw according to substantial proportion, wherein for some characteristic is described, can amplifies or dwindles local feature.Simultaneously in order to practice thrift the specification sheets length, the technology of mentioning in known to those skilled in the art or some backgrounds will be done some omissions.
Embodiment 1
(1) punching press forms adobe
In this step, select that conventional formulation gets final product in the ceramic production technology for use.Be the raw material of staple with conventional raw materials such as feldspar, quartz, clay, talcums promptly, after the spray-drying tower spraying drying is processed powder, the powder water ratio is 3~7% through ball milling, deironing, old homogenizing; Through instead beat the cloth system cloth (instead beat adobe upper surface when being punching press under distributing mode), send into the press punching press behind the cloth, the formation adobe.The die cavity of press tool has concavo-convex pattern, and between the reference plane of the high spot of concavo-convex pattern and recess and die cavity is 0.22~1.1mm (the mould coefficient of Production of Ceramics is about 1.1) apart from d.The upper surface that punching press forms the back adobe also has concavo-convex pattern in contrast, and the xsect of adobe is shown in accompanying drawing 1 or 2, and the composition of concavo-convex pattern is preferably tDesigners design and arranges in pairs or groups mutually with the floral designs of follow-up formation printed layer and be advisable.The dry kiln oven dry is gone in adobe after the punching press, makes the exsiccant ceramic adobe.
(2) execute ground-coat enamel, formation printed layer
Shown in accompanying drawing 3, through the adobe of step 1 exsiccant, the cleaning billet surface is through long conveying belt; Glaze formation ground glaze layer is drenched through bell jar in the surface above that, and ground-coat enamel is that well-known components gets final product, and selects the ground glaze layer of white in the present embodiment for use; Ground glaze layer thickness is 0.1mm, and certainly thickness can have certain floating, in force mainly through control single-piece base substrate consume ground-coat enamel quality come control thickness; In the present embodiment, adobe is 920 * 920mm, and the ground-coat enamel consumption is about 300 gram/sheets.Form printed layer then, the floral designs of printed layer are for arrange in pairs or groups with adobe upper surface concavo-convex pattern layer mutually, and printed layer is the formed trash ice crystal pattern of a spray ink Printing pattern in the present embodiment, concavo-convex pattern be with the trash ice crystalline substance in the corresponding pattern of lines.Ink-jet print system is the four look ceramic ink jet printing machines of hoping that ceramic machinery ltd produces, and ink is Spain Yi Dajia (esmaglassitaca) palm fibre that company produced, Huang, indigo plant, brown four chromatic inks.The printed layer thickness that spray ink Printing forms is 0.01~0.1mm.Shown in accompanying drawing 4, because of ground glaze layer and stamp very thin thickness, so its concavo-convex pattern with adobe layer upper surface rises and falls.
(3) burn till for the first time
Burn till the selection roller kiln, firing temperature is 1220 ℃ in the present embodiment, firing period 150 minutes.After burning till for the first time, the adobe porcelainization.
(4) dispense glass ceramics frit
Select transparent glass-ceramics frit commonly used in the industry in the present embodiment for use; The glass ceramics frit consumption can cover the concavo-convex pattern in the adobe fully and can after fusion, form thickness with the formation glass-ceramic layer after burning is that 2~5mm flat surface is advisable, and the median size of glass frit is 0.5~1.2mm.
(5) burn till for the second time
Burn till the selection roller kiln, firing temperature is 1050 ℃ in the present embodiment, firing period 180 minutes.Behind the twice firing, the sytull fusion forms glass-ceramic layer.
(6) edging, polishing
Goods to twice firing carry out edging, polishing, and it is regular to obtain size, and upper surface is that mirror polish effect, lower surface are the glass-ceramic clad plate product with 3D solid pattern.Polishing back sytull layer thickness is 1~3mm, is more preferably 1.5~1.8mm.
Embodiment 2
Present embodiment and embodiment 1 difference are:
1, the concavo-convex pattern that forms on the adobe surface in the step (1) is that having of similar natural rosin jade is radial, the needle crystal cleavage, and between the reference plane of the high spot of concavo-convex pattern and recess and die cavity is 0.55~1.1mm apart from d;
2, decalcomania is radial, the needle crystal cleavage pattern that has of the similar natural rosin jade corresponding with step 1 in the step (2), and color is main with brown coffee color;
3, the once-firing temperature is 1230 ℃ in the step (3), and firing period is 100 minutes;
4, the twice firing temperature is 1110 ℃ in the step (5), firing period 110 minutes.
Embodiment 3
Present embodiment and embodiment 1 difference are: dispense the frit particle that contains blue series long afterglow fluorescent material at random earlier before in step (4), dispensing glass ceramics frit, this makes the goods behind the twice firing have the cross-sectional structure like accompanying drawing 6.Wherein 601 contain the granuloplastic noctilucence of the frit of blue series long afterglow fluorescent material zone.
In the above-mentioned technology, the frit grain graininess that contains blue series long afterglow fluorescent material is 3~30 orders, and consumption is 20~50g/ sheet.
Goods external environment by the dark process of bright commentaries on classics in, the photon energy that long-afterglow fluorescent material discharge to absorb, the product surface subregion has nattier blue radiance, brings out the best in each other with the printed layer pattern, enhances each other's beauty, if the bright Milky Way has an array of stars indistinct.
Embodiment 4
Present embodiment and embodiment 2 differences are; Dispense in step (4) before the glass ceramics frit earlier that main lines radial along having of rosin jade, needle crystal cleavage pattern dispenses the frit particle that contains long-afterglow fluorescent material, it is orange red colour system that long-afterglow fluorescent material is selected twilight sunset.Goods external environment by the dark process of bright commentaries on classics in; Long-afterglow fluorescent material discharges the photon energy that absorbs; The product surface subregion has orange-red radiance; Simultaneously these twilight sunset mainly concentrate on the main texture place of the similar natural rosin jade of printed layer, and twilight sunset combines with patterned layer, make goods have the magical effect as the nebula of bright-colored change.
The colour system of certain above-mentioned long-afterglow fluorescent material can choose at random, and has the aesthetic feeling collocation with itself and printed layer color, pattern and is advisable.
In one embodiment of the invention, dispense slight earlier vibrations adobe behind the frit particle that contains long-afterglow fluorescent material, the frit major part falls into recess.
What should explain at last is; Above embodiment is only in order to describe technical scheme of the present invention rather than the present technique method is limited; The present invention can extend to other modification, variation, application and embodiment on using, and therefore thinks that all such modifications, variation, application, embodiment are in spirit of the present invention and teachings.

Claims (10)

1. the production technique of a glass-ceramic clad plate comprises the steps:
The punching press of step 1) charity powder forms adobe;
Step 2) forms ground glaze layer, form printed layer then;
Step 3) is burnt till for the first time;
Step 4) dispenses glass ceramics frit;
Step 5) is burnt till for the second time;
Step 6) edging, polishing;
It is characterized in that the die cavity of the employed press tool of punching press formation adobe has concavo-convex pattern in the step 1), between the reference plane of the high spot of concavo-convex pattern and recess and die cavity is 0.22~1.1mm apart from d.
2. like the production technique of claim 1 described glass-ceramic clad plate, it is characterized in that step 2) described in printed layer form through ink-jet printed mode.
3. like the production technique of claim 1 or 2 described glass-ceramic clad plates; It is characterized in that; Step 2) the ground glaze layer thickness described in is 0.05~0.2mm, and printed layer thickness is 0.01~0.1mm, and ground glaze layer and printed layer rise and fall with the concavo-convex pattern of adobe layer upper surface.
4. like the production technique of claim 1 or 2 described glass-ceramic clad plates, it is characterized in that, burn till 1210~1230 ℃ of firing temperatures, firing period 90~180 minutes for the first time in the step 3).
5. like the production technique of claim 4 described glass-ceramic clad plates, it is characterized in that burn till for the first time in the step 3), firing temperature is 1220 ℃, firing period is 150 minutes.
6. like the production technique of claim 1 or 2 described glass-ceramic clad plates, it is characterized in that, burn till 1000~1100 ℃ of firing temperatures, firing period 100~300 minutes for the second time in the step 5).
7. like the production technique of claim 6 described glass-ceramic clad plates, it is characterized in that burn till for the second time in the step 5), firing temperature is 1050 ℃, firing period is 180 minutes.
8. like the production technique of claim 1 described glass-ceramic clad plate, it is characterized in that polishing back sytull layer thickness is 1~3mm in the step 6).
9. like the production technique of claim 1 described glass-ceramic clad plate, it is characterized in that, before step 4) dispenses glass ceramics frit, dispense the frit particle that one deck contains long-afterglow fluorescent material along printed layer pattern master texture earlier.
10. like the production technique of claim 9 described glass-ceramic clad plates, it is characterized in that the said frit grain graininess that contains long-afterglow fluorescent material is 3~30 orders.
CN2012102858906A 2012-08-13 2012-08-13 Method for producing microcrystal glass ceramics composite board Pending CN102775074A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103030298A (en) * 2012-12-31 2013-04-10 佛山欧神诺陶瓷股份有限公司 Once-firing colored crystalline glass ceramic composite brick and production method
CN103835465A (en) * 2014-03-03 2014-06-04 范新晖 Long-afterglow fluorescent ceramic tile
CN103896633A (en) * 2014-03-03 2014-07-02 范新晖 Method for manufacturing long afterglow fluorescent ceramic tile
CN104230394A (en) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 Production process of microcrystalline glass ceramic composite board
CN104311159A (en) * 2014-09-23 2015-01-28 佛山市禾才科技服务有限公司 Microcrystallite glass ceramic composite plate production process
CN106631159A (en) * 2015-10-28 2017-05-10 佛山市东鹏陶瓷有限公司 Preparation method of glazed bricks
CN106631164A (en) * 2015-10-28 2017-05-10 佛山市东鹏陶瓷有限公司 Glass-ceramic tile preparation method
CN110668826A (en) * 2019-09-30 2020-01-10 江西中材新材料有限公司 Foamed ceramic with embossment effect and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101585210A (en) * 2008-05-21 2009-11-25 广东新明珠陶瓷集团有限公司 Equipment and method for producing imitation stone-texture ceramic tile
CN102557760A (en) * 2012-03-15 2012-07-11 广东高微晶科技有限公司 Marble-like glass ceramic composite board and production process thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585210A (en) * 2008-05-21 2009-11-25 广东新明珠陶瓷集团有限公司 Equipment and method for producing imitation stone-texture ceramic tile
CN102557760A (en) * 2012-03-15 2012-07-11 广东高微晶科技有限公司 Marble-like glass ceramic composite board and production process thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103030298A (en) * 2012-12-31 2013-04-10 佛山欧神诺陶瓷股份有限公司 Once-firing colored crystalline glass ceramic composite brick and production method
CN103030298B (en) * 2012-12-31 2015-07-15 佛山欧神诺陶瓷股份有限公司 Once-firing colored crystalline glass ceramic composite brick and production method
CN103835465A (en) * 2014-03-03 2014-06-04 范新晖 Long-afterglow fluorescent ceramic tile
CN103896633A (en) * 2014-03-03 2014-07-02 范新晖 Method for manufacturing long afterglow fluorescent ceramic tile
CN103896633B (en) * 2014-03-03 2015-08-12 范新晖 A kind of manufacture method of long-afterglow fluorescent ceramic tile
CN104230394A (en) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 Production process of microcrystalline glass ceramic composite board
CN104311159A (en) * 2014-09-23 2015-01-28 佛山市禾才科技服务有限公司 Microcrystallite glass ceramic composite plate production process
CN104230394B (en) * 2014-09-23 2016-03-23 佛山市禾才科技服务有限公司 A kind of glass-ceramic clad plate production technique
CN104311159B (en) * 2014-09-23 2016-08-24 佛山市禾才科技服务有限公司 A kind of glass-ceramic clad plate production technology
CN106631159A (en) * 2015-10-28 2017-05-10 佛山市东鹏陶瓷有限公司 Preparation method of glazed bricks
CN106631164A (en) * 2015-10-28 2017-05-10 佛山市东鹏陶瓷有限公司 Glass-ceramic tile preparation method
CN110668826A (en) * 2019-09-30 2020-01-10 江西中材新材料有限公司 Foamed ceramic with embossment effect and preparation method thereof

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