CN1962725B - 由含硼起始剂制备的双金属氰化物催化的低不饱和聚醚 - Google Patents

由含硼起始剂制备的双金属氰化物催化的低不饱和聚醚 Download PDF

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Publication number
CN1962725B
CN1962725B CN2006101464579A CN200610146457A CN1962725B CN 1962725 B CN1962725 B CN 1962725B CN 2006101464579 A CN2006101464579 A CN 2006101464579A CN 200610146457 A CN200610146457 A CN 200610146457A CN 1962725 B CN1962725 B CN 1962725B
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CN
China
Prior art keywords
acid
equivalent
boracic
boron
milli
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Expired - Fee Related
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CN2006101464579A
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English (en)
Chinese (zh)
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CN1962725A (zh
Inventor
J·F·帕索斯
K·G·麦克丹尼尔
E·P·布朗尼
G·G·库姆斯
D·S·沃蒂斯
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Covestro LLC
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Bayer MaterialScience LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2639—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing elements other than oxygen, nitrogen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
  • Sealing Material Composition (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN2006101464579A 2005-11-09 2006-11-08 由含硼起始剂制备的双金属氰化物催化的低不饱和聚醚 Expired - Fee Related CN1962725B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/270,100 US7323605B2 (en) 2005-11-09 2005-11-09 Double metal cyanide-catalyzed, low unsaturation polyethers from boron-containing starters
US11/270,100 2005-11-09

Publications (2)

Publication Number Publication Date
CN1962725A CN1962725A (zh) 2007-05-16
CN1962725B true CN1962725B (zh) 2012-05-30

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CN2006101464579A Expired - Fee Related CN1962725B (zh) 2005-11-09 2006-11-08 由含硼起始剂制备的双金属氰化物催化的低不饱和聚醚

Country Status (8)

Country Link
US (1) US7323605B2 (https=)
EP (1) EP1785445B1 (https=)
JP (1) JP5225571B2 (https=)
KR (1) KR101347412B1 (https=)
CN (1) CN1962725B (https=)
BR (1) BRPI0604542A (https=)
CA (1) CA2566836C (https=)
SG (1) SG132603A1 (https=)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007005960A1 (de) * 2007-02-07 2008-08-14 Bayer Materialscience Ag Ruß-gefüllte Polyurethane mit hoher Dielektrizitätskonstante und Durchschlagsfestigkeit
CN102369232B (zh) 2009-03-30 2013-08-14 三洋化成工业株式会社 聚氧化烯多元醇或聚氧化烯一元醇以及聚氨酯树脂
BR112016006429B1 (pt) 2013-09-27 2021-08-17 Dow Global Technologies Llc Processo para produzir polímeros poli(óxido de 1,2- butileno) e polímero poli(óxido de 1,2- butileno)
WO2015065769A1 (en) * 2013-10-30 2015-05-07 Dow Global Technologies Llc Syntactic polyurethane elastomers for use in subsea pipeline insulation
MX2016004745A (es) 2013-10-30 2016-07-26 Dow Global Technologies Llc Elastomero de poliuretano sintactico basado en prepolimero de segmento suave y catalizador sin mercurio para el uso en alislamiento de tuberia submarina.
CA2928691C (en) 2013-10-30 2021-11-02 Dow Global Technologies Llc Syntactic polyurethane elastomers having distinct morphology for use in subsea pipeline insulation
RU2675840C2 (ru) 2013-10-30 2018-12-25 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Синтактические полиуретановые эластомеры на основе полиолов с низкой степенью ненасыщенности для применения в изоляции подводных трубопроводов
JP6883264B2 (ja) * 2017-11-24 2021-06-09 日油株式会社 合成繊維平滑剤組成物
CN109970961B (zh) * 2017-12-22 2021-07-23 万华化学集团股份有限公司 一种端烯基封端不饱和聚醚的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US6077978A (en) * 1997-09-17 2000-06-20 Arco Chemical Technology L.P. Direct polyoxyalkylation of glycerine with double metal cyanide catalysis
CN1259151A (zh) * 1997-04-02 2000-07-05 阿科化学技术公司 具有低水亲合力的聚氧化烯单醚
EP1528073A1 (en) * 2003-11-03 2005-05-04 Bayer MaterialScience LLC Single reactor synthesis of polyols capped using basic catalysts and being based on intermediates synthesized using DMC-catalysts

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GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
GB1225803A (https=) 1967-06-02 1971-03-24
US3560539A (en) 1968-08-21 1971-02-02 Union Oil Co Selective catalyst recovery
US3829508A (en) 1969-07-14 1974-08-13 Hoechst Ag Halogenoalkyl-polyglycol ethers and process for preparing them
AU552988B2 (en) 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
JP3097854B2 (ja) 1989-05-12 2000-10-10 旭硝子株式会社 ポリウレタン類の製造方法
CA2020037A1 (en) * 1990-01-22 1991-07-23 Rodney L. Sung Polyoxyalkylene ester compounds and ori-inhibited motor fuel compositions
JPH05331278A (ja) * 1992-05-29 1993-12-14 Asahi Glass Co Ltd 高分子量ポリエーテル類の製造方法
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US6004482A (en) * 1997-12-24 1999-12-21 Bayer Corporation Stable aromatic amine composition, and a process for preparing color stable aromatic amines
US6063897A (en) * 1998-05-05 2000-05-16 Arco Chemical Technology, L.P. Acid-treated double metal cyanide complex catalysts
PT1177239E (pt) 1999-05-05 2005-03-31 Bayer Materialscience Ag Catalisadores de cianetos bimetalicos usados para a producao de polieteres-poliois
DE10001779A1 (de) * 2000-01-18 2001-07-19 Basf Ag Verfahren zur Herstellung von Polyetheralkoholen
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US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
CN1259151A (zh) * 1997-04-02 2000-07-05 阿科化学技术公司 具有低水亲合力的聚氧化烯单醚
US6077978A (en) * 1997-09-17 2000-06-20 Arco Chemical Technology L.P. Direct polyoxyalkylation of glycerine with double metal cyanide catalysis
EP1528073A1 (en) * 2003-11-03 2005-05-04 Bayer MaterialScience LLC Single reactor synthesis of polyols capped using basic catalysts and being based on intermediates synthesized using DMC-catalysts

Also Published As

Publication number Publication date
SG132603A1 (en) 2007-06-28
CN1962725A (zh) 2007-05-16
BRPI0604542A (pt) 2007-08-28
EP1785445B1 (en) 2013-10-16
JP5225571B2 (ja) 2013-07-03
KR20070049978A (ko) 2007-05-14
US7323605B2 (en) 2008-01-29
CA2566836C (en) 2014-04-08
US20070106097A1 (en) 2007-05-10
HK1100412A1 (en) 2007-09-21
EP1785445A1 (en) 2007-05-16
CA2566836A1 (en) 2007-05-09
KR101347412B1 (ko) 2014-01-02
JP2007131845A (ja) 2007-05-31

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