CN1925974A - 具有放射标记的容器 - Google Patents
具有放射标记的容器 Download PDFInfo
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Abstract
一种生产可识别容器的方法,该方法包括提供模制塑料容器(10),该容器包括至少一个混有添加剂的材料层。提供具有可识别标记形式的放射缝隙(32)的掩模(28),和引导辐射线通过掩模的缝隙并到达容器上以使该辐射线为添加剂所吸收,由此使添加剂以可识别标记(26)的形式显著响应。
Description
技术领域
本发明提供空心塑料容器,和更尤其提供一种具有作为可识别保密措施以防仿造容器使用的放射标记的空心塑料容器。
背景技术
在空心塑料容器的生产过程中,通常是注塑预型件,然后吹塑该预型件以获得容器的最终形状。该容器的主体部分可以是单层结构,或可以是多层结构,在多层结构中一或多个中间层形成阻挡层以防气体透过该容器。上述的多层吹塑容器经常用于医疗型产品如药剂。然而,药剂时常被仿造并被包装在看上去与市场销售的真药剂的真包装容器相同的仿造容器里。因此,使用上述仿造容器来欺骗药剂师和消费者去购买仿造的药剂。
发明内容
根据本发明的一方面,一种生产可识别容器的方法包括:提供具有壁的模制塑料容器,它包括至少一个与添加剂混合的材料层;提供具有可识别标记形式的放射缝隙的掩模;和引导放射线通过该掩模的放射缝隙并到达该容器上以使该放射线为添加剂所吸收,由此使该添加剂以可识别标记的形式产生明显的响应。容器壁可以具有单层结构,或多层结构,其中在这些层的至少一层中提供添加剂,优选在阻挡层中。
根据本发明的第二方面,提供一种包括塑料壁的容器,它具有至少一个与添加剂混合的材料层。该材料层具有通过吸收射线产生的可见部分,并且该部分是以可识别标记的形式存在。
附图说明
将由下列描述、所附的权利要求和附图最佳地理解本发明和附加的目的、特性、优点及其外观,其中:
图1说明了本发明一实施方案的容器的透视图、以及用于本发明方法的一实施方案的掩模和辐射源;
图1A说明了取自其圆圈1A的图1容器侧壁的放大剖视图;和
图1B说明了根据本发明一替换实施方案的容器侧壁的放大剖视图。
具体实施方式
大体上,图1说明了根据本发明一实施方案的容器10,以及用于实现本发明制造该制品的方法的举例性装置。除了本发明下面将要详细描写的发明特征之外,该容器基本上与公开在U.S.专利4,954,376中的容器相似。该容器还可以通过分别公开在U.S.专利4,710,118和4,609,516中的装置和方法来生产。因此,在此引入U.S.专利4,710,118、4,609,516和4,954,376的全部内容作为参考。
在具体参考图1中,容器10包括封闭的底端12、从所述封闭的底端12延伸出的侧壁14、和接在侧壁14端部上的并具有基本上与封闭底端12相对的开口端18的颈结束部分16。容器10可以通过任何已知的形成容器的方法来制造,如通过挤出吹塑,但是优选通过连续地吹制成型注模预型件来制造。
图1A描述了图1容器10的放大的断面部分。这里,能够看出侧壁14是多层的,优选用多层树脂制造,并且包括由基体树脂组成的内外层20、22和优选由阻隔树脂组成的中间层24。中间层24的优选厚度大约是侧壁14整个厚度的40%,而内外层20,22每个大约是侧壁14整个厚度的30%。可以提供另外的或替换的中间层,如一层再生树脂。可以预见,在不脱离本发明的范围下,多层的侧壁14可以由更多或更少的层组成。在任何情况下,在层20,22中的基体树脂优选由聚碳酸酯或聚乙烯聚合物组成,但它可以由任何其它所要求的容器材料组成。在层24中的阻隔树脂优选是尼龙或乙烯-乙烯醇(EVOH)聚合物,但它可以是用于容器的任何其它合适的阻隔材料。
图1B描述了根据本发明一替换实施方案的容器110的放大的断面部分。这里,容器110仅仅包括一个树脂材料层来限定侧壁114—即,它具有单层结构。侧壁114可以由任何所要求的树脂材料组成,如基体树脂、阻隔树脂或其混合物。
在容器10或110形成以前,例如在注塑用来吹制形成容器10或110的预型件之前或期间,将添加剂加入侧壁14或114的一个层中。添加剂可以混入图1B中的单层114,或混入图1A中的任何层中(优选阻隔层24)。使用添加剂作为独特的标识符使得容器10,110的仿造更加困难。优选,该添加剂尤其是在紫外光下可辨别的材料,如发荧光或发磷光的材料。上述材料的实例包括硅酸锶磷光体、硫化锌、硫化镉、钠荧光素、若丹明等等。然而,添加剂可以是易于在一个波长下吸收辐射以便以另一个波长发射辐射达连续的时间延续的任何材料。
再次参考图1,侧壁14(或图1B中的侧壁114)包括局部放射部分26,它可以是包括任何几何形状、标志、文字等等的任何合适的、所希望的标记。该放射部分26是通过掩盖并且辐射容器10来生产的。提供抗辐射的掩模28,它具有一个不透明的或固体部分30和一个透明部分或在其中形成的缝隙32。例如,掩模28可以是铅管,容器10插入其中并通过它的一个侧壁冲压、切削或其它的方式形成缝隙。提供辐射源34来引导辐射通过掩模28并到达容器10上,以便由容器10内的添加剂吸收放射线,由此使该添加剂以掩模30的缝隙32的轮廓或形状产生明显的响应。例如,如果添加剂是发荧光试剂,那么由发荧光试剂吸收放射线,由此与容器10的其余背景相对比使发荧光试剂以标记26的形式产生荧光或发光,由于掩盖了容器10的其余背景所以它不会发光。辐射源34可以是发射γ射线的γ辐射源。γ射线的吸收将使该标记产生微弱的发光达数周或数月。通过本发明可以预期任何形式的放射线和放时源,只要它们对在容器10的阻隔层内的添加剂产生明显的响应。
因此,添加剂和其以容器10上标记26的形式的辐射结合起来提供局部的或不连续的放射标志符,以便由此更独特地鉴别容器10。换句话说,由此本发明以在容器10的侧壁14中的一种“水印”形式提供了一种明显的安全特性。带有上述水印的本发明的“真”容器10可以更容易地区别于没有上述水印的非真容器。对伪造者来说仿制该水印容器是困难的并且该水印容器显示包装在其中的产品的真实性。因此,通过运用本发明,相对进一步保护了药剂师和消费者以防伪造药物闯入市场。
就此已经描述了一种制品和制造该制品的方法,它们完全满足先前阐述的所有目的和目标。目前本发明已经与其优选方案一起公开,并且已经论述了许多修改和变化。鉴于上述的说明,其它的修改和变化将容易地呈现在本领域技术人员的面前。例如,本发明已经与在容器的侧壁内的独特标识符一起公开。然而,在没有脱离公开的内容下,独特标识符可以在容器上的任何位置制造,如封闭的底端或结束部分。此外,本发明已经与容器一起公开;然而可以预期其它的设备如容器的盖板。术语容器在这里定义为包括容器预型件乃至容器的盖板。术语放射在这里广泛地定义为包括处理或使某物遭受到光或其它的辐射能以产生与周围部分相比相对更明显的标记部分的任何过程。此外,术语标记在这里广泛地定义为包括在一种或多种光的过程中提供明显标记的任何事物。当然,本发明意欲包括落入所附权利要求的精神和宽范围内的全部修改和变化。
Claims (13)
1.一种生产可识别容器的方法,它包括:
(a)提供模制塑料容器,它包括至少一个混有添加剂的材料层;
(b)提供具有可识别标记形式的放射缝隙的掩模;和
(c)引导放射线通过所述掩模的放射缝隙并到达所述容器上以使所述放射线为添加剂所吸收,由此使所述添加剂以可识别标记的形式产生明显的响应。
2.权利要求1所述的方法,其中所述放射线是γ射线,并且所述添加剂是紫外线的发荧光试剂,它应暴露于所述γ射线的响应发荧光。
3.权利要求1所述的方法,其中所述可识别标记包括标志。
4.权利要求1所述的方法,其中所述容器包括侧壁并且所述可识别标记是在所述侧壁中形成的。
5.一种由权利要求1所述方法生产的容器。
6.权利要求1所述的方法,其中所述至少一个材料层包括至少一个基体聚合物层和至少一个阻隔聚合物层。
7.权利要求6所述的方法,其中所述至少一个阻隔聚合物层包括所述添加剂。
8.一种容器,包括:
具有至少一个混有添加剂的材料层的塑料壁,
所述至少一层具有通过吸收射线产生的明显响应部分,
所述明显部分以可识别标记形式存在。
9.权利要求8所述的容器,其中所述添加剂是发荧光试剂,它应γ射线的响应发荧光。
10.权利要求8所述的容器,其中所述容器包括侧壁并且所述可识别标记是在所述侧壁中形成的。
11.权利要求8所述的容器,其中所述可识别标记包括标志。
12.权利要求8所述的容器,其中所述至少一个材料层包括至少一个体聚合物层和至少一个阻隔聚合物层。
13.权利要求12所述的容器,其中所述至少一个阻隔聚合物层包括所述添加剂。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/793,523 | 2004-03-03 | ||
US10/793,523 US7253422B2 (en) | 2004-03-03 | 2004-03-03 | Container having irradiated indicia |
Publications (1)
Publication Number | Publication Date |
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CN1925974A true CN1925974A (zh) | 2007-03-07 |
Family
ID=34912075
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA200580006597XA Pending CN1925974A (zh) | 2004-03-03 | 2005-03-02 | 具有放射标记的容器 |
Country Status (10)
Country | Link |
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US (1) | US7253422B2 (zh) |
EP (1) | EP1720694B1 (zh) |
JP (1) | JP2007535446A (zh) |
CN (1) | CN1925974A (zh) |
AT (1) | ATE534503T1 (zh) |
BR (1) | BRPI0508278A (zh) |
CA (1) | CA2557266A1 (zh) |
MX (1) | MXPA06009851A (zh) |
NO (1) | NO20064476L (zh) |
WO (1) | WO2005084907A2 (zh) |
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US20080258356A1 (en) * | 2007-04-19 | 2008-10-23 | Inbev S.A. | Integrally blow-moulded bag-in-container comprising an inner layer and an outer layer comprising energy absorbing additives, and preform for making it |
US20150266621A1 (en) | 2007-04-19 | 2015-09-24 | Anheuser-Busch Inbev S.A. | Integrally Blow-Moulded Bag-in-Container Having Interface Vents Opening to the Atmosphere at Location Adjacent to Bag's Mouth, Preform for Making It; and Processes for Producing the Preform and Bag-in-Container |
WO2011091013A1 (en) * | 2010-01-19 | 2011-07-28 | Becton, Dickinson And Company | Container assembly and system for detection thereof |
WO2011127282A2 (en) * | 2010-04-07 | 2011-10-13 | Sproxil, Inc | Systems and methods for verifying authenticity of a product |
DE202010009571U1 (de) * | 2010-06-26 | 2011-10-24 | Rehau Ag + Co. | Hohlkörper aus Polymermaterial |
KR102522879B1 (ko) | 2013-06-28 | 2023-04-18 | 다이니폰 인사츠 가부시키가이샤 | 블로우 성형 방법, 복합 프리폼, 복합 용기, 내측 라벨 부재 및 플라스틱제 부재 |
US11962876B2 (en) | 2014-01-31 | 2024-04-16 | Digimarc Corporation | Recycling methods and systems, and related plastic containers |
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US9367849B1 (en) | 2015-05-21 | 2016-06-14 | Owens-Brockway Glass Container Inc. | Packaging authentication |
GB201522872D0 (en) * | 2015-12-24 | 2016-02-10 | Now 2 Now Ltd | Labelling system, method and label |
MX2018012105A (es) * | 2016-04-06 | 2019-03-28 | Amcor Rigid Plastics Usa Llc | Preforma y recipiente de multicapas. |
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-
2004
- 2004-03-03 US US10/793,523 patent/US7253422B2/en not_active Expired - Fee Related
-
2005
- 2005-03-02 WO PCT/US2005/006516 patent/WO2005084907A2/en active Application Filing
- 2005-03-02 CA CA002557266A patent/CA2557266A1/en not_active Abandoned
- 2005-03-02 BR BRPI0508278-1A patent/BRPI0508278A/pt not_active IP Right Cessation
- 2005-03-02 JP JP2007501887A patent/JP2007535446A/ja not_active Ceased
- 2005-03-02 CN CNA200580006597XA patent/CN1925974A/zh active Pending
- 2005-03-02 MX MXPA06009851A patent/MXPA06009851A/es active IP Right Grant
- 2005-03-02 EP EP05732606A patent/EP1720694B1/en active Active
- 2005-03-02 AT AT05732606T patent/ATE534503T1/de active
-
2006
- 2006-10-03 NO NO20064476A patent/NO20064476L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CA2557266A1 (en) | 2005-09-15 |
NO20064476L (no) | 2006-10-03 |
EP1720694A2 (en) | 2006-11-15 |
JP2007535446A (ja) | 2007-12-06 |
US20050194280A1 (en) | 2005-09-08 |
WO2005084907A3 (en) | 2005-12-08 |
BRPI0508278A (pt) | 2007-08-07 |
ATE534503T1 (de) | 2011-12-15 |
EP1720694B1 (en) | 2011-11-23 |
MXPA06009851A (es) | 2007-04-16 |
WO2005084907A2 (en) | 2005-09-15 |
US7253422B2 (en) | 2007-08-07 |
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