CN1918191B - 聚合方法 - Google Patents

聚合方法 Download PDF

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Publication number
CN1918191B
CN1918191B CN2004800416755A CN200480041675A CN1918191B CN 1918191 B CN1918191 B CN 1918191B CN 2004800416755 A CN2004800416755 A CN 2004800416755A CN 200480041675 A CN200480041675 A CN 200480041675A CN 1918191 B CN1918191 B CN 1918191B
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CN
China
Prior art keywords
group
hydrogen
sir
alkyl
ethene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2004800416755A
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English (en)
Chinese (zh)
Other versions
CN1918191A (zh
Inventor
B·S·金伯利
G·拉康
S·马斯特罗伊安尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Commercial Services UK Ltd
Ineos Sales UK Ltd
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Innovene Europe Ltd
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Filing date
Publication date
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Publication of CN1918191A publication Critical patent/CN1918191A/zh
Application granted granted Critical
Publication of CN1918191B publication Critical patent/CN1918191B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
CN2004800416755A 2003-12-18 2004-12-08 聚合方法 Expired - Fee Related CN1918191B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0329348.7 2003-12-18
GBGB0329348.7A GB0329348D0 (en) 2003-12-18 2003-12-18 Polymerisation process
PCT/GB2004/005197 WO2005058978A1 (en) 2003-12-18 2004-12-08 Polymerisation process

Publications (2)

Publication Number Publication Date
CN1918191A CN1918191A (zh) 2007-02-21
CN1918191B true CN1918191B (zh) 2011-06-08

Family

ID=30471312

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2004800416755A Expired - Fee Related CN1918191B (zh) 2003-12-18 2004-12-08 聚合方法

Country Status (10)

Country Link
US (1) US7705095B2 (de)
EP (1) EP1694717B1 (de)
JP (1) JP2007515521A (de)
KR (1) KR20060118556A (de)
CN (1) CN1918191B (de)
AT (1) ATE498637T1 (de)
CA (1) CA2549078A1 (de)
DE (1) DE602004031456D1 (de)
GB (1) GB0329348D0 (de)
WO (1) WO2005058978A1 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0610667D0 (en) * 2006-05-30 2006-07-05 Nova Chem Int Sa Supported polymerization catalysts
BRPI1015130B1 (pt) 2009-07-28 2019-11-26 Univation Tech Llc processo de polimerização usando um catalisador de geometria limitada suportado
US20110065846A1 (en) * 2009-09-11 2011-03-17 Abel Grosjean Olefin polymerisation process
BR112013006169B1 (pt) * 2010-09-28 2020-02-11 Basell Polyolefine Gmbh Método para a alimentação de um composto antiestático a um reator de polimerização, pasta catalítica, seu uso e processo para a polimerização de olefinas
CA2749835C (en) 2011-08-23 2018-08-21 Nova Chemicals Corporation Feeding highly active phosphinimine catalysts to a gas phase reactor
ES2842573T3 (es) * 2012-07-13 2021-07-14 Univation Tech Llc Relación de índice de fluidez aumentada de polímeros mediante la alimentación de un catalizador soportado saturado con un agente líquido seleccionado
CN115246900B (zh) * 2021-04-28 2023-08-15 中国石油化工股份有限公司 一种聚合物的制备方法及聚合物

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
CN1192752A (zh) * 1995-07-06 1998-09-09 埃克森化学专利公司 生产预聚的、载体上的金属茂催化剂体系的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
AU682821B2 (en) * 1993-04-26 1997-10-23 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
KR100420432B1 (ko) * 1995-03-10 2004-07-23 다우 글로벌 테크놀로지스 인크. 지지된촉매및이를이용한중합방법
WO1996034020A1 (en) * 1995-04-28 1996-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5721184A (en) * 1995-11-17 1998-02-24 Hoechst Method for making supported catalyst systems and catalyst systems therefrom
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
EP1218423B1 (de) * 1999-10-02 2005-03-16 Borealis Technology Oy Geträgerter und modifizierter katalysator für die polymerisation von olefine
JP2002179723A (ja) * 2000-12-08 2002-06-26 Asahi Kasei Corp オレフィン重合用触媒及び該触媒を用いるオレフィンの重合方法
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
WO2003016362A1 (en) 2001-08-17 2003-02-27 Dow Global Technologies Inc. Ethylene polymerization process
GB0319738D0 (en) * 2003-08-22 2003-09-24 Bp Chem Int Ltd Supported polymerisation catalysts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
CN1192752A (zh) * 1995-07-06 1998-09-09 埃克森化学专利公司 生产预聚的、载体上的金属茂催化剂体系的方法

Also Published As

Publication number Publication date
KR20060118556A (ko) 2006-11-23
CA2549078A1 (en) 2005-06-30
CN1918191A (zh) 2007-02-21
WO2005058978A1 (en) 2005-06-30
GB0329348D0 (en) 2004-01-21
US20070066773A1 (en) 2007-03-22
US7705095B2 (en) 2010-04-27
JP2007515521A (ja) 2007-06-14
DE602004031456D1 (de) 2011-03-31
EP1694717B1 (de) 2011-02-16
ATE498637T1 (de) 2011-03-15
EP1694717A1 (de) 2006-08-30

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CF01 Termination of patent right due to non-payment of annual fee