CN1899682A - 一种耐硫脱氧剂及其制备与应用 - Google Patents
一种耐硫脱氧剂及其制备与应用 Download PDFInfo
- Publication number
- CN1899682A CN1899682A CN 200610019605 CN200610019605A CN1899682A CN 1899682 A CN1899682 A CN 1899682A CN 200610019605 CN200610019605 CN 200610019605 CN 200610019605 A CN200610019605 A CN 200610019605A CN 1899682 A CN1899682 A CN 1899682A
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- CN
- China
- Prior art keywords
- sulfur
- deoxidizing agent
- proof deoxidizing
- carrier
- proof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- 239000007789 gas Substances 0.000 claims abstract description 35
- 230000000694 effects Effects 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000002360 preparation method Methods 0.000 claims abstract description 20
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 18
- 239000011593 sulfur Substances 0.000 claims abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000007598 dipping method Methods 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 9
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- 230000003197 catalytic effect Effects 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- 238000002803 maceration Methods 0.000 claims description 20
- 239000000470 constituent Substances 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- 230000004913 activation Effects 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- 230000001105 regulatory effect Effects 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- 239000003245 coal Substances 0.000 claims description 9
- 239000003595 mist Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- 238000006424 Flood reaction Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- XOCUXOWLYLLJLV-UHFFFAOYSA-N [O].[S] Chemical group [O].[S] XOCUXOWLYLLJLV-UHFFFAOYSA-N 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- NVIVJPRCKQTWLY-UHFFFAOYSA-N cobalt nickel Chemical compound [Co][Ni][Co] NVIVJPRCKQTWLY-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 2
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 2
- 230000001147 anti-toxic effect Effects 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000008235 industrial water Substances 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 229910003158 γ-Al2O3 Inorganic materials 0.000 abstract 1
- 238000013019 agitation Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 125000001741 organic sulfur group Chemical group 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
Description
脱氧剂 | 温度,℃ | 空速,小时-1 | 入口氧含量,% | 出口氧含量,×10-6 |
R-1 | 250350 | 10002000 | 1.01.0 | 1.00.7 |
R-2 | 300400 | 10003000 | 1.01.0 | 1.20.8 |
R-3 | 200300400 | 100020003000 | 1.01.01.0 | 1.41.00.7 |
R-4 | 200300400 | 100020003000 | 1.01.01.0 | 2.51.10.5 |
R-5 | 200300400 | 100020003000 | 1.01.01.0 | 3.11.10.7 |
R-6 | 200300400 | 100020003000 | 1.01.01.0 | 1.70.80.4 |
R-7 | 200300400 | 100020003000 | 1.01.01.0 | 2.31.21.0 |
R-8 | 200300400 | 100020003000 | 1.01.01.0 | 2.41.10.9 |
时间,小时 | 温度,℃ | 空速,小时-1 | 入口氧含量,% | 出口氧含量,×10-6 |
103072108160208242284320364 | 400400400350350300300250250200 | 1000100010001000100010001000100010001000 | 0.90.90.80.90.80.80.70.90.50.9 | 1.61.10.81.31.62.32.93.13.84.5 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006100196050A CN100402140C (zh) | 2006-07-11 | 2006-07-11 | 一种耐硫脱氧剂及其制备与应用 |
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CNB2006100196050A CN100402140C (zh) | 2006-07-11 | 2006-07-11 | 一种耐硫脱氧剂及其制备与应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1899682A true CN1899682A (zh) | 2007-01-24 |
CN100402140C CN100402140C (zh) | 2008-07-16 |
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CNB2006100196050A Active CN100402140C (zh) | 2006-07-11 | 2006-07-11 | 一种耐硫脱氧剂及其制备与应用 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102423623A (zh) * | 2011-08-29 | 2012-04-25 | 华烁科技股份有限公司 | 一种多功能原料气净化剂及其制备和应用方法 |
CN104888798A (zh) * | 2015-06-10 | 2015-09-09 | 西南化工研究设计院有限公司 | 一种用于富co气耐硫脱氧的高活性催化剂及其制备方法 |
CN105886695A (zh) * | 2016-05-09 | 2016-08-24 | 上海宝钢气体有限公司 | 一种转炉煤气的脱氧方法和装置 |
CN111905837A (zh) * | 2020-07-30 | 2020-11-10 | 成都龙飞科技有限公司 | 一种耐硫脱氧催化剂及其制备方法 |
CN114602487A (zh) * | 2022-04-13 | 2022-06-10 | 湖北禾谷环保有限公司 | 一种耐硫脱氧催化剂及其制备方法和应用 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1031746C (zh) * | 1993-12-24 | 1996-05-08 | 华东理工大学 | 高效钼系脱氧剂及其制法与应用 |
CN1111082C (zh) * | 2001-01-09 | 2003-06-11 | 华东理工大学 | 一种氧化钼脱氧剂及其制备方法 |
CN1332753C (zh) * | 2005-06-20 | 2007-08-22 | 天津化工研究设计院 | 一种耐硫催化脱氧剂及其生产方法 |
-
2006
- 2006-07-11 CN CNB2006100196050A patent/CN100402140C/zh active Active
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102423623A (zh) * | 2011-08-29 | 2012-04-25 | 华烁科技股份有限公司 | 一种多功能原料气净化剂及其制备和应用方法 |
CN104888798A (zh) * | 2015-06-10 | 2015-09-09 | 西南化工研究设计院有限公司 | 一种用于富co气耐硫脱氧的高活性催化剂及其制备方法 |
CN105886695A (zh) * | 2016-05-09 | 2016-08-24 | 上海宝钢气体有限公司 | 一种转炉煤气的脱氧方法和装置 |
CN105886695B (zh) * | 2016-05-09 | 2017-08-29 | 上海宝钢气体有限公司 | 一种转炉煤气的脱氧方法 |
CN111905837A (zh) * | 2020-07-30 | 2020-11-10 | 成都龙飞科技有限公司 | 一种耐硫脱氧催化剂及其制备方法 |
CN114602487A (zh) * | 2022-04-13 | 2022-06-10 | 湖北禾谷环保有限公司 | 一种耐硫脱氧催化剂及其制备方法和应用 |
CN114602487B (zh) * | 2022-04-13 | 2022-11-15 | 湖北禾谷环保有限公司 | 一种耐硫脱氧催化剂及其制备方法和应用 |
Also Published As
Publication number | Publication date |
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CN100402140C (zh) | 2008-07-16 |
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GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: HUASHUO SCIENCE CO., LTD. Free format text: FORMER NAME: HUBEI INST. OF CHEMISTRY |
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Address after: No. 30 Guan Shan Road, Hongshan District, Hubei, Wuhan Patentee after: HAISO TECHNOLOGY Co.,Ltd. Address before: No. 30 Guan Shan Road, Hongshan District, Hubei, Wuhan Patentee before: Hubei Research Institute of Chemistry |
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EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Hunan Huanda environmental protection Co. Ltd. Assignor: HAISO TECHNOLOGY Co.,Ltd. Contract fulfillment period: 2009.9.1 to 2019.9.1 Contract record no.: 2009430000206 Denomination of invention: Sulfur-proof deoxidizing agent and its preparing and use Granted publication date: 20080716 License type: Exclusive license Record date: 20091125 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.9.1 TO 2019.9.1; CHANGE OF CONTRACT Name of requester: HUNAN PROVINCE HUANDA ENVIRONMENTAL PROTECTION CO. Effective date: 20091125 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Sulfur Resistant Deoxidizer and Its Preparation and Application Effective date of registration: 20231024 Granted publication date: 20080716 Pledgee: Hubei Science and Technology Financing Guarantee Co.,Ltd. Pledgor: HAISO TECHNOLOGY Co.,Ltd. Registration number: Y2023980062125 |