CN1867614B - 磷酸接枝的杂化无机-有机质子电解质膜(PEMs) - Google Patents
磷酸接枝的杂化无机-有机质子电解质膜(PEMs) Download PDFInfo
- Publication number
- CN1867614B CN1867614B CN2004800302646A CN200480030264A CN1867614B CN 1867614 B CN1867614 B CN 1867614B CN 2004800302646 A CN2004800302646 A CN 2004800302646A CN 200480030264 A CN200480030264 A CN 200480030264A CN 1867614 B CN1867614 B CN 1867614B
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- China
- Prior art keywords
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- organic
- silicon
- multipolymer
- precursor
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/30—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen phosphorus-containing groups
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1037—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having silicon, e.g. sulfonated crosslinked polydimethylsiloxanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicon Polymers (AREA)
- Conductive Materials (AREA)
- Fuel Cell (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50217803P | 2003-09-11 | 2003-09-11 | |
| US60/502,178 | 2003-09-11 | ||
| US51183603P | 2003-10-16 | 2003-10-16 | |
| US60/511,836 | 2003-10-16 | ||
| US10/938,268 | 2004-09-10 | ||
| US10/938,268 US7183370B2 (en) | 2003-09-11 | 2004-09-10 | Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs) |
| PCT/US2004/029741 WO2005027240A2 (en) | 2003-09-11 | 2004-09-13 | PHOSPHONIC-ACID GRAFTED HYBRID INORGANIC-ORGANIC PROTON ELECTROLYTE MEMBRANES (PEMs) |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1867614A CN1867614A (zh) | 2006-11-22 |
| CN1867614B true CN1867614B (zh) | 2010-09-08 |
Family
ID=34317477
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2004800302646A Expired - Fee Related CN1867614B (zh) | 2003-09-11 | 2004-09-13 | 磷酸接枝的杂化无机-有机质子电解质膜(PEMs) |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7183370B2 (enExample) |
| EP (1) | EP1673404A4 (enExample) |
| JP (3) | JP5475941B2 (enExample) |
| CN (1) | CN1867614B (enExample) |
| WO (1) | WO2005027240A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI740542B (zh) * | 2020-06-16 | 2021-09-21 | 元智大學 | 耐高溫質子交換膜、膜電極組、燃料電池、及發電裝置 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7601759B2 (en) * | 2003-10-10 | 2009-10-13 | Bdf Ip Holdings Ltd. | Water insoluble additive for improving conductivity of an ion exchange membrane |
| DE10347569A1 (de) * | 2003-10-14 | 2005-06-02 | Degussa Ag | Keramische, flexible Membran mit verbesserter Haftung der Keramik auf dem Trägervlies |
| US7576165B2 (en) | 2004-01-27 | 2009-08-18 | Georgia Institute Of Technology | Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes |
| US7811693B2 (en) * | 2004-05-13 | 2010-10-12 | Toyota Motor Engineering & Manfacturing North America, Inc. | Proton exchange membranes (PEM) based on hybrid inorganic-organic copolymers with grafted phosphoric acid groups and implanted metal cations |
| US7531588B2 (en) * | 2004-07-30 | 2009-05-12 | Momentive Performance Materials Inc. | Silane compositions, processes for their preparation and rubber compositions containing same |
| US7459487B2 (en) * | 2005-02-16 | 2008-12-02 | The University Of Hong Kong | Polymer composite membrane and method of making the same |
| EA200702450A1 (ru) * | 2005-05-09 | 2008-04-28 | Майкробиа, Инк. | Металлоорганические бензолфосфонатные связующие вещества |
| JP2007123833A (ja) * | 2005-09-30 | 2007-05-17 | National Institute Of Advanced Industrial & Technology | 固体酸塩の活性化方法及びこれを用いた大容量キャパシター並びに燃料電池 |
| CN101336265B (zh) * | 2005-12-22 | 2012-11-07 | Bdfip控股有限公司 | 改进离子交换膜的传导率的水不溶性添加剂 |
| FR2896803B1 (fr) | 2006-02-01 | 2010-12-10 | Commissariat Energie Atomique | Nouveaux composes silanes et leur utilisation pour fonctionnaliser des supports solides et immobiliser sur ces supports des molicules biologiques |
| US20090048395A1 (en) * | 2006-02-17 | 2009-02-19 | Basf Se | Oligomeric and polymeric siloxanes substituted by arylphosphonic acids |
| JP4730540B2 (ja) * | 2006-03-03 | 2011-07-20 | 信越化学工業株式会社 | 燃料電池電解質膜用樹脂組成物並びに電解質膜 |
| DE102006053156A1 (de) * | 2006-11-10 | 2008-05-15 | Wacker Chemie Ag | Zusammensetzungen enthaltend Phosphonat-funktionelle Partikel |
| FR2908558B1 (fr) * | 2006-11-13 | 2008-12-19 | Commissariat Energie Atomique | Materiau d'electrolyte silicie pour pile a combustible, procede pour sa realisation et pile a combustible mettant en oeuvre un tel materiau. |
| US7790803B2 (en) * | 2008-06-02 | 2010-09-07 | Uop Llc | Crosslinked organic-inorganic hybrid membranes and their use in gas separation |
| US7947410B2 (en) * | 2008-08-22 | 2011-05-24 | Toyota Motor Engineering & Manufacturing North America, Inc. | Fuel cell electrodes with triazole modified polymers and membrane electrode assemblies incorporating same |
| DE112010004591T5 (de) * | 2009-11-29 | 2013-01-24 | National University Corporation Toyohashi University Of Technology | Elektrolytmembran, Brennstoffzelle und Elektrolytmembran-Herstellungsverfahren |
| CN102299353B (zh) * | 2010-06-25 | 2013-10-23 | 大连融科储能技术发展有限公司 | 有机无机复合膜在酸性电解液液流储能电池中的应用 |
| WO2012116782A1 (en) | 2011-03-03 | 2012-09-07 | Daimler Ag | Proton conducting electrolytes with cross-linked copolymer additives for use in fuel cells |
| CN103408760B (zh) * | 2013-08-16 | 2015-09-30 | 武汉理工大学 | 一种中温质子交换膜材料及其制备方法及使用该材料制备的燃料电池 |
| CN103531831B (zh) * | 2013-08-16 | 2015-09-30 | 武汉理工大学 | 一种酸碱型氨基多膦酸聚硅氧烷中温质子交换膜材料及其制备方法 |
| DE102013216787A1 (de) | 2013-08-23 | 2015-02-26 | Evonik Degussa Gmbh | Guanidingruppen aufweisende semi-organische Siliciumgruppen enthaltende Verbindungen |
| CN104086591B (zh) * | 2014-07-15 | 2016-05-11 | 武汉理工大学 | 基于格氏反应的苯基膦酸三甲氧基硅烷的制备方法 |
| JP6337670B2 (ja) * | 2014-07-24 | 2018-06-06 | トヨタ自動車株式会社 | 燃料電池用電極 |
| CN109524699B (zh) * | 2016-12-07 | 2022-10-25 | 新研氢能源科技有限公司 | 具有高电导率的交联型高温质子交换膜及其制备方法 |
| US11827807B2 (en) | 2019-09-18 | 2023-11-28 | Novelis Inc. | Metal surface coatings for improving bond performance and methods of making the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1349269A (zh) * | 2001-11-19 | 2002-05-15 | 华南理工大学 | 燃料电池用有机硅/稀土金属盐/无机多元酸(盐)的质子交换膜 |
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| US2843615A (en) * | 1956-05-31 | 1958-07-15 | Gen Electric | Organophosphorus-silicon compositions |
| US3122581A (en) * | 1961-10-27 | 1964-02-25 | Union Carbide Corp | Preparation of phosphorus-containing organosilicon compounds |
| US3408420A (en) * | 1964-04-30 | 1968-10-29 | Du Pont | Silane-modified olefinic copolymers |
| GB8418591D0 (en) * | 1984-07-20 | 1984-08-22 | Bp Chem Int Ltd | Polymer composition |
| FR2601017B1 (fr) * | 1986-07-02 | 1988-09-23 | Centre Nat Rech Scient | Nouvelles compositions a base de derives de silice modifiee par des groupements organiques, leur preparation et leur application, notamment comme conducteurs protoniques |
| US4965334A (en) * | 1986-08-06 | 1990-10-23 | First Brands Corporation | Copolymers of polysilyl compounds and anti-gelling agents |
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| DE19632285A1 (de) | 1996-08-09 | 1998-02-19 | Hoechst Ag | Protonenleiter mit einer Temperaturbeständigkeit in einem weiten Bereich und guten Protonenleitfähigkeiten |
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| EP1230278B1 (en) | 1999-11-08 | 2005-06-01 | E.I. Du Pont De Nemours And Company | Moisture curable, melt processible graft ethylene copolymers |
| US6423784B1 (en) | 1999-12-15 | 2002-07-23 | 3M Innovative Properties Company | Acid functional fluoropolymer membranes and method of manufacture |
| JP2001199961A (ja) | 2000-01-21 | 2001-07-24 | Fuji Photo Film Co Ltd | 重合性溶融塩モノマー、電解質組成物および電気化学電池 |
| DE10017654A1 (de) | 2000-04-08 | 2001-10-18 | Degussa | Organosiliciumverbindungen |
| DE10021106A1 (de) | 2000-05-02 | 2001-11-08 | Univ Stuttgart | Polymere Membranen |
| DE10021104A1 (de) | 2000-05-02 | 2001-11-08 | Univ Stuttgart | Organisch-anorganische Membranen |
| US20020127474A1 (en) | 2001-01-09 | 2002-09-12 | E.C.R.-Electro-Chemical Research Ltd. | Proton-selective conducting membranes |
| WO2002088222A1 (de) | 2001-03-13 | 2002-11-07 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. | Phosphorhaltige, organisch polymerisierbare silane und damit hergestellte kieselsäure-polykondensate |
| US6713643B2 (en) | 2001-05-24 | 2004-03-30 | Board Of Trustees Of Michigan State University | Ultrastable organofunctional microporous to mesoporous silica compositions |
| US6756436B2 (en) | 2001-06-26 | 2004-06-29 | Acushnet Company | Golf balls comprising highly-neutralized acid polymers |
| KR100526085B1 (ko) * | 2001-10-30 | 2005-11-08 | 세키스이가가쿠 고교가부시키가이샤 | 양성자 전도성 막, 그의 제조 방법 및 그것을 이용한 연료전지 |
| DE10163518A1 (de) | 2001-12-21 | 2003-07-10 | Fraunhofer Ges Forschung | Protonenleitfähige Membranen/Schichten und Verfahren zu deren Herstellung |
| US6716908B2 (en) | 2002-01-30 | 2004-04-06 | Dow Corning Corporation | Alkoxysilyl functional silicone based materials |
| EP1474839B1 (en) | 2002-02-06 | 2010-04-07 | Battelle Memorial Institute | Polymer electrolyte membranes for use in fuel cells |
| WO2004005380A1 (en) | 2002-07-04 | 2004-01-15 | Ben-Gurion University Of The Negev | Highly conductive ordered ion exchange membranes |
| JP3884340B2 (ja) | 2002-07-10 | 2007-02-21 | 本田技研工業株式会社 | プロトン伝導性高分子固体電解質 |
-
2004
- 2004-09-10 US US10/938,268 patent/US7183370B2/en not_active Expired - Fee Related
- 2004-09-13 CN CN2004800302646A patent/CN1867614B/zh not_active Expired - Fee Related
- 2004-09-13 EP EP04783815A patent/EP1673404A4/en not_active Withdrawn
- 2004-09-13 WO PCT/US2004/029741 patent/WO2005027240A2/en not_active Ceased
- 2004-09-13 JP JP2006526352A patent/JP5475941B2/ja not_active Expired - Fee Related
-
2011
- 2011-12-27 JP JP2011285879A patent/JP2012107245A/ja active Pending
-
2013
- 2013-02-12 JP JP2013024604A patent/JP2013216861A/ja not_active Abandoned
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1349269A (zh) * | 2001-11-19 | 2002-05-15 | 华南理工大学 | 燃料电池用有机硅/稀土金属盐/无机多元酸(盐)的质子交换膜 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI740542B (zh) * | 2020-06-16 | 2021-09-21 | 元智大學 | 耐高溫質子交換膜、膜電極組、燃料電池、及發電裝置 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1867614A (zh) | 2006-11-22 |
| EP1673404A4 (en) | 2012-02-08 |
| EP1673404A2 (en) | 2006-06-28 |
| JP2013216861A (ja) | 2013-10-24 |
| JP2007514007A (ja) | 2007-05-31 |
| US20050113547A1 (en) | 2005-05-26 |
| JP5475941B2 (ja) | 2014-04-16 |
| JP2012107245A (ja) | 2012-06-07 |
| WO2005027240A2 (en) | 2005-03-24 |
| WO2005027240A3 (en) | 2006-03-09 |
| US7183370B2 (en) | 2007-02-27 |
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