CN1781962A - 一种合成革用聚氨酯树脂的生产方法 - Google Patents
一种合成革用聚氨酯树脂的生产方法 Download PDFInfo
- Publication number
- CN1781962A CN1781962A CN 200410011296 CN200410011296A CN1781962A CN 1781962 A CN1781962 A CN 1781962A CN 200410011296 CN200410011296 CN 200410011296 CN 200410011296 A CN200410011296 A CN 200410011296A CN 1781962 A CN1781962 A CN 1781962A
- Authority
- CN
- China
- Prior art keywords
- synthetic leather
- siloxane
- polyurethane resin
- organo
- reaction solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002649 leather substitute Substances 0.000 title claims abstract description 41
- 229920005749 polyurethane resin Polymers 0.000 title claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 21
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 11
- 239000007810 chemical reaction solvent Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 21
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 20
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 20
- 125000005375 organosiloxane group Chemical group 0.000 claims description 15
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 8
- 239000004970 Chain extender Substances 0.000 claims description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 6
- 241000790917 Dioxys <bee> Species 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- -1 adipate glycol diglycolate acetal Chemical class 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 5
- 239000002202 Polyethylene glycol Substances 0.000 abstract description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 3
- 229920000728 polyester Polymers 0.000 abstract description 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract description 3
- 239000002002 slurry Substances 0.000 abstract description 3
- 239000012948 isocyanate Substances 0.000 abstract description 2
- 150000002513 isocyanates Chemical class 0.000 abstract description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 238000012805 post-processing Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 8
- 230000002209 hydrophobic effect Effects 0.000 description 7
- 239000010985 leather Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000003993 interaction Effects 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920001558 organosilicon polymer Polymers 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 description 1
- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100112963A CN1318470C (zh) | 2004-12-03 | 2004-12-03 | 一种合成革用聚氨酯树脂的生产方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100112963A CN1318470C (zh) | 2004-12-03 | 2004-12-03 | 一种合成革用聚氨酯树脂的生产方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1781962A true CN1781962A (zh) | 2006-06-07 |
CN1318470C CN1318470C (zh) | 2007-05-30 |
Family
ID=36772616
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100112963A Expired - Fee Related CN1318470C (zh) | 2004-12-03 | 2004-12-03 | 一种合成革用聚氨酯树脂的生产方法 |
Country Status (1)
Country | Link |
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CN (1) | CN1318470C (zh) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101092537B (zh) * | 2006-06-23 | 2010-07-07 | 宜兴市新光化工有限公司 | 芳香族防水透湿合成革涂饰树脂及其半预聚制造方法 |
CN101381448B (zh) * | 2008-10-14 | 2010-07-21 | 旭川化学(苏州)有限公司 | 一种防水透气服装革用聚氨酯树脂 |
CN101338016B (zh) * | 2007-07-04 | 2010-12-08 | 上海华峰超纤材料股份有限公司 | 超细纤维合成革用高回弹湿法聚氨酯树脂 |
CN101628963B (zh) * | 2009-08-17 | 2011-04-13 | 旭川化学(苏州)有限公司 | 用于制作聚酯型聚氨酯仿木材料的双组份 |
CN101186798B (zh) * | 2007-11-08 | 2012-03-28 | 江阴市诺科科技有限公司 | 汽车、鞋用水性聚氨酯硅氧烷透气涂层胶的制备方法 |
CN102618204A (zh) * | 2012-04-01 | 2012-08-01 | 江阴市诺科科技有限公司 | 一种人造革粘接层用热熔粘合剂及其制备方法、应用 |
CN102617826A (zh) * | 2012-03-26 | 2012-08-01 | 合肥安利聚氨酯新材料有限公司 | 一种软质不粘连湿式聚氨酯树脂及其制备方法 |
CN101608108B (zh) * | 2009-07-16 | 2012-08-15 | 天津锐欧威化工有限公司 | 轨道浇注材料底胶及制备方法 |
CN103304769A (zh) * | 2013-06-06 | 2013-09-18 | 广东伊诗德新材料科技有限公司 | 合成革用高耐磨耗聚氨酯树脂及其制备方法 |
CN104693403A (zh) * | 2015-03-17 | 2015-06-10 | 浙江深蓝轻纺科技有限公司 | 一种合成革用彩色聚氨酯树脂及其制备方法 |
CN108359072A (zh) * | 2018-03-16 | 2018-08-03 | 上海汇得科技股份有限公司 | 一种高耐湿热老化聚酯型沙发革用聚氨酯粘结层树脂及其制备方法 |
CN112280450A (zh) * | 2020-10-26 | 2021-01-29 | 佛山市高明明海化学企业有限公司 | 一种pvc人造革水性改色处理剂及其制备方法 |
CN113564938A (zh) * | 2021-07-26 | 2021-10-29 | 温州市巨特鞋业有限公司 | 透气防霉聚氨酯皮革及其制备方法和应用 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0856018B1 (en) * | 1995-10-19 | 2001-10-31 | Huntsman International Llc | Rigid polyurethane foams |
US5721284A (en) * | 1996-12-20 | 1998-02-24 | The Dow Chemical Company | Open-celled rigid polyurethane foam |
US6235804B1 (en) * | 1999-12-23 | 2001-05-22 | Air Products And Chemicals, Inc. | Silicone surfactants for making polyurethane flexible molded foams |
CN1513901A (zh) * | 2003-07-31 | 2004-07-21 | 拜耳(中国)有限公司 | 硬质聚氨酯泡沫用组合多元醇的添加剂配方 |
-
2004
- 2004-12-03 CN CNB2004100112963A patent/CN1318470C/zh not_active Expired - Fee Related
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101092537B (zh) * | 2006-06-23 | 2010-07-07 | 宜兴市新光化工有限公司 | 芳香族防水透湿合成革涂饰树脂及其半预聚制造方法 |
CN101338016B (zh) * | 2007-07-04 | 2010-12-08 | 上海华峰超纤材料股份有限公司 | 超细纤维合成革用高回弹湿法聚氨酯树脂 |
CN101186798B (zh) * | 2007-11-08 | 2012-03-28 | 江阴市诺科科技有限公司 | 汽车、鞋用水性聚氨酯硅氧烷透气涂层胶的制备方法 |
CN101381448B (zh) * | 2008-10-14 | 2010-07-21 | 旭川化学(苏州)有限公司 | 一种防水透气服装革用聚氨酯树脂 |
CN101608108B (zh) * | 2009-07-16 | 2012-08-15 | 天津锐欧威化工有限公司 | 轨道浇注材料底胶及制备方法 |
CN101628963B (zh) * | 2009-08-17 | 2011-04-13 | 旭川化学(苏州)有限公司 | 用于制作聚酯型聚氨酯仿木材料的双组份 |
CN102617826A (zh) * | 2012-03-26 | 2012-08-01 | 合肥安利聚氨酯新材料有限公司 | 一种软质不粘连湿式聚氨酯树脂及其制备方法 |
CN102618204B (zh) * | 2012-04-01 | 2013-11-27 | 江阴市诺科科技有限公司 | 一种人造革粘接层用热熔粘合剂及其制备方法、应用 |
CN102618204A (zh) * | 2012-04-01 | 2012-08-01 | 江阴市诺科科技有限公司 | 一种人造革粘接层用热熔粘合剂及其制备方法、应用 |
CN103304769A (zh) * | 2013-06-06 | 2013-09-18 | 广东伊诗德新材料科技有限公司 | 合成革用高耐磨耗聚氨酯树脂及其制备方法 |
CN104693403A (zh) * | 2015-03-17 | 2015-06-10 | 浙江深蓝轻纺科技有限公司 | 一种合成革用彩色聚氨酯树脂及其制备方法 |
CN104693403B (zh) * | 2015-03-17 | 2019-05-10 | 浙江深蓝新材料科技有限公司 | 一种合成革用彩色聚氨酯树脂及其制备方法 |
CN108359072A (zh) * | 2018-03-16 | 2018-08-03 | 上海汇得科技股份有限公司 | 一种高耐湿热老化聚酯型沙发革用聚氨酯粘结层树脂及其制备方法 |
CN108359072B (zh) * | 2018-03-16 | 2020-12-08 | 上海汇得科技股份有限公司 | 一种高耐湿热老化聚酯型沙发革用聚氨酯粘结层树脂及其制备方法 |
CN112280450A (zh) * | 2020-10-26 | 2021-01-29 | 佛山市高明明海化学企业有限公司 | 一种pvc人造革水性改色处理剂及其制备方法 |
CN113564938A (zh) * | 2021-07-26 | 2021-10-29 | 温州市巨特鞋业有限公司 | 透气防霉聚氨酯皮革及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN1318470C (zh) | 2007-05-30 |
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Owner name: WENZHOU UNIVERSITY Free format text: FORMER OWNER: ZHAO YAJUAN Effective date: 20070119 |
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Effective date of registration: 20070119 Address after: 325027 Wenzhou University, Wenzhou, Zhejiang, Xueyuan Road Applicant after: Wenzhou University Address before: 325027 School of chemistry and materials science, Wenzhou Normal College, Wenzhou, Zhejiang, Xueyuan Road Applicant before: Zhao Yajuan |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Zhejiang Huafeng Synthetic Resin Co., Ltd. Assignor: Wenzhou University Contract fulfillment period: 2008.5.20 to 2014.5.19 contract change Contract record no.: 2008330002801 Denomination of invention: Method for producing polyurethane resin for synthetic leather Granted publication date: 20070530 License type: Exclusive license Record date: 20081225 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.5.20 TO 2014.5.19; CHANGE OF CONTRACT Name of requester: ZHEJIANG PROVINCE HUAFENG SYNTHETIC RESIN CO., LTD Effective date: 20081225 |