CN1775027A - Disinsection soluble granules containing methylamino avermection benzoate - Google Patents
Disinsection soluble granules containing methylamino avermection benzoate Download PDFInfo
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- CN1775027A CN1775027A CN 200510012997 CN200510012997A CN1775027A CN 1775027 A CN1775027 A CN 1775027A CN 200510012997 CN200510012997 CN 200510012997 CN 200510012997 A CN200510012997 A CN 200510012997A CN 1775027 A CN1775027 A CN 1775027A
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- benzoate
- emamectin
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Abstract
The present invention discloses an insecticidal soluble granule preparation containing emamectin benzoate. Its composition includes (by wt%) emamectin benzoate 0.5-40%, dispersing agent 1-10%, wetting agent 1-5%, binder 2-4%, stabilizing agent 1-3% and the rest is filling material. It can be extensively used for controlling injurious insects of crops.
Description
Technical field
The present invention relates to a kind of disinsection soluble granules that contains emamectin-benzoate, particularly a kind of pesticide for protecting plant that contains the disinsection soluble granules of emamectin-benzoate.
Background technology
The insecticide that protective plant is used generally adopts cream preparation and wetting powder.Missible oil contain be easy in a large number volatilization catch fire, to human body and the virulent organic solvent of plant, transportation is also inconvenient; Wetting powder has a large amount of dust in producing, using, contaminated environment influences operating personnel's health.
Summary of the invention
The present invention overcomes shortcoming of the prior art, provides a kind of have safety, environmental protection, the disinsection soluble granules that contains emamectin-benzoate that result of use is good.
In order to solve the problem of above-mentioned technology, the present invention is achieved by the following technical solutions: the disinsection soluble granules that contains emamectin-benzoate, form soluble granule by emamectin-benzoate, dispersant, wetting agent, binding agent, stabilizing agent, filler, it forms content (is 100% in soluble granule weight): emamectin-benzoate 0.5-40%, dispersant 2～10%, wetting agent 1～5%, binding agent 2～4%, stabilizing agent 1～3%, all the other are fillers.
The present invention also can be achieved through the following technical solutions: the disinsection soluble granules that contains emamectin-benzoate, wherein dispersant is selected from sodium lignin sulfonate, wherein wetting agent is selected from OP-10, OP-21, lauryl sodium sulfate, GFC, wherein binding agent is selected from dextrin, polyethylene glycol, gelatin, wherein stabilizing agent is selected from BHT, tributyl phosphate, sodium hydrogen phosphate, and wherein filler is selected from maltose, glucose, solvable starch, Lactis Anhydrous, anhydrous sodium sulfate.
Compared with prior art, the invention has the beneficial effects as follows: have safety, environmental protection, result of use is good.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1: the emamectin-benzoate with 1%, 3% sodium lignin sulfonate dispersant, 2% OP-10 wetting agent, 1% BHT stabilizing agent and 91% maltose filler mixes and through comminution by gas stream, adding 2% dextrin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; The product of not crossing sieve is mediated and extruder grain again through pulverizing, and vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 2: the emamectin-benzoate with 2%, 5% sodium lignin sulfonate dispersant, 2% OP-21 wetting agent, 1% tributyl phosphate stabilizing agent and 88% glucose filler mixes and through comminution by gas stream, adding 2% dextrin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; The product of not crossing sieve is mediated and extruder grain again through comminution by gas stream, and vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 3: the emamectin-benzoate with 5%, 7% sodium lignin sulfonate dispersant, 3% lauryl sodium sulfate wetting agent, 1% tributyl phosphate stabilizing agent and 82% solvable starch filler mixes and through comminution by gas stream, adding 2% polyethylene glycol binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; The product of not crossing sieve is mediated and extruder grain again through comminution by gas stream, and vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 4: the emamectin-benzoate with 10%, 8% sodium lignin sulfonate dispersant, 2% JFC wetting agent, 1% sodium hydrogen phosphate stabilizing agent and 77% Lactis Anhydrous filler mixes and through comminution by gas stream, adding 2% gelatin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; Do not cross the product of sieve and mediate and extruder grain through comminution by gas stream, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 5: the emamectin-benzoate with 30%, 10% sodium lignin sulfonate dispersant, 2% OP-21 wetting agent, 1% BHT stabilizing agent and 55% anhydrous sodium sulfate filler mixes and through comminution by gas stream, adding 2% dextrin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; Do not cross the product of sieve and mediate and extruder grain through comminution by gas stream, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Emamectin-benzoate is a kind of semisynthetic antibiotics insecticides agricultural chemicals, be that a class has the bioactive insecticide of super-high-efficient, its mechanism of action is that the effect of neurotic glutamate of enhancing and γ-An Jidingsuan is that a large amount of chlorions enter nerve cell, make the cell function forfeiture, upset nerve conduction.Have stomach toxicity and action of contace poison, permeability is strong.This product can be widely used in the control of the various pests on the crops such as vegetables, fruit tree, cotton.Normally used formulation is 1% emamectin-benzoate missible oil, for reducing processing, the quantity of storing, transporting, reduce the preparation consumption, be user-friendly to, we have carried out a large amount of careful research work to the emamectin-benzoate soluble granule, develop the emamectin-benzoate soluble granule.
Emamectin-benzoate soluble granule performance indications are as follows:
| Project | Performance indications |
| Outward appearance | Yellowish or yellow loose granular particle does not have visible exogenous impurity |
| Content | ≥0.5-40％ |
| Dispersed | Adopt the graduated cylinder bulk method to carry out favorable dispersibility |
| Wetability | Adopt the measuring graduates test method(s), wetting time was less than 1 minute |
| Dissolubility | Undertaken by HG/T2467.15-2003, residue behind the 5min≤ |
| 0.5%, residue behind the 18h≤2.0% | |
| Moisture | Adopt azeotropic method or karl Fischer method, moisture is less than 3.0% |
| PH value | Undertaken by GB/T1601, measure PH5.5～7.5 |
| Lasting foaming characteristic | Carry out foam volume≤60ml behind the 1min by HG/T2467.5-2003 |
Product stability research: the emamectin-benzoate soluble granule sample that will sieve is sealed in respectively in 12 50ml ampoule bottles, about 20 gram samples in every ampoule bottle, be placed in (54 ± 2) ℃ insulating box and carry out check and analysis after two weeks of storage, calculate heat storage resolution ratio, the heat storage stability experimental result is as follows:
| Numbering | 20040801 | 20040803 | 20040805 | 20040809 | 20040901 |
| Resolution ratio, % | 2.88 | 2.97 | 3.47 | 2.43 | 2.50 |
By last table result as seen, emamectin-benzoate soluble granule heat storage stability is better, and heat storage resolution ratio is less than 5%.
Dispersant, wetting agent are to the influence of properties of product: dispersant is meant the solid chemicals particle is dispersed in the aqueous solution, makes solia particle long period in liquid phase keep a homodisperse class material.Wetting agent is after making product particle fully wetting, to play the effect of fine dissolving.Dispersant and wetting agent are most important auxiliary elements in the soluble granule, by dispersant above-mentioned, wetting agent kind are screened, composite, obtain emamectin-benzoate soluble granule product.
Soluble granule is a kind of pesticides new formulation, with the advantage of solid pharmaceutical preparation and liquid preparation, is the more comprehensive product of combination property in the current pesticidal preparations.The emamectin-benzoate soluble granule at present common crop pests as diamond-back moth, beet armyworm, tomato moth, cabbage caterpillar, two spotted spider mite, mites etc. have the incomparable result of use of general chemical pesticide, and succeeding in developing of its green novel form will further strengthen its safety to environment, people and animals, crop.No matter be various auxiliary agents sources in the prescription, or production equipment all is based on domesticly, product cost is lower, therefore, and for the suitability for industrialized production of this formulation and apply and lay a good foundation.
Claims (2)
1, a kind of disinsection soluble granules that contains emamectin-benzoate, it is characterized in that forming soluble granule by emamectin-benzoate, dispersant, wetting agent, binding agent, stabilizing agent, filler, it forms content (is 100% in soluble granule weight): emamectin-benzoate 0.5-40%, dispersant 2～10%, wetting agent 1～5%, binding agent 2～4%, stabilizing agent 1～3%, all the other are fillers.
2, the disinsection soluble granules that contains emamectin-benzoate as claimed in claim 1, it is characterized in that described dispersant is selected from sodium lignin sulfonate, described wetting agent is selected from OP-10, OP-21, lauryl sodium sulfate, JFC, described binding agent is selected from dextrin, polyethylene glycol, gelatin, described stabilizing agent is selected from BHT, tbp, sodium hydrogen phosphate, and described filler is selected from maltose, glucose, solvable starch, Lactis Anhydrous, anhydrous sodium sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510012997 CN1775027A (en) | 2005-11-21 | 2005-11-21 | Disinsection soluble granules containing methylamino avermection benzoate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510012997 CN1775027A (en) | 2005-11-21 | 2005-11-21 | Disinsection soluble granules containing methylamino avermection benzoate |
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| Publication Number | Publication Date |
|---|---|
| CN1775027A true CN1775027A (en) | 2006-05-24 |
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| CN 200510012997 Pending CN1775027A (en) | 2005-11-21 | 2005-11-21 | Disinsection soluble granules containing methylamino avermection benzoate |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100394852C (en) * | 2006-09-21 | 2008-06-18 | 栾贵书 | Methylamino avermectin benzoate soluble granule and preparation method thereof |
| WO2009086739A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of chlorfenapyr and its preparation |
| WO2009086741A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of spinosad and its preparation |
| WO2009086740A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of indoxacarb and its preparation |
| WO2009089687A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of kresoxim-methyl and its preparation |
| WO2009089688A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of fipronil and its preparation |
| CN101731207B (en) * | 2009-12-30 | 2013-04-03 | 北京富力特农业科技有限责任公司 | Emulsifiable grains of emamectin benzoate and preparation method thereof |
| CN103238617A (en) * | 2012-07-04 | 2013-08-14 | 河北威远生物化工股份有限公司 | Clothianidin synergia solubility granula and preparation method thereof |
| CN103858936A (en) * | 2014-02-14 | 2014-06-18 | 暨南大学 | Multifunctional environment-friendly emamectin benzoate aqueous solution and preparation method thereof |
| CN104304271A (en) * | 2011-12-09 | 2015-01-28 | 沈阳科创化学品有限公司 | Binary pesticide composition and application |
| CN104621170A (en) * | 2015-02-03 | 2015-05-20 | 河北威远生化农药有限公司 | Acetamiprid and emamectin benzoate mixed soluble granular insecticide and preparation method thereof |
| CN106259325A (en) * | 2016-08-17 | 2017-01-04 | 河北威远生化农药有限公司 | A kind of glufosinate-ammonium synergia solubility granula and preparation method thereof |
| CN106857653A (en) * | 2017-02-15 | 2017-06-20 | 华北制药集团爱诺有限公司 | Soluble granule and its application process for preventing and treating root disease |
| CN107494557A (en) * | 2017-08-02 | 2017-12-22 | 江苏仁信化工有限公司 | A kind of emamectin-benzoate granule and its production method |
| CN109042641A (en) * | 2018-09-14 | 2018-12-21 | 河北威远生物化工有限公司 | A kind of emamectin benzoate B2a/B2b benzoate granule and preparation method thereof |
| CN110519986A (en) * | 2016-09-16 | 2019-11-29 | 阿伦·沙旺特 | The stabilization formulations of water sensitivity active matter |
| CN112106769A (en) * | 2020-09-11 | 2020-12-22 | 惠州市银农科技股份有限公司 | Emamectin benzoate dry suspending agent and preparation method thereof |
| CN112970767A (en) * | 2019-12-13 | 2021-06-18 | 佳木斯兴宇生物技术开发有限公司 | Emamectin benzoate and ningnanmycin soluble granules and preparation method thereof |
-
2005
- 2005-11-21 CN CN 200510012997 patent/CN1775027A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100394852C (en) * | 2006-09-21 | 2008-06-18 | 栾贵书 | Methylamino avermectin benzoate soluble granule and preparation method thereof |
| WO2009086739A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of chlorfenapyr and its preparation |
| WO2009086741A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of spinosad and its preparation |
| WO2009086740A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of indoxacarb and its preparation |
| WO2009089687A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of kresoxim-methyl and its preparation |
| WO2009089688A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of fipronil and its preparation |
| CN101657093A (en) * | 2008-01-15 | 2010-02-24 | 栾贵书 | Water soluble granule of kresoxim-methyl and its preparation |
| CN101657093B (en) * | 2008-01-15 | 2012-11-21 | 佳木斯兴宇生物技术开发有限公司 | Water soluble granule of kresoxim-methyl and preparation thereof |
| CN101731207B (en) * | 2009-12-30 | 2013-04-03 | 北京富力特农业科技有限责任公司 | Emulsifiable grains of emamectin benzoate and preparation method thereof |
| CN104304271A (en) * | 2011-12-09 | 2015-01-28 | 沈阳科创化学品有限公司 | Binary pesticide composition and application |
| CN104304271B (en) * | 2011-12-09 | 2016-08-17 | 沈阳科创化学品有限公司 | A kind of binary pesticide composition and purposes |
| CN103238617B (en) * | 2012-07-04 | 2015-01-28 | 河北威远生化农药有限公司 | Clothianidin synergia solubility granula and preparation method thereof |
| CN103238617A (en) * | 2012-07-04 | 2013-08-14 | 河北威远生物化工股份有限公司 | Clothianidin synergia solubility granula and preparation method thereof |
| CN103858936A (en) * | 2014-02-14 | 2014-06-18 | 暨南大学 | Multifunctional environment-friendly emamectin benzoate aqueous solution and preparation method thereof |
| CN103858936B (en) * | 2014-02-14 | 2016-06-29 | 暨南大学 | A kind of Multifunctional environment friendly emamectin-benzoate water preparation and preparation method thereof |
| CN104621170A (en) * | 2015-02-03 | 2015-05-20 | 河北威远生化农药有限公司 | Acetamiprid and emamectin benzoate mixed soluble granular insecticide and preparation method thereof |
| CN106259325A (en) * | 2016-08-17 | 2017-01-04 | 河北威远生化农药有限公司 | A kind of glufosinate-ammonium synergia solubility granula and preparation method thereof |
| CN106259325B (en) * | 2016-08-17 | 2019-11-22 | 河北威远生物化工有限公司 | A kind of glufosinate-ammonium synergia solubility granula and preparation method thereof |
| CN110519986A (en) * | 2016-09-16 | 2019-11-29 | 阿伦·沙旺特 | The stabilization formulations of water sensitivity active matter |
| CN106857653A (en) * | 2017-02-15 | 2017-06-20 | 华北制药集团爱诺有限公司 | Soluble granule and its application process for preventing and treating root disease |
| CN107494557A (en) * | 2017-08-02 | 2017-12-22 | 江苏仁信化工有限公司 | A kind of emamectin-benzoate granule and its production method |
| CN109042641A (en) * | 2018-09-14 | 2018-12-21 | 河北威远生物化工有限公司 | A kind of emamectin benzoate B2a/B2b benzoate granule and preparation method thereof |
| CN112970767A (en) * | 2019-12-13 | 2021-06-18 | 佳木斯兴宇生物技术开发有限公司 | Emamectin benzoate and ningnanmycin soluble granules and preparation method thereof |
| CN112106769A (en) * | 2020-09-11 | 2020-12-22 | 惠州市银农科技股份有限公司 | Emamectin benzoate dry suspending agent and preparation method thereof |
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