CN1666863A - 层合膜 - Google Patents
层合膜 Download PDFInfo
- Publication number
- CN1666863A CN1666863A CNA2005100513840A CN200510051384A CN1666863A CN 1666863 A CN1666863 A CN 1666863A CN A2005100513840 A CNA2005100513840 A CN A2005100513840A CN 200510051384 A CN200510051384 A CN 200510051384A CN 1666863 A CN1666863 A CN 1666863A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- laminate film
- carboxylic acid
- mass parts
- acrylic polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005001 laminate film Substances 0.000 title claims description 121
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 53
- 239000010410 layer Substances 0.000 claims description 121
- 210000004276 hyalin Anatomy 0.000 claims description 88
- 239000007787 solid Substances 0.000 claims description 52
- 239000008199 coating composition Substances 0.000 claims description 51
- 239000000470 constituent Substances 0.000 claims description 38
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 24
- 239000003505 polymerization initiator Substances 0.000 claims description 19
- 239000002243 precursor Substances 0.000 claims description 19
- 230000009477 glass transition Effects 0.000 claims description 17
- 239000004925 Acrylic resin Substances 0.000 claims description 9
- 229920000178 Acrylic resin Polymers 0.000 claims description 9
- 238000004040 coloring Methods 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 210000003684 theca cell Anatomy 0.000 claims description 9
- 229920005749 polyurethane resin Polymers 0.000 claims description 8
- 239000012790 adhesive layer Substances 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims 6
- 238000000576 coating method Methods 0.000 abstract description 63
- 239000011248 coating agent Substances 0.000 abstract description 58
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 53
- 238000005507 spraying Methods 0.000 abstract description 13
- 238000000465 moulding Methods 0.000 abstract description 11
- 238000010030 laminating Methods 0.000 abstract 2
- 238000005034 decoration Methods 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- -1 3,4-epoxycyclohexyl (methyl) acrylate Chemical compound 0.000 description 52
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
- 239000000463 material Substances 0.000 description 50
- 239000000243 solution Substances 0.000 description 39
- 239000004593 Epoxy Substances 0.000 description 37
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 34
- 150000001875 compounds Chemical class 0.000 description 32
- 229920005989 resin Polymers 0.000 description 30
- 239000011347 resin Substances 0.000 description 30
- 238000004519 manufacturing process Methods 0.000 description 29
- 239000000203 mixture Substances 0.000 description 27
- 238000012360 testing method Methods 0.000 description 25
- 239000002904 solvent Substances 0.000 description 24
- 238000000034 method Methods 0.000 description 23
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 22
- 150000003254 radicals Chemical class 0.000 description 22
- 229920001577 copolymer Polymers 0.000 description 19
- 239000000523 sample Substances 0.000 description 19
- DYKQZKPEUOVBCV-UHFFFAOYSA-N cyclopentylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CCCC1 DYKQZKPEUOVBCV-UHFFFAOYSA-N 0.000 description 18
- 239000003973 paint Substances 0.000 description 18
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 17
- 238000011156 evaluation Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 12
- 230000001070 adhesive effect Effects 0.000 description 12
- 150000001260 acyclic compounds Chemical class 0.000 description 11
- 239000004922 lacquer Substances 0.000 description 11
- 238000012986 modification Methods 0.000 description 11
- 230000004048 modification Effects 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 10
- 238000001723 curing Methods 0.000 description 10
- 230000007423 decrease Effects 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 230000005670 electromagnetic radiation Effects 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 9
- 230000002950 deficient Effects 0.000 description 8
- 238000003618 dip coating Methods 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 6
- 238000007259 addition reaction Methods 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004611 light stabiliser Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920001228 polyisocyanate Polymers 0.000 description 4
- 239000005056 polyisocyanate Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000013007 heat curing Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000000630 rising effect Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical class CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000005041 Mylar™ Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- WUDNUHPRLBTKOJ-UHFFFAOYSA-N ethyl isocyanate Chemical compound CCN=C=O WUDNUHPRLBTKOJ-UHFFFAOYSA-N 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229940119545 isobornyl methacrylate Drugs 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 235000016804 zinc Nutrition 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- AKABKVXLWWIVIW-UHFFFAOYSA-N 1,1-diisocyanatohexane Chemical compound CCCCCC(N=C=O)N=C=O AKABKVXLWWIVIW-UHFFFAOYSA-N 0.000 description 1
- OTKCEEWUXHVZQI-UHFFFAOYSA-N 1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(=O)CC1=CC=CC=C1 OTKCEEWUXHVZQI-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- LNBMZFHIYRDKNS-UHFFFAOYSA-N 2,2-dimethoxy-1-phenylethanone Chemical class COC(OC)C(=O)C1=CC=CC=C1 LNBMZFHIYRDKNS-UHFFFAOYSA-N 0.000 description 1
- JWOACSMESNKGGJ-UHFFFAOYSA-N 2-ethenyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)C=C JWOACSMESNKGGJ-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- MWKAGZWJHCTVJY-UHFFFAOYSA-N 3-hydroxyoctadecan-2-one Chemical compound CCCCCCCCCCCCCCCC(O)C(C)=O MWKAGZWJHCTVJY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 description 1
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 206010018612 Gonorrhoea Diseases 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- YFKGZRWMLKUAAF-UHFFFAOYSA-N OC(=CC)CC.C(C=1C(C(=O)O)=CC=CC1)(=O)O Chemical group OC(=CC)CC.C(C=1C(C(=O)O)=CC=CC1)(=O)O YFKGZRWMLKUAAF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
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- 241000251184 Rajiformes Species 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
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- 150000001454 anthracenes Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- YAVVGPBYBUYPSR-UHFFFAOYSA-N benzene;oxygen Chemical compound [O].C1=CC=CC=C1 YAVVGPBYBUYPSR-UHFFFAOYSA-N 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
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- LOLKAJARZKDJTD-UHFFFAOYSA-N butanedioic acid monoethyl ester Natural products CCOC(=O)CCC(O)=O LOLKAJARZKDJTD-UHFFFAOYSA-N 0.000 description 1
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- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
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- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
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- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
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- C08J2433/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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Abstract
Description
前体 | ||||||||||||||
(1) | (2) | (3) | (4) | (5) | (6) | (7) | (8) | (9) | (10) | (11) | (12) | |||
(I) | 甲苯(g) | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | |
(II) | 甲基丙烯酸缩水甘油酯(g) | (分子量)142 | 30 | 30 | 30 | 30 | 30 | 10 | 30 | 22.5 | 24.6 | 25.4 | 59.4 | 24.1 |
甲基丙烯酸甲酯(g)异冰片基甲基丙烯酸酯(g)甲基丙烯酸丁酯(g) | 100222128 | 35.834.2- | 35.834.2- | 35.834.2- | 31.824.214 | 664- | 50335 | 35.834.2- | 55.522- | 5223.4- | 49.625- | --- | 51.424.5- | |
二环戊基甲基丙烯酸酯(g)2-羟基乙基甲基丙烯酸酯(g) | 264130 | -- | -- | -- | -- | -- | -2 | -- | -- | -- | -- | 26.614 | -- | |
过氧丁基(g) | 0.6 | 2 | 0.3 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | ||
(III) | 甲苯(g)过氧丁基(g) | 251 | 251 | 251 | 251 | 251 | 251 | 251 | 251 | 251 | 251 | 251 | 251 | |
(IV) | 甲苯(g) | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | |
重均分子量(×1,000) | 60 | 20 | 150 | 110 | 110 | 110 | 110 | 110 | 110 | 110 | 110 | 110 | ||
玻璃化转变温度(℃) | 97 | 97 | 97 | 60 | 110 | 97 | 97 | 97 | 97 | 97 | 70 | 97 | ||
固体重量分数(%) | 46.5 | 46.5 | 45.7 | 45.8 | 46.5 | 45.7 | 45.7 | 46.5 | 45.7 | 45.8 | 46.5 | 45.7 |
前体 | 比较前体 | |||||||||||
(13) | (14) | (15) | (16) | (17) | (18) | (19) | (20) | (1) | (2) | |||
(I) | 甲苯(g) | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | 70 | |
(II) | 甲基丙烯酸缩水甘油酯(g) | (分子量)142 | 24.1 | 24.1 | 9.6 | 73.8 | 22.3 | 24.7 | 19.7 | 73 | 24.1 | 24.1 |
甲基丙烯酸甲酯(g)异冰片基甲基丙烯酸酯(g)甲基丙烯酸丁酯(g) | 100222128 | 36.91524 | --- | 55.4305 | --- | 57.720- | 50.325- | 64.316- | --- | 51.424.5- | 51.424.5- | |
二环戊基(甲基)丙烯酸酯(g)2-羟基乙基甲基丙烯酸酯(g) | 264130 | -- | 75.9- | -- | 15.211 | -- | -- | -- | -27 | -- | -- | |
过氧丁基(g) | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 3 | 0.1 | ||
(III) | 甲苯(g) | 25 | 25 | 25 | 25 | 25 | 25 | 25 | 25 | 25 | 25 | |
过氧丁基(g) | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | ||
(IV) | 甲苯(g) | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | 29 | |
重均分子量(×1,000) | 110 | 110 | 110 | 110 | 110 | 110 | 110 | 110 | 12 | 200 | ||
玻璃化转变温度(℃) | 40 | 133 | 97 | 57 | 97 | 97 | 97 | 45 | 97 | 97 | ||
固体重量分数(%) | 45.7 | 45.8 | 46.5 | 45.5 | 45.7 | 46.5 | 45.7 | 45.8 | 46.5 | 46.5 |
分子量 | 树脂 | |||||||||||||
(1) | (2) | (3) | (4) | (5) | (6) | (7) | (8) | (9) | (10) | (11) | (12) | |||
(V) | 前体(g) | - | (1)225.6 | (2)225.6 | (3)225.3 | (4)225.4 | (5)225.4 | (6)225.4 | (7)225.4 | (8)225.4 | (9)225.4 | (10)225.4 | (11)225.4 | (12)225.4 |
长链不饱和羧酸(B1d1)アロニツクスM5300(g) | 315 | 34.2 | 34.2 | 34.2 | 34.2 | 34.2 | 11.4 | 33.27 | 10.1 | 44.9 | 46.4 | 27.3 | 27.5 | |
短链不饱和羧酸(B1d2)甲基丙烯酸(g)丙烯酸(g) | 8672 | -7.84 | -7.84 | -7.84 | -7.84 | -7.84 | -2.6 | 9.08- | -9.43 | -2.6 | -2.7 | -24.8 | -6.3 | |
氢醌单甲基酯(g)甲苯(g) | -- | 0.4356 | 0.4356 | 0.4356 | 0.4356 | 0.4356 | 0.4320 | 0.4356 | 0.4330 | 0.4330 | 0.4356 | 0.4356 | 0.4356 | |
(VI) | 溴化四乙铵甲苯(g) | -- | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 |
(VII) | 氢醌单甲基酯(g)甲苯(g) | -- | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 |
(VIII) | カレンズMOI甲苯(g)二月桂酸二丁锌 | 155-- | 16.950.043 | 10.150.043 | 10.150.043 | 10.150.043 | 16.950.043 | 1.850.043 | -30- | 5.850.043 | 5.950.043 | 9.550.043 | 24.450.043 | 5.450.043 |
(IX) | 甲醇(g)甲苯(g) | -- | 210 | 210 | 210 | 210 | 210 | 210 | -- | 210 | 210 | 210 | 210 | 210 |
重均分子量(×1,000) | 150 | 70 | 400 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | ||
羟基值(OHV)(mg KOH/g) | 37 | 55 | 55 | 55 | 55 | 35 | 83 | 54 | 49 | 42 | 125 | 54 | ||
固体重量分数(%) | 44 | 44 | 44.9 | 44 | 45.7 | 40 | 40 | 41 | 45.6 | 44 | 45.8 | 40 | ||
长链不饱和羧酸(B1d1)(摩尔%) | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 20 | 80 | 80 | 20 | 50 | ||
短链不饱和羧酸(B1d2)(摩尔%) | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 80 | 20 | 20 | 80 | 50 |
分子量 | 前体 | 比较前体 | ||||||||||
(13) | (14) | (15) | (16) | (17) | (18) | (19) | (20) | (1) | (2) | |||
(V) | 前体(g) | (13)225.4 | (14)225.4 | (15)225.4 | (16)225.4 | (17)225.4 | (18)225.4 | (19)225.4 | (20)225.4 | (1)228 | (2)225.6 | |
长链不饱和羧酸(B1d1)アロニツクスM5300(g) | 315 | 27.5 | 27.5 | 10.9 | 33.7 | 5 | 50.9 | 22.6 | 83.4 | 27.5 | 27.5 | |
短链不饱和羧酸(B1d2)甲基丙烯酸(g)丙烯酸(g) | 8672 | -6.3 | -6.3 | -2.5 | -30.8 | -10.5 | -1.2 | -5.2 | -19 | -6.3 | -6.3 | |
氢醌单甲基酯(g)甲苯(g) | -- | 0.4320 | 0.4320 | 0.4320 | 0.4350 | 0.4320 | 0.4335 | 0.4320 | 0.43100 | 0.4356 | 0.4356 | |
(VI) | 溴化四乙铵甲苯(g) | -- | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 | 0.813 |
(VII) | 氢醌单甲基酯(g)甲苯(g) | -- | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 | 0.433 |
(VIII) | カレンズMOI甲苯(g)二月桂酸二丁锌 | 155-- | 5.450.043 | 5.450.043 | --- | 29.850.043 | 5.650.043 | 6.150.043 | 1250.043 | 32.350.043 | 5.450.043 | 5.450.043 |
IX | 甲醇(g)甲苯(g) | -- | 210 | 210 | -10 | 240 | 210 | 210 | 210 | 230 | 210 | 210 |
重均分子量(×1,000) | 400 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 20 | 600 | ||
羟基值(OHV)(mg KOH/g) | 54 | 54 | 33 | 125 | 56 | 48 | 25 | 132 | 54 | 54 | ||
固体重量分数(%) | 44.9 | 44 | 40 | 45.3 | 41 | 45.4 | 44.6 | 45.8 | 44 | 44 | ||
长链不饱和羧酸(B1d1)(摩尔%) | 50 | 50 | 50 | 20 | 10 | 90 | 50 | 50 | 50 | 50 | ||
短链不饱和羧酸(B1d2)(摩尔%) | 50 | 50 | 50 | 80 | 90 | 10 | 50 | 50 | 50 | 50 |
实施例 | 层合膜/实验片 | 树脂(B1) | 树脂(B1)(固体成分重量(g)) | 氨基甲酸类低聚物(B2)(固体成分重量(g)) |
1 | 1 | (1) | 50 | 50 |
2 | 2 | (2) | 50 | 50 |
3 | 3 | (3) | 50 | 50 |
4 | 4 | (4) | 50 | 50 |
5 | 5 | (5) | 50 | 50 |
6 | 6 | (6) | 50 | 50 |
7 | 7 | (7) | 50 | 50 |
8 | 8 | (8) | 50 | 50 |
9 | 9 | (9) | 50 | 50 |
10 | 10 | (10) | 50 | 50 |
11 | 11 | (11) | 50 | 50 |
12 | 12 | (12) | 40 | 60 |
13 | 13 | (13) | 60 | 40 |
14 | 14 | (14) | 50 | 50 |
15 | 15 | (15) | 50 | 50 |
16 | 16 | (16) | 50 | 50 |
17 | 17 | (17) | 50 | 50 |
18 | 18 | (18) | 50 | 50 |
19 | 19 | (19) | 50 | 50 |
20 | 20 | (20) | 50 | 50 |
21 | 21 | (21) | 50 | 50 |
实施例 | 相溶性 | 不粘结性 | 万能硬度(N/mm2) | 断裂伸长率(%) | 成型性 | 初期贴合性 | 耐水性 | 耐乙醇汽油溶液性 | 硬度 | 弯曲性 | |
透明层(B) | 透明涂层 | ||||||||||
1 | ○ | ○ | 125 | 670 | 8 | ○ | ○ | ○ | ○ | ○ | ○ |
2 | ○ | ○ | 120 | 670 | 8 | ○ | ○ | ○ | ○ | ○ | ○ |
3 | ○ | ○ | 125 | 670 | 8 | ○ | ○ | ○ | ○ | ○ | ○ |
4 | ○ | ○ | 70 | 530 | 10 | ○ | ○ | ○ | ○ | ○ | ○ |
5 | ○ | ○ | 130 | 580 | 7 | ○ | ○ | ○ | ○ | ○ | ○ |
6 | ○ | ○ | 105 | 420 | 12 | ○ | ○ | ○ | ○ | ○ | ○ |
7 | ○ | ○ | 135 | 550 | 6 | ○ | ○ | ○ | ○ | ○ | ○ |
8 | ○ | ○ | 135 | 560 | 6 | ○ | ○ | ○ | ○ | ○ | ○ |
9 | ○ | ○ | 110 | 630 | 11 | ○ | ○ | ○ | ○ | ○ | ○ |
10 | ○ | ○ | 120 | 620 | 8 | ○ | ○ | ○ | ○ | ○ | ○ |
11 | ○ | ○ | 145 | 560 | 5 | ○ | ○ | ○ | ○ | ○ | ○ |
12 | ○ | ○ | 65 | 430 | 20 | ○ | ○ | ○ | ○ | ○ | ○ |
13 | ○ | ○ | 130 | 540 | 5 | ○ | ○ | ○ | ○ | ○ | ○ |
比较例 | 比较层合膜/比较试验片 | 树脂(B1) | 树脂(B1)/比较树脂(固体成分重量(g)) | 氨基甲酸类低聚物(B2)(固体成分重量(g)) |
1 | 1 | 比较树脂(1) | 50 | 50 |
2 | 2 | 比较树脂(2) | 50 | 50 |
3 | 3 | 树脂(12) | 20 | 80 |
4 | 4 | 树脂(12) | 80 | 20 |
Claims (8)
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JP7421885B2 (ja) | 2019-08-20 | 2024-01-25 | 株式会社エフコンサルタント | 面材 |
TWI724765B (zh) * | 2020-01-21 | 2021-04-11 | 達興材料股份有限公司 | 可雷射離型的組成物、其積層體和雷射離型方法 |
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MY121667A (en) | 1996-04-26 | 2006-02-28 | Nissha Printing | Thermo and active energy ray curable resin composition used for protecting layer of transfer material transfer material surface protecting material and process for producing molded article excellent in abrasion resistance and chemical resistance. |
DE69921952T2 (de) | 1998-06-30 | 2005-11-03 | Nissha Printing Co., Ltd. | Laminierte folie zum einsatzformen und verfahren zum einsatzformen mit dieser folie |
JP3516384B2 (ja) * | 1998-07-31 | 2004-04-05 | 日本合成化学工業株式会社 | 再剥離型粘着剤組成物 |
US6329060B1 (en) * | 1999-11-10 | 2001-12-11 | Ppg Industries Ohio, Inc. | Solvent-free film-forming compositions for clearcoats, coated substrates and method related thereto |
US7052769B2 (en) * | 2003-03-31 | 2006-05-30 | Nippon Bee Chemical Co., Ltd. | Laminate film and article having same |
-
2004
- 2004-03-10 JP JP2004067340A patent/JP4374262B2/ja not_active Expired - Fee Related
-
2005
- 2005-03-09 CN CNB2005100513840A patent/CN100471670C/zh not_active Expired - Fee Related
- 2005-03-09 US US11/074,702 patent/US7510769B2/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102471426A (zh) * | 2009-07-22 | 2012-05-23 | 日立化成工业株式会社 | 光固化性树脂组合物和其固化物、树脂片材和其制造法以及显示装置 |
CN102471426B (zh) * | 2009-07-22 | 2013-10-30 | 日立化成株式会社 | 光固化性树脂组合物和其固化物、树脂片材和其制造法以及显示装置 |
US8697240B2 (en) | 2009-07-22 | 2014-04-15 | Hitachi Chemical Company, Ltd. | Photocurable resin composition and cured product of same, resin sheet and production method for same, and display device |
CN109828701A (zh) * | 2019-03-16 | 2019-05-31 | 北京氦舶科技有限责任公司 | 一种电容式触摸屏用透明导电膜及其制备方法 |
Also Published As
Publication number | Publication date |
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JP4374262B2 (ja) | 2009-12-02 |
US7510769B2 (en) | 2009-03-31 |
US20050202266A1 (en) | 2005-09-15 |
JP2005255781A (ja) | 2005-09-22 |
CN100471670C (zh) | 2009-03-25 |
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