CN1655868A - 含铋和磷的催化剂载体、由其制备的重整催化剂、其制备方法和石脑油重整方法 - Google Patents
含铋和磷的催化剂载体、由其制备的重整催化剂、其制备方法和石脑油重整方法 Download PDFInfo
- Publication number
- CN1655868A CN1655868A CNA038116375A CN03811637A CN1655868A CN 1655868 A CN1655868 A CN 1655868A CN A038116375 A CNA038116375 A CN A038116375A CN 03811637 A CN03811637 A CN 03811637A CN 1655868 A CN1655868 A CN 1655868A
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- Prior art keywords
- catalyst
- carrier
- bismuth
- amount
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1856—Phosphorus; Compounds thereof with iron group metals or platinum group metals with platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
载体 | A | B | C | D | E |
溶液: | |||||
gBi(NO3)3.5H2O | 3.20 | 1.87 | 1.49 | 1.12 | 0.747 |
g右旋甘露糖醇 | 1.50 | 0.90 | 0.72 | 0.54 | 0.36 |
g去离子水 | 10.0 | 6.0 | 4.5 | 3.5 | 2.5 |
成品载体: | |||||
Bi,wt% | 0.17 | 0.10 | 0.08 | 0.06 | 0.04 |
P,wt% | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
Al2O3 | 余量 | 余量 | 余量 | 余量 | 余量 |
阶段 | 催化剂,cc | SiC,cc |
1(入口) | 1.9 | 17.1 |
2 | 5.7 | 13.3 |
3 | 11.4 | 7.6 |
4(出口) | 19.0 | 0 |
催化剂 | Pt/Bi/P,wt% | 活性,℃/hr | C5+产率,vol%/hr | 结焦率,wt%/hr |
A | 0.25/0.17/0.3 | +0.357 | -0.069 | +0.074 |
B | 0.25/0.1/0.32 | +0.270 | -0.043 | +0.058 |
C | 0.25/0.07/0.28 | +0.270 | -0.034 | +0.054 |
D | 0.26/0.06/0.29 | +0.258 | -0.045 | +0.052 |
E | 0.26/0.04/0.3 | +0.332 | -0.056 | +0.068 |
F | 0.24/0.06/0 | +0.300 | -0.054 | +0.061 |
G | 0.3/0/0.3 | +0.458 | -0.087 | +0.072 |
H | 0.3/0/0 | +0.390 | -0.095 | +0.074 |
催化剂 | Pt/Re/Bi/P,wt% | 活性,℃/hr | C5+产率,vol%/hr | 结焦率,wt%/hr |
I | 0.25/0.26/0.06/0.3 | +0.184 | -0.016 | +0.070 |
J | 0.26/0.24/0.06/0 | +0.284 | -0.035 | +0.076 |
K | 0.25/0.25/0/0.3 | +0.247 | -0.020 | +0.074 |
L | 0.25/0.25/0/0 | +0.281 | -0.027 | +0.075 |
Claims (25)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/154,458 | 2002-05-22 | ||
US10/154,458 US6667270B2 (en) | 2002-05-22 | 2002-05-22 | Bismuth-and phosphorus-containing catalyst support, reforming catalysts made from same, method of making and naphtha reforming process |
PCT/US2003/015916 WO2003099432A1 (en) | 2002-05-22 | 2003-05-20 | Bismuth-and phosphorus-containing catalysts support, reforming catalysts made from same, method of making and naphtha reforming process |
Publications (2)
Publication Number | Publication Date |
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CN1655868A true CN1655868A (zh) | 2005-08-17 |
CN1655868B CN1655868B (zh) | 2010-05-26 |
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CN038116375A Expired - Fee Related CN1655868B (zh) | 2002-05-22 | 2003-05-20 | 含铋和磷的催化剂载体、由其制备的重整催化剂、其制备方法和石脑油重整方法 |
Country Status (19)
Country | Link |
---|---|
US (2) | US6667270B2 (zh) |
EP (1) | EP1507585B1 (zh) |
JP (1) | JP4642460B2 (zh) |
KR (2) | KR20040111661A (zh) |
CN (1) | CN1655868B (zh) |
AR (2) | AR039832A1 (zh) |
AT (1) | ATE344100T1 (zh) |
AU (1) | AU2003229339A1 (zh) |
BR (1) | BR0311131A (zh) |
CA (1) | CA2486572C (zh) |
DE (1) | DE60309464T2 (zh) |
DK (1) | DK1507585T3 (zh) |
ES (1) | ES2272991T3 (zh) |
MX (1) | MXPA04011551A (zh) |
NO (1) | NO20044765L (zh) |
RU (1) | RU2310506C2 (zh) |
TW (2) | TW200400850A (zh) |
WO (1) | WO2003099432A1 (zh) |
ZA (2) | ZA200408771B (zh) |
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-
2002
- 2002-05-22 US US10/154,458 patent/US6667270B2/en not_active Expired - Lifetime
- 2002-08-08 US US10/216,155 patent/US6864212B2/en not_active Expired - Lifetime
-
2003
- 2003-05-20 WO PCT/US2003/015916 patent/WO2003099432A1/en active IP Right Grant
- 2003-05-20 KR KR10-2004-7018718A patent/KR20040111661A/ko not_active Application Discontinuation
- 2003-05-20 BR BR0311131-8A patent/BR0311131A/pt not_active IP Right Cessation
- 2003-05-20 KR KR10-2004-7018719A patent/KR20040111662A/ko not_active Application Discontinuation
- 2003-05-20 RU RU2004137502/04A patent/RU2310506C2/ru not_active IP Right Cessation
- 2003-05-20 DK DK03726931T patent/DK1507585T3/da active
- 2003-05-20 TW TW092113604A patent/TW200400850A/zh unknown
- 2003-05-20 EP EP03726931A patent/EP1507585B1/en not_active Expired - Lifetime
- 2003-05-20 CN CN038116375A patent/CN1655868B/zh not_active Expired - Fee Related
- 2003-05-20 MX MXPA04011551A patent/MXPA04011551A/es not_active Application Discontinuation
- 2003-05-20 ES ES03726931T patent/ES2272991T3/es not_active Expired - Lifetime
- 2003-05-20 AR ARP030101742A patent/AR039832A1/es unknown
- 2003-05-20 AU AU2003229339A patent/AU2003229339A1/en not_active Abandoned
- 2003-05-20 AR ARP030101741A patent/AR039831A1/es unknown
- 2003-05-20 TW TW092113603A patent/TW200400252A/zh unknown
- 2003-05-20 CA CA2486572A patent/CA2486572C/en not_active Expired - Fee Related
- 2003-05-20 JP JP2004506950A patent/JP4642460B2/ja not_active Expired - Fee Related
- 2003-05-20 AT AT03726931T patent/ATE344100T1/de not_active IP Right Cessation
- 2003-05-20 DE DE60309464T patent/DE60309464T2/de not_active Expired - Fee Related
-
2004
- 2004-10-29 ZA ZA200408771A patent/ZA200408771B/en unknown
- 2004-10-29 ZA ZA200408770A patent/ZA200408770B/en unknown
- 2004-11-03 NO NO20044765A patent/NO20044765L/no not_active Application Discontinuation
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CN102665897A (zh) * | 2009-07-01 | 2012-09-12 | Ifp新能源公司 | 具有接近优化位点的多金属催化剂的制备方法 |
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CN114761124B (zh) * | 2019-11-29 | 2024-09-06 | 沙索德国有限公司 | 氧化铝铋催化剂载体及其制备方法 |
Also Published As
Publication number | Publication date |
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RU2004137502A (ru) | 2005-06-10 |
US20030220192A1 (en) | 2003-11-27 |
RU2310506C2 (ru) | 2007-11-20 |
EP1507585B1 (en) | 2006-11-02 |
US6667270B2 (en) | 2003-12-23 |
DE60309464T2 (de) | 2007-11-15 |
JP2005525932A (ja) | 2005-09-02 |
ZA200408770B (en) | 2005-11-22 |
AR039832A1 (es) | 2005-03-02 |
ES2272991T3 (es) | 2007-05-01 |
ZA200408771B (en) | 2006-07-26 |
WO2003099432A1 (en) | 2003-12-04 |
US6864212B2 (en) | 2005-03-08 |
ATE344100T1 (de) | 2006-11-15 |
CN1655868B (zh) | 2010-05-26 |
AR039831A1 (es) | 2005-03-02 |
AU2003229339A1 (en) | 2003-12-12 |
CA2486572C (en) | 2011-09-20 |
KR20040111661A (ko) | 2004-12-31 |
TW200400850A (en) | 2004-01-16 |
CA2486572A1 (en) | 2003-12-04 |
DE60309464D1 (de) | 2006-12-14 |
KR20040111662A (ko) | 2004-12-31 |
MXPA04011551A (es) | 2005-02-14 |
JP4642460B2 (ja) | 2011-03-02 |
US20030220193A1 (en) | 2003-11-27 |
DK1507585T3 (da) | 2007-03-12 |
TW200400252A (en) | 2004-01-01 |
BR0311131A (pt) | 2005-02-22 |
NO20044765L (no) | 2004-12-21 |
EP1507585A1 (en) | 2005-02-23 |
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